메뉴 건너뛰기




Volumn 23, Issue 7, 2004, Pages 1480-1483

Half-sandwich complexes with 4,7-dihydroxy-1,10-phenanthroline: Water-soluble, highly efficient catalysts for hydrogenation of bicarbonate attributable to the generation of an oxyanion on the catalyst ligand

Author keywords

[No Author keywords available]

Indexed keywords

ADDITIVES; AMINES; CATALYSIS; CATALYSTS; COMPLEXATION; HYDROGENATION; IRIDIUM COMPOUNDS; RHODIUM COMPOUNDS; RUTHENIUM COMPOUNDS; SOLUBILITY; SOLUTIONS;

EID: 1842741026     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030382s     Document Type: Article
Times cited : (139)

References (34)
  • 1
    • 85085784197 scopus 로고    scopus 로고
    • Song, C., Gaffney, A. F., Fujimoto, K., Eds.; ACS Symposium Series 809; American Chemical Society: Washington, DC
    • 2 Conversion and Utilization; ACS Symposium Series 809; American Chemical Society: Washington, DC, 2001.
    • (2001) 2 Conversion and Utilization
  • 13
    • 85085783794 scopus 로고    scopus 로고
    • note
    • 3 as an initial reaction solution led to results similar to those in aqueous KOH.
  • 17
    • 85085784869 scopus 로고    scopus 로고
    • note
    • 3 at 25°C) but is slightly soluble under acidic conditions. In contrast, the water solubility of the unsubstituted bipyridine complex [Cp*Ir(bpy)Cl]Cl is pH independent and high (over 200 mg/mL in aqueous solution at 25°C).
  • 24
    • 4243664295 scopus 로고
    • Although the redox potential of the oxyanion complexes 2b,c could not be detected in cyclic voltammograms in DMF, the Hammett substituent constant of the oxyanion is known: Hansch, C.; Leo, A.; Taft, R. W. Chem. Rev. 1991, 91, 165-195.
    • (1991) Chem. Rev. , vol.91 , pp. 165-195
    • Hansch, C.1    Leo, A.2    Taft, R.W.3
  • 32
    • 0031013608 scopus 로고    scopus 로고
    • For example, an oxyanion-accerelated, palladium-mediated intromolecular coupling reaction in dimethylacetamide was reported: Hennings, D. D.; Iwasa, S.; Rawal, V. H. J. Org. Chem. 1997, 62, 2-3.
    • (1997) J. Org. Chem. , vol.62 , pp. 2-3
    • Hennings, D.D.1    Iwasa, S.2    Rawal, V.H.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.