Property-oriented rational design of single-molecule magnets: A C 3-symmetric Mn6Cr complex based on three molecular building blocks with a spin ground state of St = 21/2

Angewandte Chemie - International Edition

Volumn 45, Issue 36, 2006, Pages 6033-6037

  Glaser, Thorsten ^a   Heidemeier, Maik ^a   Weyhermüller, Thomas ^b   Hoffmann, Rolf Dieter ^c   Rupp, Holger ^d   Müller, Paul ^d  

^a BIELEFELD UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^c UNIVERSITY OF MÜNSTER   (Germany)

^d UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Chromium; Magnetic properties; Manganese; N,O ligands; Single molecule magnets

Indexed keywords

N,O LIGANDS; QUANTUM TUNNELING; SINGLE-MOLECULE MAGNETS;

CHROMIUM; COMPLEXATION; GROUND STATE; MAGNETIC ANISOTROPY; MAGNETIZATION; MANGANESE; MOLECULAR STRUCTURE;

MAGNETS;

CHROMIUM; MANGANESE; ORGANOMETALLIC COMPOUND; PHLOROGLUCINOL; STRONTIUM;

ARTICLE; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROSPRAY MASS SPECTROMETRY; MAGNETISM; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION REDUCTION REACTION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CHROMIUM; CRYSTALLOGRAPHY, X-RAY; MAGNETIC RESONANCE SPECTROSCOPY; MAGNETICS; MANGANESE; MODELS, CHEMICAL; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PHLOROGLUCINOL; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; SPECTROMETRY, MASS, MATRIX-ASSISTED LASER DESORPTION-IONIZATION; STRONTIUM;

EID: 33748764927     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600712     Document Type: Article

References (61)

1. G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66-71.
2. a) R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141-143;
3. b) R. Sessoli, H. L. Tsai, A. R. Schake, S. Y. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1993, 115, 1804-1816.
4. a) D. Gatteschi, A. Caneschi, L. Pardi, R. Sessoli, Science 1994, 265, 1054-1058;
5. b) S. M. J. Aubin, N. R. Dilley, L. Pardi, J. Krzystek, M. W. Wemple, L. C. Brunel, M. B. Maple, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1998, 120, 4991-5004;
6. c) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278-309;
7. Angew. Chem. Int. Ed. 2003, 42, 268-297;
8. d) J. R. Long in Chemistry of None-structured Materials (Ed.: P. Yang), World Scientific, Hong Kong, 2003, pp. 291-315;
9. e) L. Thomas, F. Lionti, R. Ballou, D. Gatteschi, R. Sessoli, B. Barbara, Nature 1996, 383, 145-147.
10. a) J. Tejada, E. M. Chudnovsky, E. del Barca, J. M. Hernandez, T. P. Spiller, Nanotechnology 2001, 12, 181-186;
11. b) J. Tejada, Polyhedron 2001, 20, 1751-1756;
12. c) D. D. Awschalom, D. P. Di Vincenzo, J. J. Smyth, Science 1992, 258, 414-421;
13. d) M. N. Leuenberger, D. Loss, Nature 2001, 410, 789-793;
14. e) A. Cornia, A. C. Fabretti, M. Pacchioni, L. Zobbi, D. Bonachi, A. Caneschi, D. Gatteschi, R. Biagi, U. Del Pennino, V. De Renzi, L. Gurevich, H. S. J. van der Zant, Angew. Chem. 2003, 115, 1683-1686;
15. Angew. Chem. Int. Ed. 2003, 42, 1645-1648;
16. f) E. D. Dahlberg, Phys. Today 1995, 48, 34.
17. a) T. Lis, Acta Crystallogr. Sect. B 1980, 36, 2042-2046;
18. b) P. D. W. Boyd, Q. Y. Li, J. B. Vincent, K. Folting, H. R. Chang, W. E. Streib, J. C. Huffman, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1988, 110, 8537-8539;
19. c) H. L. Tsai, H. J. Eppley, N. Devries, K. Folting, G. Christou, D. N. Hendrickson, J. Chem. Soc. Chem. Commun. 1994, 1745-1746;
20. d) Z. M. Sun, D. Ruiz, E. Rumberger, C. D. Incarvito, K. Folting, A. L. Rheingold, G. Christou, D. N. Hendrickson, Inorg. Chem. 1998, 37, 4758-4759;
21. e) C. Boskovic, E. K. Brechin, W. E. Streib, K. Folting; J. C. Bollinger, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 2002, 124, 3725-3736.
22. a) C. Delfs, D. Gatteschi, L. Pardi, R. Sessoli, K. Wieghardt, D. Hanke, Inorg. Chem. 1993, 32, 3099-3103;
23. b) S. M. J. Aubin, N. R. Dilley, M. W. Wemple, N. B. Maple, G. Christou, D. N. Hendrickson, J. Am. Chem. Soc. 1998, 120, 839-840;
24. c) S. L. Castro, Z. M. Sun, C. M. Grant, J. C. Bollinger, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 1998, 120, 2365-2375;
25. d) S. T. Ochsenbein, M. Murrie, E. Rusanov, H. Stoeckli-Evans, C. Sekine, H. U. Güdel, Inorg. Chem. 2002, 41, 5133-5140;
26. e) C. P. Berlinguelle, D. Vaughn, C. Canada-Vilalta, J. R. Galan-Mascaros, K. R. Dunbar, Angew. Chem. 2003, 115, 1561-1564;
27. Angew. Chem. Int. Ed. 2003, 42, 1523-1526;
28. f) J. J. Sokol, A. G. Hee, J. R. Long, J. Am. Chem. Soc. 2002, 124, 7656-7657;
29. g) A. J. Tsasiopoulos, A. Vinslava, W. Wernsdorfer, K. A. Abboud, G. Christou, Angew. Chem. 2004, 116, 2169-2173;
30. Angew. Chem. Int. Ed. 2004, 43, 2117-2121;
31. h) E. K. Brechin, E. C. Sanudo, W. Wernsdorfer, C. Boskovic, J. Yoo, D. N. Hendrickson, K. Yamaguchi, H. Ishimoto, T. E. Concolino, A. L. Rheingold, G. Christou, Inorg. Chem. 2005, 44, 502-511;
32. i) R. E. P. Winpenny, J. Chem. Soc. Dalton Trans. 2002, 1-10;
33. j) J. C. Goodwin, R. Sessoli, D. Gatleschi, W. Wernsdorfer, A. K. Powell, S. L. Heath, J. Chem. Soc. Dalton Trans. 2000, 1835-1840;
34. k) S. Maheswaran, G. Chastanet, S. J. Teal, T. Mallah, R. Sessoli, W. Wernsdorfer, R. E. P. Winpenny, Angew. Chem. 2005, 117, 5172-5176;
35. Angew. Chem. Int. Ed. 2005, 44, 5044-5048.
36. A. Bencini, D. Gatteschi, Electron Paramagnetic Resonance of Exchanged Coupled Systems, Springer, Berlin, 1990.
37. A. Bencini, I. Ciofini, M. G. Uytlerhoeven, Inorg. Chim. Acta 1998, 274, 90-101.
38. T. Glaser, M. Heidemeier, T. Lügger, Dalton Trans. 2003, 2381-2383.
39. a) T. Glaser, M. Gerenkamp, R. Fröhlich, Angew. Chem. 2002, 114, 3984-3986;
40. Angew. Chem. Int. Ed. 2002, 47, 3823-3825;
41. b) T. Glaser, M. Heidemeier, S. Grimme, E. Bill, Inorg. Chem. 2004, 43, 5192-5194.
42. V. A. Ung, A. Thompson, D. A. Bardwell, D. Gatteschi, J. C. Jeffery, J. A. McCleverty, F. Totti, M. D. Ward, Inorg. Chem. 1997, 36, 3447-3454.
43. B. J. Kennedy, K. S. Murray, Inorg. Chem. 1985, 24, 1552-1557.
44. W. Zhang, E. N. Jacobsen, J. Org. Chem. 1991, 56, 2296-2298.
45. a) K. A. Campbell, M. R. Lashley, J. K. Wyatt, M. H. Nantz, R. D. Britt, J. Am. Chem. Soc. 2001, 123, 5710-5719;
46. b) J. Krzystek, J. Telser, J. Magn. Reson. 2003, 162, 454-465.
47. H. Miyasaka, R. Clerac, W. Wernsdorfer, L. Leeren, C. Bonhomme, K.-i. Sugiura, M. Yamashita, Angew. Chem. 2004, 116, 2861-2865;
48. Angew. Chem. Int. Ed. 2004, 43, 2801-2805.
49. a) H. Miyasaka, N. Matsumolo, H. Okawa, N. Re, E. Gallo, C. Floriani, J. Am. Chem. Soc. 1996, 118, 981-994;
50. b) H. Miyasaka, N. Matsumoto, N. Re, E. Gallo, C. Floriani, Inorg. Chem. 1997, 36, 670-676;
51. c) N. Re, R. Crescenzi, C. Floriani, H. Miyasaka, N. Matsumoto, Inorg. Chem. 1998, 37, 2717-2722;
52. d) H. Miyasaka, H. Ieda, N. Matsumoto, N. Re, R. Crescenzi, C. Floriani, Inorg. Chem. 1998, 37, 255-263;
53. e) M. Clemente-Leon, E. Coronado, J. R. Galan-Mascaros, C. J. Gomez-Garcia, T. Woike, J. M. Clemente-Juan, Inorg. Chem. 2001, 40, 87-94;
54. f) L. M. C. Beltran, J. R. Long, Acc. Chem. Res. 2005, 38, 325-334.
55. W. Shen, B. Li, J. Zou, Z. Xu, Y. Yu, S. Liu, Transition Met. Chem. 2002, 27, 372-376.
56. H. J. Choi, J. J. Sokol, J. R. Long, Inorg. Chem. 2004, 43, 1606-1608.
57. T. Glaser, M. Heidemeier, R. Fröhlich, P. Hildebrandt, E. Bothe, E. Bill, Inorg. Chem. 2005, 44, 5467-5482.
58. -3. CCDC-292667 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
59. J.-J. Girerd, Y. Journaux in Physical Methods in Bioinorganic Chemistry (Ed.: L. Que, Jr.), University Science Books, Sausalito, CA, 2000, p. 335.
60. a) J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, B. S. Tsukerblat, Inorg. Chem. 1999, 38, 6081-6088;
61. b) J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, B. S. Tsukerblat, J. Comput. Chem. 2001, 22, 985-991.