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Volumn , Issue 5, 2006, Pages 1177-1184

The design and synthesis of bis(thiourea) ligands and their application in Pd-catalyzed heck and suzuki reactions under aerobic conditions

Author keywords

Cross coupling; Homogeneous catalysis; Palladium; S ligands

Indexed keywords


EID: 33644748180     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200500644     Document Type: Article
Times cited : (70)

References (66)
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    • For recent reviews on N-heterocyclic carbene-palladium catalysts, see: a) W. A. Herrmann, Angew. Chem. Int. Ed. 2002, 41, 1290-1309;
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 1290-1309
    • Herrmann, W.A.1
  • 44
    • 33644755802 scopus 로고    scopus 로고
    • note
    • Some Pd black deposited when the Pd complex of monothiourea 7a was heated under the same conditions.
  • 45
    • 33644764254 scopus 로고    scopus 로고
    • note
    • 0·2a (m/z = 720.7 [M + Na]).
  • 50
    • 85078684394 scopus 로고    scopus 로고
    • and references cited therein
    • C. Gurtler, S. L. Buchwald, Chem. Eur. J. 1999, 5, 3107-3112 and references cited therein.
    • (1999) Chem. Eur. J. , vol.5 , pp. 3107-3112
    • Gurtler, C.1    Buchwald, S.L.2
  • 58
    • 4644233894 scopus 로고    scopus 로고
    • For recent reports on the use of ESI-MS in Pd-catalyzed mechanism studies, see: a) C. Markert, A. Pfaltz, Angew. Chem. Int. Ed. 2004, 43, 2498-2500;
    • (2004) Angew. Chem. Int. Ed. , vol.43 , pp. 2498-2500
    • Markert, C.1    Pfaltz, A.2
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    • [9b]
    • [9b]
  • 63
    • 33644759569 scopus 로고    scopus 로고
    • note
    • 2 could not be formed owing to the steric hindrance.
  • 64
    • 33644787246 scopus 로고    scopus 로고
    • note
    • The same ESI-MS results were obtained with bis(thiourea) ligand 1f.
  • 65
    • 33644764253 scopus 로고    scopus 로고
    • Trigonal or coordinatively saturated Pd complexes can be produced from diphosphane ligands and palladium. The latter complexes also display low catalytic activity in the Heck reaction. See: a) M. Portnoy, D. Milstein, Organometallics 1999, 18, 1655-1664;
    • (1999) Organometallics , vol.18 , pp. 1655-1664
    • Portnoy, M.1    Milstein, D.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.