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3] and 106 (Pd).
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8944230206
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5/2 peak remains essentially unchanged, the peak at 533.3 eV completely disappears.
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The satellite peak with the highest binding energy is due to a simultaneous 3d to 4p transition occurring during the photoionization process; the satellite peak with the smaller energy shift can be explained by a simultaneous 3d to ligand transition. Cotton, F. A.; Harris, C. B.; Wise, J. J. Inorg. Chem. 1967, 6, 909-915.
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8944226592
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2 desorbs from carbonaceous copper surfaces.
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47
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33845183292
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and references therein
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0000241957
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There is little doubt that surface structures present on the polycrystal must be more diverse and complex than those found on a high-quality Cu-(111) single crystal. It is for this reason that the simple pattern of coincident peaks seen in Figure 8 is so perplexing. Such behavior could be rationalized if other features, such as diffusion to or trapping at strong bonding sites, dominated the adsorbate decomposition kinetics. This type of dynamical effect must be important at some level in the decomposition processes but to what extent it is expressed in the observed kinetics is unclear. We can offer little more here than to point out that "intuitive notions" of rate-structure sensitivities in heterogeneous reaction kinetics can be very misleading. An excellent discussion of the influence of surface heterogeneity in adsorption/desorption kinetics can be found in: Serri, J. A.; Tully, J. C.; Cardillo, M. J. J. Chem. Phys. 1983, 79, 1530-1536.
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II species on the surface as judged by XPS studies.
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