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For current reviews, see: (a) Schumann, H.; Meese-Marktscheffel, J. A.; Esser, L. Chem. Rev. 1995, 95, 865. (b) Edelmann, F. T. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 4, Chapter 2.
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Attempts to simplify the method of preparation of lanthanidocene complexes have only rarely been undertaken: (a) Watson, P. L.; Whitney, J. F.; Harlow, R. L. Inorg. Chem. 1981, 20, 3271. (b) Booij, M.; Kiers, N. H.; Heeres, H. J.; Teuben, J. H. J. Organomet. Chem. 1989, 364, 79. (c) For further non-salt metathesis routes to organolanthanide complexes, see: Schaverien, C. J. Adv. Organomet. Chem. 1994, 36, 283.
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Watson, P.L.1
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Attempts to simplify the method of preparation of lanthanidocene complexes have only rarely been undertaken: (a) Watson, P. L.; Whitney, J. F.; Harlow, R. L. Inorg. Chem. 1981, 20, 3271. (b) Booij, M.; Kiers, N. H.; Heeres, H. J.; Teuben, J. H. J. Organomet. Chem. 1989, 364, 79. (c) For further non-salt metathesis routes to organolanthanide complexes, see: Schaverien, C. J. Adv. Organomet. Chem. 1994, 36, 283.
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77956777915
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Attempts to simplify the method of preparation of lanthanidocene complexes have only rarely been undertaken: (a) Watson, P. L.; Whitney, J. F.; Harlow, R. L. Inorg. Chem. 1981, 20, 3271. (b) Booij, M.; Kiers, N. H.; Heeres, H. J.; Teuben, J. H. J. Organomet. Chem. 1989, 364, 79. (c) For further non-salt metathesis routes to organolanthanide complexes, see: Schaverien, C. J. Adv. Organomet. Chem. 1994, 36, 283.
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The amine elimination reaction as a route to zirconocene complexes is meanwhile established: (a) Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. (b) Herrmann, W. A.; Morawietz, M. J. A.; Priermeier, T. Angew. Chem. 1994, 106, 2025. (c) Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045 and references therein.
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Hughes, A.K.1
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The amine elimination reaction as a route to zirconocene complexes is meanwhile established: (a) Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. (b) Herrmann, W. A.; Morawietz, M. J. A.; Priermeier, T. Angew. Chem. 1994, 106, 2025. (c) Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045 and references therein.
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Priermeier, T.3
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13
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0001235228
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and references therein
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The amine elimination reaction as a route to zirconocene complexes is meanwhile established: (a) Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936. (b) Herrmann, W. A.; Morawietz, M. J. A.; Priermeier, T. Angew. Chem. 1994, 106, 2025. (c) Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045 and references therein.
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Diamond, G.M.1
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0030562964
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For example, see: Haar, M. D.; Stern, C. L.; Marks, T. J. Organometallics 1996, 15, 1765.
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For a recent review, see: Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. Angew. Chem. 1995, 107, 1255.
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Herrmann, W. A.; Anwander, R.; Riepl, H.; Scherer, W.; Whitaker, C. R. Organometallics 1993, 12, 4342.
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Herrmann, W. A.; Anwander, R.; Munck, F. C.; Scherer, W.; Dufaud, V.; Huber, N. W.; Artus, G. R. J. Z. Naturforsch., B 1994, 49, 1789.
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Artus, G.R.J.7
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33748245136
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For the preparation of 2, see: Spaleck, W.; Antberg, M.; Rohrmann, J.; Winter, A.; Bachmann, B.; Kiprof, P.; Behm, J.; Herrmann, W. A. Angew. Chem., Int. Ed. Engl. 1992, 31, 1347.
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Spaleck, W.1
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Behm, J.7
Herrmann, W.A.8
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20
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4043177927
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note
-
bridge), -22.41 (Si-N).
-
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21
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0000375105
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(a) Mu, Y.; Piers, W. E.; MacDonald, M.-A.; Zaworotko, M. J. Can. J. Chem. 1995, 73, 2233.
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Mu, Y.1
Piers, W.E.2
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Zaworotko, M.J.4
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0000430237
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(b) Mu, Y.; Piers, W. E.; MacQuarrie, D. C.; Zaworotko, M. J.; Young, V. G., Jr. Organometallics 1996, 15, 2720.
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Mu, Y.1
Piers, W.E.2
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Zaworotko, M.J.4
Young Jr., V.G.5
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24
-
-
4043173648
-
-
note
-
For full experimental and characterization details for 4, see the Supporting Information.
-
-
-
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25
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84944502245
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(a) Herrmann, W. A.; Huber, N. W.; Behm, J. Chem. Ber. 1992, 125, 1405.
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Herrmann, W.A.1
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0028316719
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(b) Procopio, L. J.; Carroll, P. J.; Berry, D. H. J. Am. Chem. Soc. 1994, 116, 177.
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0028056290
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89Y NMR resonance could be observed for rac-3. Similar problems were reported for a cyclopentadienyl-derived yttrium complex: Schaverien, C. J. Organometallics 1994, 13, 69.
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Schaverien, C.J.1
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30
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4043152324
-
-
note
-
-3 for Z = 4. Data were collected at 163 K on an Enraf-Nonius CAD4 diffractometer. The structure was solved by Patterson methods, and least-squares refinement of the model based on 2472 reflections (I > 0.01σ(I)) converged to a final R1 = 3.2% (wR2 = 7.4%) and GOF = 1.05. All hydrogen atoms were located in difference Fourier maps and refined with isotropic thermal parameters.
-
-
-
-
31
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0001248656
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Giardello, M. A.; Conticello, V. P.; Brard, L.; Sabat, M.; Rheingold, A. L.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10212.
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Stern, C.L.6
Marks, T.J.7
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2342512360
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(a) den Haan, K. H.; de Boer, J. L; Teuben, J. H.; Spek, A. L.; Kojic-Prodic, B.; Hays, G. R.; Huis, R. Organometallics 1986, 5, 1726.
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Hays, G.R.6
Huis, R.7
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0040567837
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For polyagostic Ln⋯Me interactions, see: (a) Tilley, T. D.; Andersen, R. A.; Zalkin, A. Inorg. Chem. 1984, 23, 2271. (b) Evans, W. J.; Anwander, R.; Ziller, J. W.; Khan, S. I. Inorg. Chem. 1995, 34, 5927.
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Tilley, T.D.1
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Zalkin, A.3
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For polyagostic Ln⋯Me interactions, see: (a) Tilley, T. D.; Andersen, R. A.; Zalkin, A. Inorg. Chem. 1984, 23, 2271. (b) Evans, W. J.; Anwander, R.; Ziller, J. W.; Khan, S. I. Inorg. Chem. 1995, 34, 5927.
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