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Volumn 42, Issue 44, 2003, Pages 5492-5495

Excited-State Deprotonation and H/D Exchange of an Iridium Hydride Complex

Author keywords

Hydrides; Iridium; Isotope effects; Kinetics; Photochemistry

Indexed keywords

IRIDIUM COMPOUNDS; IRRADIATION; METHANOL; PHOSPHATES;

EID: 0344413479     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352061     Document Type: Article
Times cited : (38)

References (45)
  • 33
    • 0344181952 scopus 로고    scopus 로고
    • note
    • 3OD.
  • 38
    • 0345475884 scopus 로고    scopus 로고
    • note
    • 1]-1*.
  • 39
    • 0345475856 scopus 로고    scopus 로고
    • note
    • D) on the rate of deprotonation of 1* is significantly smaller than that observed in the protonation process of 2.
  • 40
    • 0344181982 scopus 로고    scopus 로고
    • note
    • 2H NMR.
  • 41
    • 0345044494 scopus 로고    scopus 로고
    • note
    • 2O (Figure 3 c and d).
  • 43
    • 0345044493 scopus 로고    scopus 로고
    • note
    • The DFT calculations of 2 indicate that the HOMO orbital is more metal-centered (24%) than the LUMO orbital (21%). However, this is not a genuine MLCT example and there exists considerable orbital mixing between the metal and ligand orbitals.[14]
  • 44
    • 0000535345 scopus 로고
    • Alternatively photoinduced opening of a coordination site followed by binding of methanol may result in intramolecular H/D exchange. Such intramolecular H/D exchange in an Ir-H complex has previously been reported, see: R. Koelliker, D. Milstein, J. Am. Chem. Soc. 1991, 113, 8524.
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 8524
    • Koelliker, R.1    Milstein, D.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.