Five and six-coordinate silicon complexes with an O,N,O′-chelating ligand derived from o-hydroxyacetophenone-N-(2-hydroxyethyl)imine

Inorganic Chemistry Communications

Volumn 10, Issue 4, 2007, Pages 482-484

  Böhme, Uwe ^a   Günther, Betty ^a  

^a TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

Complexes; Crystal structure; Hypercoordinate silicon

Indexed keywords

EID: 33847256305     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2007.01.008     Document Type: Article

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13. 3, mp 195 °C, melting under decomposition.
14. 3): δ = -172.3 ppm.
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16. 2) = 0.1018, 236 parameters, only coordinates of H atoms refined. Data were collected with a Bruker X8 APEX2 diffractometer. Intensities were collected with graphite monochromatised Mo Kα radiation at -70 °C. The structure was solved by direct methods, using the SHELXS program and refined by full-matrix least squares method using SHELX97. CCDC 257 769.
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19. 2) = 0.0850, 282 parameters, only coordinates of H atoms refined. Data were collected with a Bruker X8 APEX2 diffractometer. Intensities were collected with graphite monochromatised Mo Kα radiation at -180 °C. The structure was solved by direct methods, using the SHELXS program and refined by full-matrix least squares method using SHELX97. CCDC 278 080.
20. Böhme U., and Günther B. Acta Crystallographica Section E (2006) m1711-m1712