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Volumn 14, Issue 15, 2008, Pages 4618-4630

Optically active zwitterionic λ5Si, λ5Si′-disilicates: Syntheses, crystal structures, and behavior in aqueous solution

Author keywords

Coordination modes; Silicates; Silicon; Stereochemistry; Zwitterions

Indexed keywords

COORDINATION MODES; SILICATES; SILICON; STEREOCHEMISTRY; ZWITTERIONS;

EID: 53849090990     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200701858     Document Type: Article
Times cited : (25)

References (51)
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    • The degree of distortion was calculated by using the dihedral angle method described in references [9a.b, all nine dihedral angles and the values for the reference geometry of the ideal square pyramid given in reference [9a] were considered for this calculation, d The quantification of the distortion in this form relates to the transition from the ideal trigonal bipyramid toward the ideal square pyramid along the reaction coordinate of the Berry pseudorotation
    • c) The degree of distortion was calculated by using the dihedral angle method described in references [9a.b]: all nine dihedral angles and the values for the reference geometry of the ideal square pyramid given in reference [9a] were considered for this calculation, d) The quantification of the distortion in this form relates to the transition from the ideal trigonal bipyramid toward the ideal square pyramid along the reaction coordinate of the Berry pseudorotation.
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    • The hydrogen-bonding systems were analyzed by using the PLATON program system; A. L. Spek. PLATON, University of Utrecht, Utrecht, The Netherlands, 2003.
    • a) The hydrogen-bonding systems were analyzed by using the PLATON program system; A. L. Spek. PLATON, University of Utrecht, Utrecht, The Netherlands, 2003.
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    • 3CN, and 15 are available in the Supporting Information.
    • 3CN, and 15 are available in the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.