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Volumn 7, Issue 20, 2001, Pages 4438-4446

Coupled molecular switches: A redox-responsive ligand and the redox-switched complexation of metal ions

Author keywords

Electrochemistry; Electron transfer; Molecular devices; Supramolecular chemistry

Indexed keywords

ELECTRON TRANSITIONS; IONS; ORGANIC COMPOUNDS; X RAY CRYSTALLOGRAPHY;

EID: 0035887134     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20011015)7:20<4438::AID-CHEM4438>3.0.CO;2-K     Document Type: Article
Times cited : (53)

References (74)
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    • J. Howard, Nature 1997, 389, 561.
    • (1997) Nature , vol.389 , pp. 561
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  • 31
    • 0002998041 scopus 로고    scopus 로고
    • note
    • The term switch, even though used within the community, may be somewhat misleading; according to the laws of thermodynamics there can only be a certain increase or decrease in the binding affinity as expressed by a change in the stability constant K for the equilibrium under observation.
  • 46
    • 0003051890 scopus 로고    scopus 로고
    • note
    • 2+ to effect a quantitative redox reaction.
  • 51
    • 0003059979 scopus 로고    scopus 로고
    • note
    • The oxidation is at a very anodic potential of ca. 0.8 V. However, from electrochemical simulations with DIGISIM we found that for EC processes with very fast chemical reactions the oxidation potentials can be shifted anodically, as observed here.
  • 52
    • 0002975330 scopus 로고    scopus 로고
    • note
    • 2+ this complex can be probed directly. It is, however, very unlikely that a protonated species is observed instead.
  • 65
    • 0002918919 scopus 로고    scopus 로고
    • note
    • 2HCN.
  • 67
    • 0002930469 scopus 로고    scopus 로고
    • note
    • -1] and due to the weakness of the appropriate bands for evaluation.
  • 71
    • 0003068048 scopus 로고    scopus 로고
    • note
    • To further slow down the reaction, a 1/1/1 stoichiometry of the same reaction partners was mixed in a stopped-flow cell. Here the sequence of reactions is complete after about 1 s.
  • 74
    • 0002975334 scopus 로고    scopus 로고
    • note
    • Crystal data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-153271. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.