Fe(I)-mediated reductive cleavage and coupling of CO2: An FeII(μ-O,μ-CO)FeII core

Journal of the American Chemical Society

Volumn 129, Issue 1, 2007, Pages 4-5

  Lu, Connie C ^a   Saouma, Caroline T ^a   Day, Michael W ^a   Peters, Jonas C ^a  

^a California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; IRON;

ARTICLE; CHEMICAL REACTION; ELECTRON SPIN RESONANCE; MOLECULAR INTERACTION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION; X RAY CRYSTALLOGRAPHY;

CARBON DIOXIDE; IRON; OXIDATION-REDUCTION;

EID: 33846104560     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja065524z     Document Type: Article

References (23)

1. 2 cleavage reactions, see: (a) Bryan, J. C.; Geib, S. J.; Rheingold, A. L.; Mayer, J. M. J. Am. Chem. Soc. 1987, 109, 2826.
2. (b) Castro-Rodriguez, I.; Meyer, K. J. Am. Chem. Soc. 2005, 127, 11242.
3. (c) Fachinetti, G.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. J. Am. Chem. Soc. 1979, 101, 1767.
4. (d) Procopio, L. J.; Carroll, P. J.; Berry, D. H. Organometallics 1993, 12, 3087.
5. 2 reduction can he mediated by later first row metals: (a) Simón-Manso, E.; Kubiak, C. P. Organometallics 2005, 24, 96.
6. (b) Hammouche, M.; Lexa, D.; Momenteau, M.; Savéant, J.-M. J. Am. Chem. Soc. 1991, 113, 8455.
7. (c) Beley, M.; Collin, J.-P.; Ruppert, R.; Sauvage, J.-P. J. Am. Chem. Soc. 1986, 108, 7461.
8. (d) Fisher, B.; Eisenberg, R. J. Am. Chem. Soc. 1980, 102, 7361.
9. (e) Dubois, D. L.; Miedaner, A.; Haltiwanger, R. C. J. Am. Chem. Soc. 1991, 113, 8753-8764.
10. 2 reduction usine diborane reductants, see: Laitar, D. S.; Muller, P.; Sadighi, J. P. J. Am. Chem. Soc. 2005, 127, 17196.
11. (a) Ragsdale, S. W.; Kumar, M. Chem. Rev. 1996, 96, 2515.
12. (b) Evans, D. J. Coord. Chem. Rev. 2005, 249, 1582.
13. 2 to generate oxalate are uncommon. See. for example: Evans, W. J.; Seibel, C. A.; Ziller, J. W. Inorg. Chem. 1998, 37, 770.
14. (a) Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 10782.
15. (b) Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2004, 126, 6252.
16. (a) Butts, M. D.; Bergman, R. G. Organometallics 1994, 13, 2668.
17. (b) Nolan, S. P.; Hoff, C. D.; Stoutland, P. O.; Newman, L. J.; Buchanan, J. M.; Bergman, R. G.; Yang, G. K.; Peters, K. G. J. Am. Chem. Soc. 1987, 109, 3143.
18. For related Fe(III) imides, see: (a) Brown, S. D.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 322.
19. (b) Brown, S. D.; Peters, J. C. J. Am. Chem. Soc. 2005, 127, 1913.
20. (c) Thomas, C. M.; Mankad, N. P.; Peters, J. C. J. Am. Chem. Soc. 2006, 128, 4956. Also see 6a.
21. Triclinic, monoclinic, and tetragonal crystals of 6 were examined: each crystal form was problematic. The triclinic crystals diffracted poorly and contained large areas of highly disordered solvent (see Supporting Information). In the monoclinic crystals, 6 was very disordered in addition to the disordered solvent molecules. The tetragonal crystal form yielded no atomic information.
22. There are a few examples of dimetal μ-sulfide/μ-CO core structures. See. for example: (a) Kubiak, C. P.; Woodcock, C.; Eisenberg, R. Inorg. Chem. 1980, 19, 2733.
23. (b) Balch, A. L.; Catalano, V. J.; Olmstead, M. M. Inorg. Chem. 1990, 29, 1638.