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Volumn 20, Issue 23, 2001, Pages 4819-4832

An examination of C-H bond activation by cationic TpMe2Ir(III) complexes

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC EFFECT; HYDRIDOTRISDIMETHYLPYRAZOLYLBORATE; LIGAND; SATURATED HYDROCARBON; STERIC EFFECT;

EID: 0035851946     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010697c     Document Type: Article
Times cited : (68)

References (104)
  • 5
  • 23
    • 0011402831 scopus 로고    scopus 로고
    • C-H = 180 Hz)
    • C-H = 180 Hz).
  • 30
    • 0011403347 scopus 로고    scopus 로고
    • See Experimental Section for details
    • See Experimental Section for details.
  • 33
    • 0011403464 scopus 로고    scopus 로고
    • note
    • 2, this complex is thermally sensitive, preventing its isolation.
  • 34
    • 0011463511 scopus 로고    scopus 로고
    • note
    • For examples of TpMo and TpW aldehyde complexes, see refs 36 and 37.
  • 37
    • 0011447122 scopus 로고    scopus 로고
    • note
    • For a discussion of characterization and bonding modes of transition metal-aldehyde complexes, see refs 39-42.
  • 45
    • 0011447123 scopus 로고    scopus 로고
    • note
    • 4 at 75 °C along with decomposition
  • 46
    • 0011447792 scopus 로고    scopus 로고
    • note
    • An extensive amount of work has recently appeared on C-H activation by cationic late transition metals. See refs 48-53.
  • 54
    • 0011400764 scopus 로고    scopus 로고
    • note
    • Support for dissociative loss of the triflate ligand can be found in ref 56.
  • 71
    • 0011403349 scopus 로고    scopus 로고
    • note
    • Please see refs 27-29 and 73-81 for other iridium dinitrogen complexes.
  • 82
    • 0011495593 scopus 로고    scopus 로고
    • note
    • Support for this hypothesis obtained by utilizing the Tp ligand will be published separately.
  • 84
    • 0011445678 scopus 로고    scopus 로고
    • note
    • 2)H.
  • 91
    • 0011448533 scopus 로고    scopus 로고
    • note
    • The desire to maintain an octahedral geometry has been used to explain why TpM complexes form nonclassical dihydrogen structures whereas the corresponding Cp* complexes will go seven-coordinate and form classical dihydride structures. See the two references immediately following this one.
  • 100
    • 0003900489 scopus 로고
    • Siemens Industrial Automation, Inc.: Madison, WI
    • SMART Area-Detector Software Package; Siemens Industrial Automation, Inc.: Madison, WI, 1995.
    • (1995) SMART Area-Detector Software Package
  • 102
    • 0009206476 scopus 로고
    • Part of the SHELXTL Crystal Structure Determination Package; Siemens Industrial Automation, Inc.: Madison, WI
    • XPREP (v 5.03), Part of the SHELXTL Crystal Structure Determination Package; Siemens Industrial Automation, Inc.: Madison, WI, 1995.
    • (1995) XPREP (v 5.03)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.