A viable hydrogen-storage system based on selective formic acid decomposition with a ruthenium catalyst

Angewandte Chemie - International Edition

Volumn 47, Issue 21, 2008, Pages 3966-3968

  Fellay, Céline ^a   Dyson, Paul J ^a   Laurenczy, Gábor ^a  

^a EPFL   (Switzerland)

Author keywords

Formic acid; Homogeneous catalysis; Hydrogen storage; Ruthenium

Indexed keywords

ACIDS; CHEMICAL REACTIONS; HYDROGEN; HYDROGEN STORAGE; ORGANIC ACIDS; RUTHENIUM; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

ACID DECOMPOSITION; CATALYTIC SYSTEMS; CHEMICAL EQUATIONS; HOMOGENEOUS CATALYSIS; RUTHENIUM CATALYSTS; STORAGE SYSTEMS; TRIPHENYL PHOSPHINES; WATER-SOLUBLE COMPLEXES;

FORMIC ACID;

CARBON DIOXIDE; FORMIC ACID; FORMIC ACID DERIVATIVE; HYDROGEN; ORGANOMETALLIC COMPOUND; OXYGEN; RUTHENIUM; WATER;

ARTICLE; CATALYSIS; CHEMISTRY; PRESSURE; SOLUTION AND SOLUBILITY; SYNTHESIS; TEMPERATURE; TIME;

CARBON DIOXIDE; CATALYSIS; FORMIC ACIDS; HYDROGEN; ORGANOMETALLIC COMPOUNDS; OXYGEN; PRESSURE; RUTHENIUM; SOLUTIONS; TEMPERATURE; TIME FACTORS; WATER;

EID: 47049083045     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200800320     Document Type: Article

References (35)

1. B. C. H. Steele, A. Heinzel, Nature 2001, 414, 345.
2. L. Schlapbach, A. Züttel, Nature 2001, 414, 353.
3. a) Y. Filinchuk, D. Chernyshov, A. Nevidomskyy, V. Dmitriev, Angew. Chem. Int. Ed. 2008, 47, 529;
4. b) F. Schüth, B. Bogdanović, M. Felderhoff, Chem. Commun. 2004, 2249.
5. a) C. Liu, H.-M. Cheng, J. Phys. D 2005, 38, R231;
6. b) U. Bünger, W. Zittel, Appl. Phys. A 2001, 72, 147.
7. a) R. S. Paonessa, W. C. Trogler, J. Am. Chem. Soc. 1982, 104, 3529;
8. b) Y. Gao, J. K. Kuncheria, H. A. Jenkins, R. J. Puddephatt, G. P. A. Yap, J. Chem. Soc. Dalton Trans. 2000, 3212;
9. c) S. Ogo, H. Nishida, H. Hayashi, Y. Murata, S. Fukuzumi, Organometallics 2005, 24, 4816.
10. a) M. Emelock, US Patent 4597363, 1986;
11. b) P. D. Hopkins, X. D. Hu, S. Zhao, D. Shobe, WO 2006/127775, 2006.
12. a) J. R. Hyde, M. Poliakoff, Chem. Commun. 2004, 1482;
13. b) E. Garcia-Verdugo, Z. Liu, E. Ramirez, J. Garcia-Serna, J. Fraga-Dubreuil, J. R. Hyde, P. A. Hamley, M. Poliakoff, Green Chem. 2006, 8, 359.
14. a) R. Williams, R. S. Crandall, A. Bloom, Appl. Phys. Lett. 1978, 33, 381;
15. b) B. Zaidman. H. Wiener, Y. Sasson, Int. J. Hydrogen Energy 1986, 11, 341;
16. c) H. Wiener, Y. Sasson, J. Blum, J. Mol. Catal. 1986, 35, 277;
17. d) H. Wiener, S. Vandel, Y. Sasson, US Patent 4792625, 1988.
18. C. Fellay, P. J. Dyson, G. Laurenczy, European patent application filed, 2006.
19. I. Jószai, F. Joó, J. Mol. Catal. A 2004, 224, 87.
20. C. Wakai, K. Yoshida, Y. Tsujino, N. Matubayasi, M. Nakahara, Chem. Lett. 2004, 33, 572.
21. a) H. A. Gasteiger, N. Markovic, P. N. Ross, E. J. Caims, J. Phys. Chem. 1994, 98, 617;
22. b) F. J. Scott, C. Roth, D. E. Ramaker, J. Phys. Chem. C 2007, 111, 11403.
23. a) G. Negre, C. Negre, WO 2005/049968, 2005;
24. b) G. Negre, C. Negre, WO 2006/136728, 2006.
25. K. Weissermel, H.-J. Arpe, Industrial Organic Chemistry, VCH, Weinheim, 1997, p. 40.
26. P. G. Jessop, Handbook of Homogeneous Hydrogenation, Vol. 1 (Eds.: J. G. de Vries, C. J. Elsevier), Wiley-VCH, Weinheim, 2007, p. 489.
27. E. R. Keene, B. P. Sullivan, Electrochemical and Electrocatalytic Reactions of Carbon Dioxide (Eds.: B. P. Sullivan, K. Krist. H. E. Guard), Elsvier, Amsterdam, 1993, p. 118.
28. a) G. Laurenczy, F. Joó, L. Nádasdi, Inorg. Chem. 2000, 39, 5083;
29. b) Y. Himeda, Eur. J. Inorg. Chem. 2007, 3927.
30. a) P. G. Jessop, T. Ikariya, R. Noyori, Nature 1994, 368, 231;
31. b) P. G. Jessop, Y. Hsiao, T. Ikariya, R. Noyori, J. Am. Chem. Soc. 1996, 118, 344;
32. c) P. Munshi, A. D. Main, J. C. Linehan, C.-C. Tai, P. G. Jessop, J. Am. Chem. Soc. 2002, 124, 7963.
33. K. R. Jang, J. H. Kim, J. G. Shim, Y. M. Ahn, H. M. Eum, Carbon Dioxide Utilization For Global Sustainability, Vol. 153 (Eds.: S.-E. Park, J.-S. Chang, K.-W Lee), Elsevier, Amsterdam, 2004, p. 397.
34. P. Bernhard, M. Biner, A. Ludi, Polyhedron 1990, 9, 1095.
35. A. Cusanelli, U. Frey, D. T. Richens, A. E. Merbach, J. Am. Chem. Soc. 1996, 118, 5265.