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Volumn 109, Issue 1, 2009, Pages 88-130

Cryptophanes and their complexes - Present and future

Author keywords

[No Author keywords available]

Indexed keywords

BINDING PROPERTIES; INNER PHASE; MOLECULAR CAVITIES; NEW APPLICATIONS; SENSOR DEVICES; SMALL MOLECULES; SYNTHETIC STRATEGIES;

EID: 64249132406     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/cr0680437     Document Type: Article
Times cited : (366)

References (195)
  • 1
    • 65349182756 scopus 로고    scopus 로고
    • Cram, D. J.; Cram, J. M. Container Molecules and their guests Monographs in Supramolecular Chemistry; Stoddart, J. F., Eds. The Royal Society of Chemistry: Thomas Graham House, Science Park, Cambridge, U.K., 1994.
    • Cram, D. J.; Cram, J. M. Container Molecules and their guests Monographs in Supramolecular Chemistry; Stoddart, J. F., Eds. The Royal Society of Chemistry: Thomas Graham House, Science Park, Cambridge, U.K., 1994.
  • 2
    • 4243301034 scopus 로고    scopus 로고
    • Atwood, J. L, Lehn, J.-M, Davies, J. E. D, MacNicol, D. D, Vögtle, F, Eds, Elsevier: Amsterdam
    • Frömming, K. H. In Comprehensive Supramolecular Chemistry; Atwood, J. L., Lehn, J.-M., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Eds.; Elsevier: Amsterdam, 1996; Vol. 10, p 445.
    • (1996) Comprehensive Supramolecular Chemistry , vol.10 , pp. 445
    • Frömming, K.H.1
  • 7
    • 65349181145 scopus 로고    scopus 로고
    • The name cryptophane was introduced by A. Collet to designate this new class of molecules, recalling the cyclophane structure and the presence of an inner cavity
    • The name cryptophane was introduced by A. Collet to designate this new class of molecules, recalling the cyclophane structure and the presence of an inner cavity.
  • 16
    • 0000577119 scopus 로고    scopus 로고
    • Atwood, J. L, Lehn, J.-M, Davies, J. E. D, MacNicol, D. D, Vögtle, F, Eds, Elsevier: Amsterdam
    • Collet, A. In Comprehensive Supramolecular Chemistry; Atwood, J. L., Lehn, J.-M., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Eds.; Elsevier: Amsterdam, 1996; Vol. 2, p 325.
    • (1996) Comprehensive Supramolecular Chemistry , vol.2 , pp. 325
    • Collet, A.1
  • 18
    • 65349173330 scopus 로고    scopus 로고
    • See ref 1, Chapter 10.
    • See ref 1, Chapter 10.
  • 20
    • 0030515326 scopus 로고    scopus 로고
    • Rebek, J., Jr. Chem. Soc. Rev. 1996, 255.
    • Rebek, J., Jr. Chem. Soc. Rev. 1996, 255.
  • 28
    • 65349179354 scopus 로고    scopus 로고
    • 1][1,5,19,23]tetra - oxacyclohexatriacontin-5,12,13,20,25,32,33,40-octahydro-2,16,22,36, 43,52-hexamethoxy-(±).
    • 1][1,5,19,23]tetra- oxacyclohexatriacontin-5,12,13,20,25,32,33,40-octahydro-2,16,22,36, 43,52-hexamethoxy-(±).
  • 29
    • 65349115096 scopus 로고    scopus 로고
    • In the direct method, the use of dissymmetrical bis(benzyl alcohol) derivatives would lead to untractable mixtures of cryptophane compounds
    • In the direct method, the use of dissymmetrical bis(benzyl alcohol) derivatives would lead to untractable mixtures of cryptophane compounds.
  • 46
    • 65349110686 scopus 로고    scopus 로고
    • Humilière, D. Doctorat thesis, École Normale Supérieure de Lyon, France, 2002.
    • Humilière, D. Doctorat thesis, École Normale Supérieure de Lyon, France, 2002.
  • 63
    • 65349128518 scopus 로고    scopus 로고
    • 2 groups in the alkyl linkers.
    • 2 groups in the alkyl linkers.
  • 65
    • 37049054801 scopus 로고    scopus 로고
    • 2Li or dealkylation reactions of alkyl aryl ethers, see: (a) Mann, F. G.; Pragnell, M. J. J. Chem. Soc. 1965, 4120.
    • 2Li or dealkylation reactions of alkyl aryl ethers, see: (a) Mann, F. G.; Pragnell, M. J. J. Chem. Soc. 1965, 4120.
  • 70
    • 65349108405 scopus 로고    scopus 로고
    • Lozach, B. Doctorat thesis, University of Lyon, France, 1991.
    • Lozach, B. Doctorat thesis, University of Lyon, France, 1991.
  • 82
    • 33846248326 scopus 로고    scopus 로고
    • (a) Kuck, D. Chem. Rev. 2006, 106, 4885.
    • (2006) Chem. Rev , vol.106 , pp. 4885
    • Kuck, D.1
  • 88
    • 65349108404 scopus 로고    scopus 로고
    • 2) or water molecules inside the cryptophane cavities cannot be excluded.
    • 2) or water molecules inside the cryptophane cavities cannot be excluded.
  • 89
    • 0002666172 scopus 로고    scopus 로고
    • The presence of dissolved oxygen can increase even more the broadening of the signals (see, for instance: (b) Tanner, M. E.; Knobler, C. B.; Cram, D. J. J. Org. Chem. 1992, 57, 40.
    • The presence of dissolved oxygen can increase even more the broadening of the signals (see, for instance: (b) Tanner, M. E.; Knobler, C. B.; Cram, D. J. J. Org. Chem. 1992, 57, 40.
  • 90
    • 65349099109 scopus 로고
    • Doctorat thesis, University of Lyon, France
    • Garel, L. Doctorat thesis, University of Lyon, France, 1995.
    • (1995)
    • Garel, L.1
  • 91
    • 65349139206 scopus 로고    scopus 로고
    • At the time of this work, the possibility to have an out-saddle conformer was not considered. In the light of recent results and the lack of variable temperature NMR experiments, the out-saddle conformer cannot be excluded for inv-113 instead of the in-out conformer. The value of the activation energy, close to that reported in ref 31 supports this assumption
    • At the time of this work, the possibility to have an out-saddle conformer was not considered. In the light of recent results and the lack of variable temperature NMR experiments, the out-saddle conformer cannot be excluded for inv-113 instead of the in-out conformer. The value of the activation energy, close to that reported in ref 31 supports this assumption.
  • 92
    • 65349091095 scopus 로고    scopus 로고
    • Le Letty, M. Doctorat thesis, Ecole Normale Supérieure de Lyon, France, 1997.
    • Le Letty, M. Doctorat thesis, Ecole Normale Supérieure de Lyon, France, 1997.
  • 99
    • 65349088818 scopus 로고    scopus 로고
    • 1,1,2,2-Tetrachloroethane-d2 is a quite acidic solvent but was preferred to hexachloroacetone due to its higher stability see ref 39
    • 2 is a quite acidic solvent but was preferred to hexachloroacetone due to its higher stability (see ref 39).
  • 103
    • 65349102574 scopus 로고    scopus 로고
    • This value was deduced from the previous one reported for cryptophane-A (1) as estimated with the program GRASP (see ref 89, A smaller value (81.5 Å3, determined with the molecular modeling software PCMODEL, was reported earlier see ref 9
    • 3), determined with the molecular modeling software PCMODEL, was reported earlier (see ref 9).
  • 122
    • 65349088817 scopus 로고    scopus 로고
    • It is interesting to note that, according to the occupancy factor defined by Rebek Jr. (see section 6.1), radon is probably the ideal guest for cryptophane-A, and development of radon sensors based on cryptophane-A should be seriously considered, taking into account its radioactive properties.
    • It is interesting to note that, according to the occupancy factor defined by Rebek Jr. (see section 6.1), radon is probably the ideal guest for cryptophane-A, and development of radon sensors based on cryptophane-A should be seriously considered, taking into account its radioactive properties.
  • 132
    • 65349149737 scopus 로고    scopus 로고
    • 129Xe chemical shifts were referenced to the resonance frequency of pure xenon gas extrapolated to zero pressure.
    • 129Xe chemical shifts were referenced to the resonance frequency of pure xenon gas extrapolated to zero pressure.
  • 141
    • 65349130358 scopus 로고    scopus 로고
    • (b) 2003, 119, 2691.
    • (2003) , vol.2691 , Issue.119
  • 142
    • 65349163101 scopus 로고    scopus 로고
    • (c) 2003, 119, 2694.
    • (2003) , vol.2694 , Issue.119
  • 143
    • 65349160655 scopus 로고    scopus 로고
    • (d) 2004, 120, 3277.
    • (2004) , vol.3277 , Issue.120
  • 167
    • 0001221472 scopus 로고    scopus 로고
    • The spectroscopic moments are empirical parameters, which have been introduced to quantify the influence of the substituents on the absorption intensities in aromatic compounds. See, for instance: (a) Platt, J. R. J. Chem. Phys. 1951, 19, 263.
    • The spectroscopic moments are empirical parameters, which have been introduced to quantify the influence of the substituents on the absorption intensities in aromatic compounds. See, for instance: (a) Platt, J. R. J. Chem. Phys. 1951, 19, 263.
  • 169
    • 65349187385 scopus 로고
    • (c) 1977, 33, 2315.
    • (1977) , vol.2315 , Issue.33
  • 172
    • 18644382407 scopus 로고    scopus 로고
    • Bultinck, P, de Winter, H, Langenaecker, W, Tollenaere, J, Eds, Dekker: New York
    • Stephens, P. J. In Computational Medicinal Chemistry for Drug DiscoVery; Bultinck, P., de Winter, H., Langenaecker, W., Tollenaere, J., Eds.; Dekker: New York, 2003; pp 699-725.
    • (2003) Computational Medicinal Chemistry for Drug DiscoVery , pp. 699-725
    • Stephens, P.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.