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C-H = 180 Hz)
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C-H = 180 Hz).
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Support for this hypothesis obtained by utilizing the Tp ligand will be published separately.
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The desire to maintain an octahedral geometry has been used to explain why TpM complexes form nonclassical dihydrogen structures whereas the corresponding Cp* complexes will go seven-coordinate and form classical dihydride structures. See the two references immediately following this one.
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