Single-molecule magnets constructed from cyanometalates: {[Tp*Fe III(CN)3MII(DMF)4] 2[OTf]2}·2DMF (MII = Co, Ni)

Inorganic Chemistry

Volumn 44, Issue 14, 2005, Pages 4903-4905

  Li, Dongfeng ^a   Parkin, Sean ^a   Wang, Guangbin ^b   Yee, Gordon T ^b   Prosvirin, Andrey V ^c   Holmes, Stephen M ^a  

^a UNIVERSITY OF KENTUCKY   (United States)

^b VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

^c TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 22644435755     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic048367i     Document Type: Article

References (47)

1. (a) Entley, W. R.; Girolami, G. S. Science 1995, 268, 397-400.
2. (b) Verdaguer, M.; Bleuzen, A.; Marvaud, V.; Vaissermann, J.; Seuleiman, M.; Desplanches, C.; Scuiller, A.; Train, C.; Garde, R.; Gelly, G.; Lomenech, C.; Rosenman, I.; Veillet, P.; Cartier, C.; Villain, F. Coord. Chem. Rev. 1999, 190-192, 1023-1047.
3. (c) Dunbar, K. R.; Heintz, R. A. Prog. Inorg. Chem. 1997, 45, 283-291.
4. (a) Ferlay, S.; Mallah, T.; Ouahès, R.; Veillet, P.; Verdaguer, M. Nature 1995, 378, 701-703.
5. (b) Holmes, S. M.; Girolami, G. S. J. Am. Chem. Soc. 1999, 121, 5593-5594.
6. (c) Hatlevik, Ø.; Buschmann, W. E.; Zhang, J.; Manson, J. L.; Miller, J. S. Adv. Mater. 1999, 11, 914-918.
7. (a) Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Science 1996, 277, 49-51.
8. (b) Ohkoshi, S.-I.; Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. J. Am. Chem. Soc. 1998, 120, 5349-5350.
9. (a) Sato, O. Acc. Chem. Res. 2003, 36, 692-700 and references therein.
10. (b) Arimoto, Y.; Ohkoshi, S.; Zhong, Z. J.; Seino, H.; Mizobe, Y.; Hashimoto, K. J. Am. Chem. Soc. 2003, 125, 9240-9241.
11. (a) Sokol, J. J.; Hee, A. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 7656-7657.
12. (b) Choi, H. J.; Sokol, J. J.; Long, J. R. Inorg. Chem. 2004, 43, 1606-1608.
13. (c) Berlinguette, C. P.; Vaughn, D.; Cañada-Vilalta, C.; Galán-Mascarós, J. R.; Dunbar, K. R. Angew. Chem., Int. Ed. 2003, 42, 1523-1526.
14. (d) Wang, S.; Zou, J.-L.; Zhou, H.-C.; Choi, H. J.; Ke, Y.; Long, J. R.; You, X.-Z. Angew. Chem., Int. Ed. 2004, 43, 5940-5943.
15. (e) Schelter, E. J.; Prosvirin, A. V.; Dunbar, K. R. J. Am. Chem. Soc. 2004, 126, 15004-15005.
16. Berlinguette, C. P.; Dragulescu-Andrasi, A.; Sieber, A.; Galán-Mascarós, J. R.; Güdel, H.-U.; Achim, C.; Dunbar, K. R. J. Am. Chem. Soc. 2004, 126, 6222-6223.
17. (a) Ohkoshi, S.; Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Inorg. Chem. 1997, 36, 268-269.
18. (b) Ohkoshi, S.; Abe, Y.; Fujishima, A.; Hashimoto, K. Phys. Rev. Lett. 1999, 82, 1285-1288.
19. (a) Lescouzec, R.; Vaissermann, J.; Ruiz-Pérez, C.; Lloret, F.; Carrasco, R.; Julve, M.; Verdaguer, M.; Dromzee, Y.; Gatteschi, D.; Wernsdorfer, W. Angew. Chem., Int. Ed. 2003, 42, 1483-1486.
20. (b) Toma, L. M.; Lescouezec, R.; Lloret, F.; Vaissermann, J.; Verdaguer, M. Chem. Commun. 2003, 1850-1851.
21. (c) Wang, S.; Zuo, J.-L.; Gao, S.; Song, Y.; Zhou, H.-C.; Zhang, Y.-Z.; You, X.-Z. J. Am. Chem. Soc. 2004, 126, 8900-8901.
22. (a) Yang, J. Y.; Shores, M. P.; Sokol, J. J.; Long, J. R. Inorg. Chem. 2003, 42, 1403-1419.
23. (b) Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279-2292.
24. (c) Sokol, J. J.; Shores, M. P.; Long, J. R. Angew. Chem., Int. Ed. 2001, 40, 236-239.
25. (d) Heinrich, J. L.; Berseth, P. A.; Long, J. R. Chem. Commun. 1998, 1231-1232.
26. (e) Schelter, E. J.; Prosvirin, A. V.; Reiff, W. M.; Dunbar, K. R. Angew. Chem., Int. Ed. 2004, 43, 4912-4915.
27. (f) Klausmeyer, K. K.; Wilson, S. R.; Rauchfuss, T. B. J. Am. Chem. Soc. 1999, 121, 2705-2711.
28. (g) Contakes, S. M.; Kuhlman, M. L.; Ramesh, M.; Wilson, S. R.; Rauchfuss, T. B. Proc. Natl. Acad. Sci. 2002, 99, 4889-4893.
29. (a) Kim, J.; Han, S.; Cho, I.-K.; Choi, K. Y.; Heu, M.; Yoon, S.; Suh, B. J. Polyhedron 2004, 23, 1333-1339.
30. (b) Lescouezec, R.; Vaissermann, J.; Lloret, F.; Julve, M.; Verdaguer, M. Inorg. Chem. 2002, 41, 5943-5945.
31. (a) Carlin, R. L. Magnetochemistry; Springer-Verlag: New York, 1986.
32. (b) Caneschi, A.; Gatteschi, D.; Lalioti, N.; Sangregorio, C.; Sessoli, R.; Venturi, A.; Vindigni, A.; Rettori, A.; Pini, M. G.; Novak, M. A. Angew. Chem., Int. Ed. 2001, 40, 1760-1763.
33. (c) Clérac, R.; Miyasaka, H.; Yamashita, M.; Coulon, C. J. Am. Chem. Soc. 2002, 124, 12837-12844.
34. (d) Gatteschi, D.; Sessoli, R. Angew. Chem., Int. Ed. 2003, 42, 268-297 and references therein,
35. (e) Kahn, O. Molecular Magnetism; VCH Publishers: New York, 1993.
36. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; Wiley: New York, 1997; Part B, pp 54-58 and 105-116.
37. 3, R1 = 0.0636, wR2 = 0.1740. All data were collected on a Nonius Kappa CCD diffractometer at 90.0(2) K using Mo Kα (λ = 0.710 73 Å) radiation. Structures were solved by direct methods and refined against all data using SHELXL 97.
38. Figgis, B. N.; Gerloch, M.; Mason, R. Proc. R. Soc. London A 1969, 309, 91-118.
39. Smith, J. A.; Galán-Mascarós, J.-R.; Clérac, R.; Dunbar, K. R. Chem. Commun. 2000, 1077-1078.
40. Sato, O.; Einaga, Y.; Fujishima, A.; Hashimoto, K. J. Am. Chem. Soc. 1999, 38, 4405-4412.
41. Zhang, S.-W.; Fu, D.-G.; Sun, W.-Y.; Hu, Z.; Yu, K.-B.; Tang, W.-X. Inorg. Chem. 2000, 39, 1142-1146.
42. See the Supporting Information.
43. Chakov, N. E.; Wernsdorfer, W.; Abboud, K. A.; Christou, G. Inorg. Chem. 2004, 43, 5919-5930.
44. Shores, M. P.; Sokol, J. J.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 2279-2292.
45. (a) Borras-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Tsukerblat, B. S. J. Comput. Chem. 2001, 22, 985-991.
46. (b) Borras-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Tsukerblat, B. S. Inorg. Chem. 1999, 38, 6081-6088.
47. Rogez, G.; Rebilly, J.-N.; Barra, A.-L.; Sorace, L.; Blondin, G.; Kirchner, N.; Duran, M.; Slageren, J.; Parsons, S.; Ricard, L.; Marvilliers, A.; Mallah, T. Angew. Chem., Int. Ed. 2005, 44, 1876-1879 and references therein.