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After one week in tetrachloroethane solution no changes in the CD spectrum were observed, however, the fluorescence spectrum revealed a small monomer like signal (<1.5% monomer, which slowly became stronger in time. The monomer-like emission might be the result of the unwinding of the helix at its terminals or slow decomposition of the polymers at its terminals, because of reaction of the polyimide backbone with carbene- or radical-like species in solution. In the solid state the polymer is very stable over periods of up to 2 years. Differential scanning calorimetry (DSC) showed an endothermic peak at 850C in the heating trace with a corresponding exothermic peak at 58°C in the cooling trace, which can be attributed to the melting and crystallization of the alkyl tails in the periphery of the polymer, respectively, Figure S4
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