Evidence for increased exchange interactions with 5d compared to 4d metal ions. Experimental and theoretical insights into the ferromagnetic interactions of a series of trinuclear [{M(CN)8}3-/NiII] compounds (M = MoV or WV)

Journal of the American Chemical Society

Volumn 128, Issue 31, 2006, Pages 10202-10212

  Visinescu, Diana ^a,c   Desplanches, Cédric ^a   Imaz, Inhar ^a   Bahers, Vincent ^a   Pradhan, Rabindranath ^a   Villamena, Frederick A ^a   Guionneau, Philippe ^a   Sutter, Jean Pascal ^a,b  

^a INST CHIM MATIERE COND BORDEAUX   (France)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^c INSTITUTE OF PHYSICAL CHEMISTRY   (Romania)

Author keywords

[No Author keywords available]

Indexed keywords

DERIVATIVES; FERROMAGNETISM; MOLECULAR STRUCTURE; PARAMAGNETIC MATERIALS; PROBABILITY DENSITY FUNCTION;

BRIDGING LIGANDS; FERROMAGNETIC INTERACTIONS; SPIN DENSITY DISTRIBUTION; STRENGTH MODULATION; TRIMETALLIC CYANO-BRIDGE;

FERROMAGNETIC MATERIALS;

FERROMAGNETIC MATERIAL; METAL ION;

ARTICLE; CLUSTER ANALYSIS; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; GEOMETRY; LIGAND BINDING; MATERIAL STATE; MOLECULAR INTERACTION; QUALITATIVE ANALYSIS; QUANTITATIVE ANALYSIS;

EID: 33747026254     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja061911x     Document Type: Article

References (61)

1. Mathonière, C.; Sutter, J.-P.; Yakhmi, J. V. In Magnetism: molecules to materials; Miller, J. S., Drillon, M., Eds.; Wiley-VCH: Weinheim, 2002; Vol. 4, pp 1-40.
2. Ruiz, E.; Rodriguez-Fortea, A.; Alvarez, S.; Verdaguer, M. Chem. Eur. J. 2005, 11, 2135-2144.
3. Larionova, J.; Clérac, R.; Sanchiz, J.; Kahn, O.; Golhen, S.; Ouahab, L. J. Am. Chem. Soc. 1998, 120, 13088-13095.
4. Kahn, O.; Larionova, J.; Ouahab, L. Chem. Commun. 1999, 945-952.
5. Pilkington, M.; Decurtins, S. Chimia 2000, 54, 593-601.
6. Zhong, Z. J.; Seino, H.; Mizobe, Y.; Hidai, M.; Verdaguer, M.; Ohkoshi, S.-I.; Hashimoto, K. Inorg. Chem. 2000, 39, 5095-5001.
7. Larionova, J.; Clérac, R.; Donnadieu, B.; Guérin, C. Chem. Eur. J. 2002, 8, 2712-2716.
8. Herrera, J. M.; Bleuzen, A.; Dromzée, Y.; Julve, M.; Lloret, F.; Verdaguer, M. Inorg. Chem. 2003, 42, 7052-7059.
9. Tanase, S.; Tuna, F.; Guionneau, P.; Maris, T.; Rombaut, G.; Mathonière, C.; Andruh, M.; Kahn, O.; Sutter, J.-P. Inorg. Chem. 2003, 42, 1625-1631.
10. Arimoto, Y.; Ohkoshi, S.-I.; Zhong, Z. J.; Seino, H.; Mizobe, Y.; Hashimoto, K. J. Am. Chem. Soc. 2003, 125, 9240.
11. Song, Y.; Ohkoshi, S.; Arimoto, Y.; Seino, H.; Mizobe, Y.; Hashimoto, K. Inorg. Chem. 2003, 42, 1848-1856.
12. Le Goff, X. F.; Willemin, S.; Coulon, C.; Larionova, J.; Donnadieu, B.; Clérac, R. Inorg. Chem. 2004, 43, 4784-4786.
13. Kashiwagi, T.; Ohkoshi, S.; Seino, H.; Mizobe, Y.; Hashimoto, K. J. Am. Chem. Soc. 2004, 126, 5024-5025.
14. Larionova, J.; Gross, M.; Pilkington, M.; Andres, H.; Stoeckli-Evans, H.; Güdel, H. U.; Decurtins, S. Angew. Chem., Int. Ed. 2000, 39, 1605-1609.
15. Zhong, Z. J.; Seino, H.; Mizobe, Y.; Hidai, M.; Fujishima, A.; Ohkoshi, S.-I.; Hashimoto, K. J. Am. Chem. Soc. 2000, 122, 2952-2953.
16. Podgajny, R.; Desplanches, C.; Sieklucka, B.; Sessoli, R.; Villar, V.; Paulsen, C.; Wernsdorfer, W.; Dromzée, Y.; Verdaguer, M. Inorg. Chem. 2002, 41, 1323-1327.
17. Bonadio, F.; Gross, M.; Stoeckli-Evans, H.; Decurtins, S. Inorg. Chem. 2002, 41, 5891-5896.
18. Sieklucka, B.; Podgajny, R.; Korzeniak, T.; Przychodzen, P.; Kania, R. C. R. Chim. 2002, 5, 639-649.
19. Pradhan, R.; Desplanches, C.; Guionneau, P.; Sutter, J.-P. Inorg. Chem. 2003, 42, 6607-6609.
20. Song, Y.; Zhang, P.; Ren, X.-M.; Shen, X.-F.; Li, Y.-Z.; You, X.-Z. J. Am. Chem. Soc. 2005, 127, 3708-3709.
21. Li, D.; Gao, S.; Zheng, L.; Yu, K.; Tang, W. New J. Chem. 2002, 26, 1190-1195.
22. Sokol, J. J.; Hee, A. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 7656-7657.
23. Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279-2292.
24. Beauvais, L. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2110-2111.
25. Przychodzen, P.; Lewinski, K.; Balanda, M.; Pelka, R.; Rams, M.; Wasiutynski, T.; Guyard-Duhayon, C.; Sieklucka, B. Inorg. Chem. 2004, 43, 2967-2974.
26. Marvaud, V.; Decroix, C.; Souiller, A.; Tuyèras, F.; Guyard-Duhayon, C.; Vaissermann, J.; Marrot, J.; Gonnet, F.; Verdaguer, M. Chem. Eur. J. 2003, 9, 1692-1705.
27. Lescouëzec, R.; Toma, L. M.; Vaissermann, J.; Verdaguer, M.; Delgado, F. S.; Ruiz-Pérez, C.; Lloret, F.; Julve, M. Coord. Chem. Rev. 2005, 249, 2691-2729.
28. Ferromagnetic interaction was also observed for Mo(III); see ref 23.
29. Raghunathan, R.; Sutter, J.-P.; Ducasse, L.; Desplanches, C.; Ramasesha, S. Phys. Rev. B 2006, 73, 104438.
30. Perumareddi, J. R.; Liehr, A. D.; Adamson, A. W. J. Am. Chem. Soc. 1963, 85, 249-259.
31. Muetterties, E. L.; Guggenberger, L. J. J. Am. Chem. Soc. 1974, 96, 1748-1756.
32. φ is the dihedral angle between two triangles constructed from the trapezoid atoms, i.e., the triangles delineated by A-A and the middle of BB, and B-B and the middle of the AA edge (see ref 31).
33. Alvarez, S.; Alemany, P.; Casanova, D.; Cirera, J.; Llunell, M.; Avnir, D. Coord. Chem. Rev. 2005, 249, 1693-1708.
34. Casanova, D.; Llunell, M.; Alemany, P.; Alvarez, S. Chem. Eur. J. 2005, 11, 1479-1494.
35. Casanova, D.; Cirera, J.; Llunell, M.; Alemany, P.; Avnir, D.; Alvarez, S. J. Am. Chem. Soc. 2004, 126, 1755-1763.
36. Cirera, J.; Ruiz, E.; Alvarez, S. Chem. Eur. J. 2006, 12, 3162-3167.
37. Ballhausen, C. J. Introduction to ligand field theory; McGraw-Hill Books Inc.: New York, 1962.
38. x2-y2.
39. Burdett, J. K.; Hoffmann, R.; Fay, R. C. Inorg. Chem. 1978, 17, 2553-2568.
40. Verdaguer, M.; Bleuzen, A.; Train, C.; Garde, R.; Fabrizi de Biani, F.; Desplanches, C. Philos. Trans. R. Soc. London A 1999, 357, 2959-2976.
41. Glendening, E. D.; Reed, A. E.; Carpenter, J. E.; Weinhold, F. NBO 3.1; University of Wisconsin: Madison, WI, 1996.
42. Figgis, B. N.; Forsyth, J. B.; Reynolds, P. A. Inorg. Chem. 1987, 26, 101-105.
43. Gadet, V.; Mallah, T.; Castro, I.; Verdaguer, M. J. Am. Chem. Soc. 1992, 114, 9213-9214.
44. Verdaguer, M.; Girolami, G. S. In Magnetism: Molecules to materials; Miller, J. S., Drillon, M., Eds.; Wiley-VCH: Weinheim, 2005; Vol. 5, pp 283-346.
45. Kahn, O. Molecular Magnetism; VCH: Weinheim, 1993.
46. Marvaud, V.; Herrera, J.-M.; Barilero, T.; Tuyeras, F.; Grade, R.; Scuiller, A.; Decroix, C.; Cantuel, M.; Desplanches, C. Monatsh. Chem. 2003, 234, 149-163.
47. Ruiz, E.; Gopalan, G.; Alvarez, S.; Gillon, B.; Stride, J.; Clérac, R.; Larionova, J.; Decurtins, S. Angew. Chem., Int. Ed. 2005, 44, 2711-2715.
48. Verdaguer, M.; Bleuzen, A.; Marvaud, V.; Vaissermann, J.; Seuleiman, M.; Desplanches, C.; Scuiller, A.; Train, C.; Garde, R.; Gelly, G.; Lomenech, C.; Rosenman, I.; Veillet, P.; Cartier, C.; Villain, F. Coord. Chem. Rev. 1999, 190-192, 1023-1047.
49. Dennis, C. R.; van Wyk, A. J.; Basson, S. S.; Leipoldt, J. G. Transition Met. Chem. 1992, 17, 471-473.
50. Karn, J. L.; Busch, D. H. Inorg. Chem. 1969, 8, 1149-1153.
51. Hoard, J. L.; Silverton, J. V. Inorg. Chem. 1963, 2, 235-242.
52. Desplanches, C.; Ruiz, E.; Alvarez, S. Eur. J. Inorg. Chem. 2003, 1756-1760.
53. Low, D.; Rajaraman, G.; Helliwell, M.; Walsmann, O.; Gudel, H.; Adams, M.; Ruiz, E.; Alvarez, S.; McInnes, E. Chem. Eur. J. 2006, 12, 1385-1396.
54. Ruiz, E.; Nunzi, F.; Alvarez, S. Nano Lett. 2006, 6, 380-384.
55. Becke, A. D. J. J. Chem. Phys. 1993, 98, 5648-5652.
56. Frisch, M. J.; et al. Gaussian98; Gaussian, Inc.: Pittsburgh, PA, 1998.
57. Dunning, T. H. J.; Hay, P. J. In Modern Theoretical Chemistry; Schaefer, H. F., III, Ed.; Plenum: New York, 1976; Vol. 3.
58. Hay, P. J.; Wadt, R. J. Chem. Phys. 1985, 82, 299-310.
59. Ruiz, E.; Cano, J.; Alvarez, S.; Alemany, P. J. Comput. Chem. 1999, 20, 1391-1340.
60. Ruiz, E.; Alvarez, S.; Cano, J.; Polo, V. J. Chem. Phys. 2005, 1234, 164110.
61. Löwdin, P.-O. Phys. Rev. 1955, 97, 1474-1489.