Efficient catalytic decomposition of formic acid for the selective generation of H2 and H/D exchange with a water-soluble rhodium complex in aqueous solution

ChemSusChem

Volumn 1, Issue 10, 2008, Pages 827-834

  Fukuzumi, Shunichi ^a   Kobayashi, Takeshi ^a   Suenobu, Tomoyoshi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Formic acid; Homogeneous catalysis; Hydrogen; Isotope effects; Rhodium

Indexed keywords

CARBON DIOXIDE; CARRIER MOBILITY; DEUTERIUM; FORMIC ACID; HYDROGEN; REACTION KINETICS; RHODIUM; SOLUTIONS;

2 ,2'-BIPYRIDINE; ACTIVE SPECIES; AQUA COMPLEXES; CATALYTIC AMOUNTS; CATALYTIC DECOMPOSITION; DECOMPOSITION RATE; DEUTERIUM KINETIC ISOTOPE EFFECT; H/D EXCHANGE; HOMOGENEOUS CATALYSIS; ISOTOPE EFFECT; MAXIMUM VALUES; PENTAMETHYLCYCLOPENTADIENYL; SELECTIVE DECOMPOSITION; SELECTIVE GENERATION; WATER-SOLUBLE RHODIUM COMPLEX; WATERSOLUBLE;

RHODIUM COMPOUNDS;

(2,2' BIPYRIDYL)(PENTAMETHYLCYCLOPENTADIENYL)RHODIUM; (2,2'-BIPYRIDYL)(PENTAMETHYLCYCLOPENTADIENYL)RHODIUM; DEUTERIUM; FORMIC ACID; FORMIC ACID DERIVATIVE; HYDROGEN; ORGANOMETALLIC COMPOUND; RHODIUM; UNCLASSIFIED DRUG; WATER;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; SOLUBILITY;

CATALYSIS; DEUTERIUM; FORMIC ACIDS; HYDROGEN; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; RHODIUM; SOLUBILITY; WATER;

EID: 58149150086     PISSN: 18645631     EISSN: 1864564X     Source Type: Journal    
DOI: 10.1002/cssc.200800147     Document Type: Article

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