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Volumn 96, Issue 3, 1996, Pages 927-950

Comparison of phosphorus and silicon: Hypervalency, stereochemistry, and reactivity

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EID: 4243552523     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr950243n     Document Type: Article
Times cited : (482)

References (292)
  • 1
    • 23044505158 scopus 로고
    • Bethell, D., Ed.; Academic Press: New York, and references cited therein
    • Thatcher, G. R. J.; Kluger, R. Advances in Physical Organic Chemistry, Bethell, D., Ed.; Academic Press: New York, 1989; Vol. 25, pp 99-265 and references cited therein.
    • (1989) Advances in Physical Organic Chemistry , vol.25 , pp. 99-265
    • Thatcher, G.R.J.1    Kluger, R.2
  • 3
    • 84896588294 scopus 로고
    • (a) Westheimer, F. H. Acc. Chem. Res. 1968, 1, 70; Pure Appl. Chem. 1977, 49, 1059.
    • (1977) Pure Appl. Chem. , vol.49 , pp. 1059
  • 5
    • 85033025805 scopus 로고    scopus 로고
    • note
    • For additional background on earlier studies of nucleophilic displacement reactions at tetracoordinated silicon and phosphorus and associated reactivity studies, refs 10 and 11 should be consulted for silicon and refs 7 and 10 for phosphorus.
  • 11
    • 0000447030 scopus 로고
    • Lippard, S. J., Ed.; John Wiley and Sons: New York
    • Holmes, R. R. In Progress in Inorganic Chemistry; Lippard, S. J., Ed.; John Wiley and Sons: New York, 1984; Vol. 32, pp 119-235.
    • (1984) Progress in Inorganic Chemistry , vol.32 , pp. 119-235
    • Holmes, R.R.1
  • 12
    • 0002452792 scopus 로고
    • and references cited therein
    • Holmes, R. R. Chem. Rev. 1990, 90, 17-31 and references cited therein.
    • (1990) Chem. Rev. , vol.90 , pp. 17-31
    • Holmes, R.R.1
  • 25
    • 0001851492 scopus 로고
    • (a) Corriu, R. J. P.; Dabosi, G.; Martineau, M. J. Organomet. Chem. 1978, 150, 27; 1978, 154, 33.
    • (1978) J. Organomet. Chem. , vol.154 , pp. 33
  • 67
    • 24544446854 scopus 로고
    • Macharashvili, A. A.; Baukov, Yu. I.; Kramarova, E. P.; Oleneva, G. I.; Pestunovich, V. A.; Struchkov, Yu. T.; Shklover, V. E. Zh. Strukt. Khim. 1987, 28, 114; Chem. Abstr. 1988, 108, 29802x.
    • (1988) Chem. Abstr. , vol.108
  • 78
    • 85033001457 scopus 로고    scopus 로고
    • submitted for publication
    • Additional X-ray structures of neutral hexacoordinate phosphorus are found in a recent review: Wong, C. Y.; Kennepohl, D. K.; Cavell, R. G. Chem. Rev., submitted for publication.
    • Chem. Rev.
    • Wong, C.Y.1    Kennepohl, D.K.2    Cavell, R.G.3
  • 79
    • 0004195923 scopus 로고
    • Hartley, F. R., Ed.; Wiley: New York, Chapter 3 and references cited therein
    • Burgada, R.; Setton, R. The Chemistry of Organophosphorus Compounds, Hartley, F. R., Ed.; Wiley: New York, 1994; Vol. 3, Chapter 3 and references cited therein.
    • (1994) The Chemistry of Organophosphorus Compounds , vol.3
    • Burgada, R.1    Setton, R.2
  • 85
    • 0001286141 scopus 로고
    • Kosolopoff, G. M., Maier, L., Eds.; Wiley-Interscience: New York
    • Hellwinkel, D. In Organophosphorus Compounds; Kosolopoff, G. M., Maier, L., Eds.; Wiley-Interscience: New York, 1972; Vol. 3, p 185.
    • (1972) Organophosphorus Compounds , vol.3 , pp. 185
    • Hellwinkel, D.1
  • 150
    • 24844442001 scopus 로고
    • Macharashvili, A. A.; Baukov, Yu. I.; Kramarova, E. P.; Oleneva, G. I.; Pestunovich, V. A.; Struchkov, Yu. T.; Shklover, V. E. Zh. Strukt. Khim. 1987, 28, 107; Chem. Abstr. 1988, 108, 14178z.
    • (1988) Chem. Abstr. , vol.108
  • 155
    • 0347365961 scopus 로고
    • and references cited therein
    • Verkade, J. G. Coord. Chem. Rev. 1994, 137, 233 and references cited therein.
    • (1994) Coord. Chem. Rev. , vol.137 , pp. 233
    • Verkade, J.G.1
  • 179
    • 85033029171 scopus 로고    scopus 로고
    • note
    • 167 and this is with respect to the same type of nucleus. When activation energies are compared from two different magnetic nuclei in the same system, as in these studies, we can expect that the discrepancy would even be larger.
  • 180
  • 203
    • 85033011459 scopus 로고    scopus 로고
    • For mechanistic interpretation of nucleophilic substitution reactions of tetracoordinate phosphorus, critical reviews found in refs 1, 6, 7, and 180 should be consulted
    • For mechanistic interpretation of nucleophilic substitution reactions of tetracoordinate phosphorus, critical reviews found in refs 1, 6, 7, and 180 should be consulted.
  • 207
    • 85033003204 scopus 로고    scopus 로고
    • note
    • 172
  • 208
    • 1542680270 scopus 로고
    • Gutmann, V., Ed.; Academic Press: New York
    • (b) Schmutzler, R. In Halogen Chemistry; Gutmann, V., Ed.; Academic Press: New York, 1967; Vol. 2, pp 31-113.
    • (1967) Halogen Chemistry , vol.2 , pp. 31-113
    • Schmutzler, R.1
  • 224
    • 84896590310 scopus 로고
    • Boyer, P. D., Ed.; Academic Press: New York, Chapter 12
    • Watts, D. C. The Enzymes, 3rd ed.; Boyer, P. D., Ed.; Academic Press: New York, 1973; Vol. 8, Chapter 12.
    • (1973) The Enzymes, 3rd Ed. , vol.8
    • Watts, D.C.1
  • 225
    • 84896589380 scopus 로고
    • Boyer, P. D., Ed.; Academic Press: New York, Chapter 19
    • Hollander, V. P. The Enzymes, 3rd ed.; Boyer, P. D., Ed.; Academic Press: New York, 1973; Vol. 4, Chapter 19.
    • (1973) The Enzymes, 3rd Ed. , vol.4
    • Hollander, V.P.1
  • 232
    • 34548438899 scopus 로고
    • Corriu, R. J. P.; Fernandez, J. M.; Guerin, C. J. Organomet. Chem. 1978, 152, 25.
    • (1978) J. Organomet. Chem. , vol.152 , pp. 25
  • 240
    • 85033018581 scopus 로고    scopus 로고
    • note
    • b-n whereas no corresponding chlorofluorides of anionic silicon have been shown to exist under these conditions.
  • 265
    • 85033017404 scopus 로고    scopus 로고
    • note
    • Since bond energies fall off somewhat exponentially as bond distance increases from a covalent value, considerably greater penetration of a donor atom apparently is needed to cause an appreciable alteration in geometry.
  • 280
    • 84896586330 scopus 로고    scopus 로고
    • Adapted from ref 44
    • Adapted from ref 44.
  • 281
    • 84896586488 scopus 로고    scopus 로고
    • Adapted from ref 226
    • Adapted from ref 226.
  • 283
    • 84896586348 scopus 로고    scopus 로고
    • Reference 1, p 131
    • Reference 1, p 131.
  • 288
    • 85033005848 scopus 로고    scopus 로고
    • note
    • 104,105 is that enzyme residues by way of donor action may increase substrate reactivity by altering the geometry toward the higher hexacoordinate hypervalent state.
  • 289
    • 0002173005 scopus 로고
    • Sigman, D. S., Ed.; Academic Press: New York
    • Gerlt, J. A. The Enzymes, 3rd ed.; Sigman, D. S., Ed.; Academic Press: New York, 1992; Vol. XX, pp 95-139.
    • (1992) The Enzymes, 3rd Ed. , vol.20 , pp. 95-139
    • Gerlt, J.A.1
  • 290
    • 77957295740 scopus 로고
    • Sigman, D. S., Ed.; Academic Press: New York
    • Frey, P. A. The Enzymes, 3rd ed.; Sigman, D. S., Ed.; Academic Press: New York, 1992; Vol. XX, pp 141-186.
    • (1992) The Enzymes, 3rd Ed. , vol.20 , pp. 141-186
    • Frey, P.A.1


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