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65349179354
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1][1,5,19,23]tetra - oxacyclohexatriacontin-5,12,13,20,25,32,33,40-octahydro-2,16,22,36, 43,52-hexamethoxy-(±).
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2) or water molecules inside the cryptophane cavities cannot be excluded.
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2) or water molecules inside the cryptophane cavities cannot be excluded.
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89
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The presence of dissolved oxygen can increase even more the broadening of the signals (see, for instance: (b) Tanner, M. E.; Knobler, C. B.; Cram, D. J. J. Org. Chem. 1992, 57, 40.
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At the time of this work, the possibility to have an out-saddle conformer was not considered. In the light of recent results and the lack of variable temperature NMR experiments, the out-saddle conformer cannot be excluded for inv-113 instead of the in-out conformer. The value of the activation energy, close to that reported in ref 31 supports this assumption.
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65349091095
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1,1,2,2-Tetrachloroethane-d2 is a quite acidic solvent but was preferred to hexachloroacetone due to its higher stability see ref 39
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2 is a quite acidic solvent but was preferred to hexachloroacetone due to its higher stability (see ref 39).
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