Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers

Inorganic Chemistry

Volumn 44, Issue 25, 2005, Pages 9122-9124

  Casado, Miguel A ^a,b   Hack, Verena ^a   Camerano, José A ^a   Ciriano, Miguel A ^a   Tejel, Cristina ^a   Orot, Luis A ^a,b  

^a UNIVERSITY OF ZARAGOZA   (Spain)

^b CSIC UZA Instituto de Sintesis Quimica y Catalisis Homogenea ISQCH   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ANION; CARBOSILANE; DENDRIMER; IRIDIUM; LIGAND; ORGANOMETALLIC COMPOUND; ORGANOPHOSPHORUS COMPOUND; PHOSPHINE DERIVATIVE; PYRAZOLE DERIVATIVE; RHODIUM; SILANE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; SYNTHESIS; X RAY DIFFRACTION;

ANIONS; DENDRIMERS; IRIDIUM; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; ORGANOPHOSPHORUS COMPOUNDS; PHOSPHINES; PYRAZOLES; RHODIUM; SILANES; X-RAY DIFFRACTION;

EID: 29544439856     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic051279t     Document Type: Article

References (32)

1. Trofimenko, S. Scorpionates: The Coordination Chemistry of Polypyrazolylborate Ligands; Imperial College Press: London, 1999.
2. (a) Trofimenko, S. Chem. Rev. 1993, 93, 943.
3. (b) Trofimenko, S. Polyhedron 2004, 23, 197.
4. For example, see: (a) Paneque, M.; Poveda, M. L.; Rendón, N.; Mereiter, K. J. Am. Chem. Soc. 2004, 126, 1610.
5. (b) Álvarez, E.; Gómez, M.; Paneque, M.; Posadas, C. M.; Poveda, M. L.; Rendón, N.; Santos, L. L.; Rojas-Lima, S.; Salazar, V.; Mereiter, K.; Ruiz, C. J. Am. Chem. Soc. 2003, 125, 1478.
6. (c) Wiley, J. S.; Heinekey, D. M. Inorg. Chem. 2002, 41, 4961.
7. (d) Slugov, C.; Padilla-Martinez, I.; Sirol, S.; Carmona, E. Coord. Chem. Rev. 2001, 213, 129.
8. (a) Trzeciak, A. M.; Ziólkowski, J. J. Appl. Organomet. Chem. 2004, 18, 124.
9. (b) Morilla, M. E.; Molina, M. J.; Díaz-Requejo, M. M.; Belderraín, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. Organometallics 2003, 22, 2914.
10. (c) Díaz-Requejo, M. M.; Belderraín, T. R.; Nicasio, M. C.; Trofimenko, S.; Pérez, P. J. J. Am. Chem. Soc. 2003, 125, 12078.
11. (d) Murtuza, S.; Casagrande, O. L., Jr.; Jordan, R. F. Organometallics 2002, 21, 1882.
12. (e) Lail, M.; Bell, C. M.; Conner, D.; Cundari, T. R.; Gunnoe, T. B.; Petersen, J. L. Organometallics 2004, 23, 5007.
13. (f) Lail, M.; Arrowood, B. N.; Gunnoe, T. B. J. Am. Chem. Soc. 2003, 125, 7506.
14. (a) Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871.
15. (b) Turculet, L.; Feldman, J. D.; Tilley, T. D. Organometallics 2004, 23, 2488.
16. (c) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4050.
17. Otero, A.; Fernández-Baeza, J.; Antiñolo, A.; Tejeda, J.; Lara-Sánchez, A.; Sánchez-Barba, L.; Rodríguez, A. M.; Maestro, M. A. J. Am. Chem. Soc. 2004, 126, 1330.
18. Niedenzu, K.; Trofimenko, S. Inorg. Chem. 1985, 24, 4222.
19. Thompson, J. S.; Zitzmann, J. L.; Marks, T. J.; Ibers, J. A. Inorg. Chim. Acta 1980, 46, L101.
20. Ghosh, P.; Parkin, G. Chem. Commun. 1998, 413.
21. 6P: C, 66.15; H, 7.73; N, 16.53. Found: C, 66.05; H, 7.85; N, 16.49.
22. 4P: C, 52.55; H, 5.15; N, 8.17. Found: C, 52.41; H. 5.05; N, 8.22.
23. 2) = 0.0640.
24. (a) Akita, M.; Ohta, K.; Takahashi, Y.; Hikichi, S.; Moro-oka, Y. Organometallics 1997, 16, 4121
25. (b) Bucher, U. E.; Currao, A.; Nesper, R.; Rüegger, H.; Venanzi, L.M.; Younger, E. Inorg. Chem. 1995, 34, 66.
26. Bucher, U. E.; Fässler, T. F.; Hunziker, M.; Nesper, R.; Rüegger, H.; Venanzi, L. M. Gazz. Chim. Ital. 1995, 125, 181.
27. (a) Chai, M.; Pi, Z.; Tessier, C.; Rinaldi, P. L. J. Am. Chem. Soc. 1999, 121, 273.
28. (b) Cuadrado, I.; Morán, M.; Losada, J.; Casado, M. C.; Pascual, C.; Alonso, B.; Lobete, F. Adv. Dendritic Macromol. 1996, 3, 151.
29. (c) Seyferth, D.; Son, D. Y. Organometallics 1994, 13, 2682.
30. Fraenkel, G.; Winchester, W. R.; Williard, P. G. Organometallics 1989, 8, 2308.
31. 5: C, 64.28; H, 8.50; N, 13.63. Found: C, 64.13; H, 8.41; N, 13.49.
32. 5: C, 59.66; H, 6.87; N, 7.95. Found: C, 59.45; H, 6.65; N, 7.86