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Volumn 120, Issue 4, 1998, Pages 784-791

129Xe and 1H NMR study of the reversible trapping of xenon by cryptophane-A in organic solution

Author keywords

[No Author keywords available]

Indexed keywords

CRYPTOPHANE A; ORGANIC COMPOUND; UNCLASSIFIED DRUG; XENON;

EID: 0032481407     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja972377j     Document Type: Article
Times cited : (190)

References (35)
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    • (1991) Annu. Rev. Phys. Chem. , vol.42 , pp. 433-463
    • Dybowski, C.1    Bansal, N.2
  • 15
    • 0026642751 scopus 로고
    • For relevant reviews see: (a) Reisse, J. New J. Chem. 1986, 10, 665-672. (b) Dybowski, C.; Bansal, N. Annu. Rev. Phys. Chem. 1991, 42, 433-463. (c) Barrie, P. J.; Klinowski, J.; Raftery, D. Prog. Nucl. Magn. Reson. Spectrosc. 1992, 91-108. (d) Raftery, D.; Chmelka, B. F. In NMR Basic Principles and Progress. Solid-State NMR I: Methods; Springer-Verlag: Berlin, 1994; Vol. 30, pp 111-157.
    • (1992) Prog. Nucl. Magn. Reson. Spectrosc. , pp. 91-108
    • Barrie, P.J.1    Klinowski, J.2    Raftery, D.3
  • 16
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    • For relevant reviews see: (a) Reisse, J. New J. Chem. 1986, 10, 665-672. (b) Dybowski, C.; Bansal, N. Annu. Rev. Phys. Chem. 1991, 42, 433-463. (c) Barrie, P. J.; Klinowski, J.; Raftery, D. Prog. Nucl. Magn. Reson. Spectrosc. 1992, 91-108. (d) Raftery, D.; Chmelka, B. F. In NMR Basic Principles and Progress. Solid-State NMR I: Methods; Springer-Verlag: Berlin, 1994; Vol. 30, pp 111-157.
    • (1994) NMR Basic Principles and Progress. Solid-State NMR I: Methods , vol.30 , pp. 111-157
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  • 19
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    • note
    • 3, 4.33 ppm.
  • 25
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    • See ref 11b
    • See ref 11b.
  • 26
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    • note
    • 3) when the spacer bridges are in their energetically more favorable gauche conformation.
  • 28
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    • note
    • -1) of complexation (from ref 3).
  • 30
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    • note
    • -1) of complexation (from ref 3).
  • 31
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    • note
    • 3) in this cryptophane or in cryptophanes of the same size.
  • 33
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    • Cryptophanes
    • Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Eds.; Ed. Vögtle, F.; Pergamon: New York, Chapter 11
    • See ref 3 and Collet, A. Cryptophanes. In Comprehensive Supra-molecular Chemistry; Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vögtle, F., Eds.; Vol. 2 Ed. Vögtle, F.; Pergamon: New York, 1996, Chapter 11, pp 325-365.
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  • 34
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    • note
    • 3, the occupancy factor of the chloroform molecule would be as large as 88%, a figure that is certainly overestimated but nevertheless reflects the "lock and key" structure of the complex. In a close-packed crystal the packing coefficient, i.e., the molecular volume divided by the cell volume, rarely exceeds 75%.


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