Coordination features of a hybrid scorpionate/phosphane ligand exemplified with iridium

Chemistry - A European Journal

Volumn 14, Issue 6, 2008, Pages 1897-1905

  Camerano, José A ^a   Casado, Miguel A ^a,b   Ciriano, Miguel A ^a   Tejel, Cristina ^a   Oro, Luis A ^a,b  

^a UNIVERSITY OF ZARAGOZA   (Spain)

^b CSIC UZA Instituto de Sintesis Quimica y Catalisis Homogenea ISQCH   (Spain)

Author keywords

Iridium; N,P ligands; Protonation; Scorpionate ligands; Tripodal ligands

Indexed keywords

COORDINATION REACTIONS; IRIDIUM COMPOUNDS;

N,P LIGANDS; PROTONATION; SCORPIONATE LIGANDS; TRIPODAL LIGANDS;

IRIDIUM;

EID: 53849140119     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200701209     Document Type: Article

References (41)

1. S. Trofimenko, J. Am. Chem. Soc. 1966, 88, 1842-1844.
2. S. Trofimenko, Scorpionates: The Coordination Chemistry of Poly-pyrazolylborate Ligands, Imperial College Press, London, 1999.
3. S. Trofimenko, Chem. Rev. 1993, 93, 943-980.
4. 0-coordination modes of Tp systems have been reported recently, see: M. Paneque, S. Sirol, M. Trujillo, E. Carmona, E. Gutierrez-Puebla, M. A. Monge, C. Ruiz, F. Malbosc, C. SerraLe Berre, P. Kalck, M. Etienne, Chem. Eur. J. 2001, 7, 3868-3879.
5. a) D. M. Tellers, R. G. Bergman, J. Am. Chem. Soc. 2000, 122, 954-955;
6. b) D. M. Tellers, R. G. Bergman. Organometallics 2001, 20, 4819-4832;
7. c) D. M. Tellers, S. J. Skoog, R. G. Bergman, T. B. Gunnoe, W. D. Harman, Organometallics 2000, 19, 2428-2432;
8. d) N. Kitajima, W. B. Tolman, Prog. Inorg. Chem. 1995, 43, 419-531;
9. e) J. L. Koch, P. A. Shapley, Organometallics 1997, 16, 4071-4076;
10. f) E. Gutierrez-Puebla, A. Monge, M. C. Nicasio, P. J. Perez, M. L. Poveda, L. Rey, C. Ruiz, E. Carmona, Inorg. Chem. 1998, 37, 4538-4546;
11. g) E. Gutierrez-Puebla, A. Monge, M. Paneque, M. L. Poveda, S. Taboada, M. Trujillo, E. Carmona, J. Am. Chem. Soc. 1999, 121, 346-354.
12. a) J. D. Feldman, J. C. Peters, T. D. Tilley, Organometallics 2002, 21, 4050-4064;
13. b) D. Feldman, J. C. Peters, T. D. Tilley, Organometallics 2002, 21, 4065-4075;
14. c) C. C. Lu, C. T. Saouman, M. W. Day, J. C. Peters, J. Am. Chem. Soc. 2007, 129, 4-5;
15. d) C. M. Thomas, J. C. Peters, Angew. Chem. 2006, 118, 790-794;
16. Angew. Chem. Int. Ed. 2006, 45, 776-780;
17. e) S. D. Brown, M. P. Mehn, J. C. Peters, J. Am. Chem. Soc. 2005, 127, 13146-13147;
18. f) L. Turculet, J. D. Feldman, T. D. Tilley, Organometallics 2004, 23, 2488-2502;
19. g) J. C. Peters, J. D. Feldman, T. D. Tilley, J. Am. Chem. Soc. 1999, 121, 9871-9872.
20. K. Niedenzu, S. Trofimenko. Inorg. Chem. 1985, 24, 4222-4223.
21. J. S. Thompson, J. L. Zitzmann, T. J. Marks, J. A. Ibers, Inorg. Chim. Acta 1980, 46, L101-L105.
22. P. Ghosh, G. Parkin, Chem. Commun. 1998, 413-414.
23. M. A. Casado, V. Hack, J. A. Camerano, M. A. Ciriano, C. Tejel, L. A. Oro, lnorg. Chem. 2005, 44, 9122-9124.
24. a) S. Trofimenko, Polyhedron 2004, 23, 197-203;
25. b) a boron-based system that has one pyrazoyl arm and two phosphane groups has been reported recently, see: C. M. Thomas, N. P. Mankad, J. C. Peters, J. Am. Chem. Soc. 2006, 128, 4956-4957.
26. A. Albinati, M. Bovens, H. Rtiegger, L. M. Venanzi, Inorg. Chem. 1997, 36, 5991-5999.
27. D. M. Heinekey, D. A. Fine, D. Barnhart, Organometallics 1997, 16, 2530-2538.
28. T. E. Bitterwolf, G. Valle, Organometallics 1991, 10, 1416-1420.
29. T. Makino, Y. Yamamoto, K. Iloh, Organometallics 2004, 23, 1730-1737.
30. F. E. Hahn, C. Hollgrewe, T. Pape, M. Martin, E. Sola, L. A. Oro, Organometallics 2005, 24, 2203-2209.
31. I. I. Padilla-Martínez, M. L. Povìda, E. Carmona, M. A. Monge, C. Ruiz-Valero, Organometallics 2002, 21, 93-104.
32. S. Marcén, M. V. Jiménez, I. T. Dobrinovich, F. J. Lahoz, L. A. Oro, Organometallics 2002, 21, 326-330.
33. R. G. Ball, C. K. Ghosh, J. K. Hoyano, A. D. McMaster, W. A. G. Graham, J. Chem. Soc., Chem. Commun. 1989, 341-342.
34. a) C. Tejel, M. A. Ciriano, M. Millaruelo, J. A. López, F. J. Lahoz, L. A. Oro, Inorg. Chem. 2003, 42, 4750-4758;
35. b) H. C. Lo, M. A. Iron, J. M. L. Martin, E. Keinan, Chem. Eur. J. 2007, 13, 2812-2823.
36. a) J. R. Bleeke, R. Behm, J. Am. Chem. Soc. 1997, 119, 8503-8511;
37. b) M. Paneque, M. L. Poveda, L. L. Santos, E. Carmona, A. Lledós, G. Ujaque, K. Mereiter, Angew. Chem. 2004, 116, 3794-3797;
38. Angew. Chem. Int. Ed. 2004, 43, 3708-3711.
39. G. M. Sheldrick, SADABS, Bruker AXS, Madison. WI (USA), 1997.
40. G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Gòttingen (Germany), 1997.
41. L. J. Farrugia, J. Appl. Crystallogr. 1999, 32, 837-838.