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Certain equipment, instruments or materials are identified in this paper in order to adequately specify the experimental details. Such identification does not imply recommendation by the National Institute of Standards and Technology nor does it imply the materials are necessarily the best available for the purpose
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Certain equipment, instruments or materials are identified in this paper in order to adequately specify the experimental details. Such identification does not imply recommendation by the National Institute of Standards and Technology nor does it imply the materials are necessarily the best available for the purpose.
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A well-known example for order-order transitions induced by the addition of a homopolymer that exhibits selective favorable interactions with one segment of a diblock copolymer is the addition of poly(phenylene oxide) to Kraton polymers T. Hashimoto, K. Kimishima, H. Hasegawa, Macromolecules 1991, 24, 5704
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or the addition of poly(vinyl chloride) or a random copolymer of styrene-acrylonitrile to PS-PMMA
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The scattering prolile in absolute intcnsily units is fit to a Gaussian functional form to determine the full-width at half-maximum (FWHM) and intensity of the primary scattering peak. The functional form used is Iabs, Iincoh+ A* exp, q-qpeak/2σ)2; where Iincoh is the incoherent scattering intensity. A is the intensity prefactor, Iabs, qpeak and σ are the reported absolute intensity, peak position, and FWHM values, respectively
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peak and σ are the reported absolute intensity, peak position, and FWHM values, respectively.
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PA A is known to form cyclic polyanhydrides when heated to 150°C due to crosslinking. But crosslinking the disordered block copolymer melts to below the gel point stabilizes the ordered morphology as shown recently by Balsara and coworkers. E. D. Gomez, J. Das, A. K. Chakraborty. J. A. Pople, N. P. Balsara, Macromolecules 2006, 39, 4848.
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PA A is known to form cyclic polyanhydrides when heated to 150°C due to crosslinking. But crosslinking the disordered block copolymer melts to below the "gel point" stabilizes the ordered morphology as shown recently by Balsara and coworkers. E. D. Gomez, J. Das, A. K. Chakraborty. J. A. Pople, N. P. Balsara, Macromolecules 2006, 39, 4848.
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X-ray reflectivity measurements on blend thin films show that (i) the PAA/P123 blends undergo a cylindrical-to-lamellae transition between 26.5 to 28.5% PAA by mass, and (ii) PAA/P105 blends undergo a lamellae-to-cylindrical transition when PAMPS instead of PAA is added at 20% by mass. The observed order-order transitions are driven more by an increase in the effective interaction parameter, Χ(homopolymer/EO-)-PO, than from a simple increase in the effective chain length, Nhomopolymer + EO.
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X-ray reflectivity measurements on blend thin films show that (i) the PAA/P123 blends undergo a cylindrical-to-lamellae transition between 26.5 to 28.5% PAA by mass, and (ii) PAA/P105 blends undergo a lamellae-to-cylindrical transition when PAMPS instead of PAA is added at 20% by mass. The observed order-order transitions are driven more by an increase in the effective interaction parameter, Χ(homopolymer/EO-)-PO, than from a simple increase in the effective chain length, Nhomopolymer + EO.
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The uncertainty associated with determining the peak position and full-width at half-maximum obtained from the X-ray and neutron scattering data is smaller than the size of the markers used, unless explicitly represented by error bars
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The uncertainty associated with determining the peak position and full-width at half-maximum obtained from the X-ray and neutron scattering data is smaller than the size of the markers used, unless explicitly represented by error bars.
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