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0000035505
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The progress between TBP and SQP coordination geometry (% TBP) was determined using the equation % TBP = 100%(Angle 1 - Angle 2)/ 60°, in which Angle 1 is the widest angle X-Si-Y within the pentacoordinate geometry (i.e., the axial angle) and Angle 2 is the widest angle in the equatorial plane with respect to the axis defined with Angle 1. This general equation was derived from the special form % TBP = 100%(|Angle N-Si-N - Angle O-Si-O|)/60°, which has been used by Kost et al.: Kost, D.; Kingston, V.; Gostevskii, B.; Ellern, A.; Stalke, D.; Walfort, B.; Kalikhman, I. Organometallics 2002, 21, 2293.
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The progress between TBP and SQP coordination geometry (% TBP) was determined using the equation % TBP = 100%(Angle 1 - Angle 2)/ 60°, in which Angle 1 is the widest angle X-Si-Y within the pentacoordinate geometry (i.e., the axial angle) and Angle 2 is the widest angle in the equatorial plane with respect to the axis defined with Angle 1. This general equation was derived from the special form % TBP = 100%(|Angle N-Si-N - Angle O-Si-O|)/60°, which has been used by Kost et al.: Kost, D.; Kingston, V.; Gostevskii, B.; Ellern, A.; Stalke, D.; Walfort, B.; Kalikhman, I. Organometallics 2002, 21, 2293.
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27844563940
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(c) Wagler, J.; Böhme, U.; Brendler, E.; Thomas, B.; Goutal, S.; Mayr, H.; Kempf, B.; Remennikov, G. Ya.; Roewer, G. Inorg. Chim. Acta 2005, 358, 4270.
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23
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33845184519
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Other di- and oligosilanes bearing pentacoordinate Si atoms with an equatorially situated Si-Si bond were reported by (respective Si-Si bond lengths in Å): (a) Kira, M.; Sato, K.; Kabuto, C.; Sakurai, H. J. Am. Chem. Soc. 1989, 111, 3747 [2.403(3)].
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Other di- and oligosilanes bearing pentacoordinate Si atoms with an equatorially situated Si-Si bond were reported by (respective Si-Si bond lengths in Å): (a) Kira, M.; Sato, K.; Kabuto, C.; Sakurai, H. J. Am. Chem. Soc. 1989, 111, 3747 [2.403(3)].
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24
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33846240978
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Reference 9 [2.3480(9) and 2.33538
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(b) Reference 9 [2.3480(9) and 2.3353(8)].
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25
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0033516291
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El-Sayed, I.; Hatanaka, Y.; Muguruma, C.; Shimada, S.; Tanaka, M.; Koga, N.; Mikami, M. J. Am. Chem. Soc. 1999, 121, 5095 [2.329(1), 2.3395(6), 2.3362(5), 2.3447(7)].
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(c) El-Sayed, I.; Hatanaka, Y.; Muguruma, C.; Shimada, S.; Tanaka, M.; Koga, N.; Mikami, M. J. Am. Chem. Soc. 1999, 121, 5095 [2.329(1), 2.3395(6), 2.3362(5), 2.3447(7)].
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26
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0035913753
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Toshimitsu, A.; Saeki, T.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 9210 [2.348(1)].
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(d) Toshimitsu, A.; Saeki, T.; Tamao, K. J. Am. Chem. Soc. 2001, 123, 9210 [2.348(1)].
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27
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0034928888
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Toshimitsu, A; Hirao, S.; Saeki, T.; Asahara, M.; Tamao, K. Heteroat. Chem. 2001, 12, 392 [2.333(1), 2.368(1), 2.3563(6), 2.3711(9)]. Those with bulky substituants e.g., triphenylsilyl group, ref a] exhibit notably longer equatorial Si-Si bonds. Most of the Si-Si interatomic distances, however, are close to 2.35 Å, the Si-Si bond length found in 4.
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(e) Toshimitsu, A; Hirao, S.; Saeki, T.; Asahara, M.; Tamao, K. Heteroat. Chem. 2001, 12, 392 [2.333(1), 2.368(1), 2.3563(6), 2.3711(9)]. Those with bulky substituants (e.g., triphenylsilyl group, ref a] exhibit notably longer equatorial Si-Si bonds. Most of the Si-Si interatomic distances, however, are close to 2.35 Å, the Si-Si bond length found in 4.
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28
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33745793844
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Wagler, J.; Gerlach, D.; Böhme, U.; Roewer, G. Organometallics 2006, 25, 2929.
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33
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33846239052
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29Si INEPT NMR spectrum of the filtrate was recorded. It exhibits various signals between 36 and -94 ppm.
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29Si INEPT NMR spectrum of the filtrate was recorded. It exhibits various signals between 36 and -94 ppm.
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34
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In a modified reaction, addition of 1 equiv of tetrachlorodimethyldisilane to a solution of Et3N, 2 equiv of ligand 3, however, produced a mixture that exhibits various 29Si NMR signals between -84 and -94 ppm. Several smaller further signals can be found between 0 and -63 ppm. Compound 8, 81.5 ppm represents only a minor component of this mixture
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29Si NMR signals between -84 and -94 ppm. Several smaller further signals can be found between 0 and -63 ppm. Compound 8 (-81.5 ppm) represents only a minor component of this mixture.
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35
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