Electrochemical tunable magnetic phase transition in a high-Tc chromium cyanide thin film

Science

Volumn 271, Issue 5245, 1996, Pages 49-51

  Sato, O ^a   Iyoda, T ^a   Fujishima, A ^b   Hashimoto, K ^a,b  

^a KANAGAWA ACADEMY OF SCIENCE AND TECHNOLOGY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CYANIDES; ELECTROCHEMISTRY; FERRIMAGNETIC MATERIALS; FERRIMAGNETISM; HIGH TEMPERATURE SUPERCONDUCTORS; MAGNETIC PROPERTIES; MOLECULAR STRUCTURE; PARAMAGNETISM; PHASE TRANSITIONS; SUPERCONDUCTING TRANSITION TEMPERATURE; SYNTHESIS (CHEMICAL); TEMPERATURE CONTROL;

CHROMIUM CYANIDES; CRITICAL TEMPERATURE; ELECTROCHEMICAL CONTROL; FERRIMAGNETIC THIN FILMS; MAGNETIC PHASE TRANSITION; MOLECULAR BASED COMPOUNDS;

SUPERCONDUCTING FILMS;

EID: 0030569720     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.271.5245.49     Document Type: Article

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8. c, reported for a stable molecular-based magnet before the present work
9. c reported if such air-sensitive magnets are included in the comparison
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11. 6], respectively. The error of the ratio of Cr to CN for the matenals prepared under same electrochemical conditions was ±4% at maximum. The materials did not have as pure and well-defined a structure as would a single crystal.
12. K. Nakamoto, Ed., Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley, New York, ed 4. 1986)
13. c. = 240 K).
14. 6] 15. Electrically tunable magnets are proposed here to be designated as "electromagnetic materials" by analogy with the term "electrochromism "
15. We thank H. Eton and J. lchiyanagi for their support in these experiments and D Tryk for reading the manuscript