Kinetics and mechanism for the reaction of hexafluoroacetylacetone with CuO in supercritical carbon dioxide

Journal of the American Chemical Society

Volumn 130, Issue 49, 2008, Pages 16659-16668

  Durando, Michael ^a   Morrish, Rachel ^a   Muscat, Anthony J ^a  

^a University of Arizona   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; ADSORPTION; CARBON DIOXIDE; CARBON FILMS; CARBON MONOXIDE; COPPER OXIDES; EFFLUENT TREATMENT; ETCHING; HYDROGEN; INDUSTRIAL WASTE TREATMENT; MODEL STRUCTURES; PHOTOELECTRON SPECTROSCOPY; REACTION KINETICS; REACTION RATES; SUPERCRITICAL FLUID EXTRACTION; SUPERCRITICAL FLUIDS; X RAY PHOTOELECTRON SPECTROSCOPY;

APPARENT ACTIVATION ENERGIES; ETCHING RATES; ETCHING REACTIONS; FIRST ORDERS; HETEROGENEOUS REACTIONS; IN CONCENTRATIONS; KINETIC MODELS; KINETICS AND MECHANISMS; LANGMUIR; LOW CONCENTRATIONS; MATERIAL REMOVALS; MODEL SYSTEMS; NANOSCALE STRUCTURES; PHASE PROCESSES; PRECISE CONTROLS; REACTION BEHAVIORS; REACTION CONDITIONS; SOLVATION FORCES; SUPERCRITICAL CARBON DIOXIDES; SUPERCRITICAL CO; TO SWITCHES; X-RAY PHOTOELECTRON SPECTROSCOPIES;

RATE CONSTANTS;

ACETONE; CARBON DIOXIDE; COPPER OXIDE; HEXAFLUOROACETYLACETONE; UNCLASSIFIED DRUG;

ADSORPTION; ARTICLE; CHELATION; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; FILM; HYDROGEN BOND; MODEL; REACTION ANALYSIS; SCANNING ELECTRON MICROSCOPY; SOLVATION; SURFACE PROPERTY; TEMPERATURE SENSITIVITY; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 57549087915     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8050662     Document Type: Article

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