Reactivity control of an allylsilane bearing a 2-(phenylazo)phenyl group by photoswitching of the coordination number of silicon

Journal of the American Chemical Society

Volumn 126, Issue 20, 2004, Pages 6250-6251

  Kano, Naokazu ^a   Yamamura, Masaki ^a   Kawashima, Takayuki ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; BENZENE DERIVATIVE; ORGANOSILICON DERIVATIVE; SILANE DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

EID: 2442691541     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037404m     Document Type: Article

References (18)

1. (a) Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley & Sons: New York, 1989; Part 1, pp 1241-1288.
2. (b) Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. Chem. Rev. 1993, 93, 1371.
3. (c) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Patai, S., Apeloig, Y., Eds.; John Wiley & Sons: New York, 1998; Part 2, Vol. 2, pp 1339-1445.
4. Kano, N.; Komatsu, F.; Kawashima, T. J. Am. Chem. Soc. 2001, 123, 10778.
5. Kingston, V.; Gostevskii, B.; Kalikhman, I.; Kost, D. Chem. Commun. 2001, 1272.
6. (a) Kano, N.; Komatsu, F.; Kawashima, T. Chem. Lett. 2001, 338.
7. (b) Kano, N.; Yamamura, M.; Komatsu, F.; Kawashima, T. J. Organomet. Chem. 2003, 686, 192.
8. 2-(Dimethylaminomethyl)phenyl group is useful for construction and stabilization of pentacoordinate and hexacoordinate silicon compounds. See: (a) Helmer, B. J.; West, R.; Corriu, R. J. P.; Poirier, M.; Royo, G.; de Saxcé, A. J. Organomet. Chem. 1983, 251, 295.
9. (b) Boyer, J.; Brelière, C.; Carré, F.; Corriu, R. J. P.; Kpoton, A.; Poirier, M.; Royo, G.; Young, J. C. J. Chem. Soc., Dalton Trans. 1989, 43.
10. (c) Corriu, R. J. P.; Kpoton, A.; Poirier, M.; Royo, G.; de Saxcé, A.; Young, J. C. J. Organomet. Chem. 1990, 395, 1.
11. 2 (all data) = 0.088, GOF = 1.157.
12. Klebe, G. J. Organomet. Chem. 1987, 332, 35.
13. 19F NMR spectra.
14. (a) Hosomi, A.; Kohra, S.; Tominaga, Y. J. Chem. Soc., Chem. Commun. 1987, 1517.
15. (b) Hayashi, T.; Matsumoto, Y.; Kiyoi, T.; Ito, Y. Tetrahedron Lett. 1988, 29, 5667.
16. (c) Kira, M.; Sato, K.; Sakurai, H. J. Am. Chem. Soc. 1988, 110, 4599.
17. (d) Kira, M.; Sato, K.; Sakurai, H. Tetrahedron Lett. 1989, 30, 1099.
18. (e) Kira, M.; Hino, T.; Sakurai, H. Chem. Lett. 1991, 277.