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Volumn 48, Issue 4, 2009, Pages 738-741

Synthesis and redox-induced structural isomerization of the pentagonal bipyramidal complexes [W(CN)5(CO)2]3- and [W(CN)5(CO)2]2-

Author keywords

Carbonyl ligands; Cyanides; Isomerization; Oxidation; Tungsten

Indexed keywords

CARBON MONOXIDE; CARBONYLATION; CHELATION; CRYSTALLOGRAPHY; CYANIDES; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TRANSITIONS; ISOMERIZATION; ISOMERS; LIGANDS; OXIDATION; PARAMAGNETIC RESONANCE; TUNGSTEN; X RAY CRYSTALLOGRAPHY;

EID: 58249103036     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200804199     Document Type: Article
Times cited : (13)

References (46)
  • 4
    • 58249112227 scopus 로고    scopus 로고
    • C. P. Berlinguette, D. Vaughn, C. Cañada-Vilalta, J. R. Galán-Mascarós, K. R. Dunbar, Angew. Chem. 2003, 115, 1561;
    • d) C. P. Berlinguette, D. Vaughn, C. Cañada-Vilalta, J. R. Galán-Mascarós, K. R. Dunbar, Angew. Chem. 2003, 115, 1561;
  • 35
    • 41449104303 scopus 로고    scopus 로고
    • While incorporation of [Re(CN)7]3- into a pentanuclear cluster recently led to a single-molecule magnet, this species indeed proved unstable toward reduction: D. E. Freedman, D. M. Jenkins, A. T. Iavarone, J. R. Long, J. Am. Chem. Soc. 2008, 130, 2884
    • 3- into a pentanuclear cluster recently led to a single-molecule magnet, this species indeed proved unstable toward reduction: D. E. Freedman, D. M. Jenkins, A. T. Iavarone, J. R. Long, J. Am. Chem. Soc. 2008, 130, 2884.
  • 37
    • 58249117705 scopus 로고    scopus 로고
    • For recent examples of how the use of mixed cyanide/carbonyl ligand sets can shift the redox stability of octahedral iron complexes, see: a J. Jiang, S. A. Koch, Angew. Chem. 2001, 113, 2699;
    • For recent examples of how the use of mixed cyanide/carbonyl ligand sets can shift the redox stability of octahedral iron complexes, see: a) J. Jiang, S. A. Koch, Angew. Chem. 2001, 113, 2699;
  • 41
    • 58249094938 scopus 로고    scopus 로고
    • See Tables S1 and S2 in the Supporting Information for crystal data and structure refinement details. CCDC 672441 and 672442 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif..
    • See Tables S1 and S2 in the Supporting Information for crystal data and structure refinement details. CCDC 672441 and 672442 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif..
  • 46
    • 58249110473 scopus 로고    scopus 로고
    • DFT calculations were performed using Jaguar, version 6.5, Schr dinger, LLC, New York, NY, 2005, with a spin restricted formalism. Complex geometries were taken from the crystal structures of 1 and 2, and were then optimized using the LACVP functional. Effective core potentials were employed for W (LanL2DZ) while C, N, and O atoms were described with the 6-31G basis set
    • DFT calculations were performed using Jaguar, version 6.5, Schr dinger, LLC, New York, NY, 2005, with a spin restricted formalism. Complex geometries were taken from the crystal structures of 1 and 2, and were then optimized using the LACVP functional. Effective core potentials were employed for W (LanL2DZ) while C, N, and O atoms were described with the 6-31G basis set.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.