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Volumn 23, Issue 8, 2004, Pages 1730-1737

Synthesis and Structure of Novel Iridium(I) Complexes Containing η4-1,6-Diene and Diphosphine Ligands: Remarkable Effect of Ligand Bite Angle upon Ligand Dissociation

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CATALYSIS; COMPLEXATION; INFRARED SPECTROSCOPY; ISOMERIZATION; SYNTHESIS (CHEMICAL); TRANSITION METALS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 2342433098     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034282y     Document Type: Article
Times cited : (20)

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    • Widenhoefer et al. have also reported that the cationic palladium(II) phenanthroline complex rapidly reacted with 1 in the presence of triethylsilane to form a palladium(II) 5-hexenyl chelate complex. This unprecedented complex facilely converted the palladium(II) cyclopentyl chelate via β-migratory insertion; see: Perch, N. S.; Widenhoefer, R. A. Organometallics 2001, 20, 5251-5253.
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