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The term switch, even though used within the community, may be somewhat misleading; according to the laws of thermodynamics there can only be a certain increase or decrease in the binding affinity as expressed by a change in the stability constant K for the equilibrium under observation.
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2+ to effect a quantitative redox reaction.
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The oxidation is at a very anodic potential of ca. 0.8 V. However, from electrochemical simulations with DIGISIM we found that for EC processes with very fast chemical reactions the oxidation potentials can be shifted anodically, as observed here.
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52
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0002975330
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note
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2+ this complex can be probed directly. It is, however, very unlikely that a protonated species is observed instead.
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2HCN.
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0002930469
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-1] and due to the weakness of the appropriate bands for evaluation.
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69
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0001285778
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To further slow down the reaction, a 1/1/1 stoichiometry of the same reaction partners was mixed in a stopped-flow cell. Here the sequence of reactions is complete after about 1 s.
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note
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Crystal data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-153271. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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