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Selected reviews dealing with higher-coordinate silicon compounds: a D. Kost, I. Kalikhman in The Chemistry of Organic Silicon Compounds, 2, Part 2 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, Chichester, 1998, pp. 1339-1445;
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Selected reviews dealing with higher-coordinate silicon compounds: a) D. Kost, I. Kalikhman in The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, Chichester, 1998, pp. 1339-1445;
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b) V. Pestunovich, S. Kirpichenko, M. Voronkov in The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, Chichester, 1998, pp. 1447-1537;
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Tacke, R.1
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5-Si compounds with Si-S bonds: a R. Willeke, R. Tacke, Z. Anorg. Allg. Chem. 2001, 627, 1537-1541;
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5-Si compounds with Si-S bonds: a) R. Willeke, R. Tacke, Z. Anorg. Allg. Chem. 2001, 627, 1537-1541;
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b) R. Tacke, M. Mallak, R. Willeke, Angew. Chem. 2001, 113, 2401-2403;
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Angew. Chem. Int. Ed. 2001, 40, 2339-2341;
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Chem. Int. Ed
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c) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104-4110;
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Angew. Chem. Int. Ed. 2007, 46, 7006-7009.
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a) D. Kost, I. Kalikhman, S. Krivonos, R. Bertermann, C. Burschka, R. E. Neugebauer, M. Pülm, R. Willeke, R. Tacke, Organometallics 2000, 19, 1083-1095;
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29144444701
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b) O. Seiler, C. Burschka, S. Metz, M. Penka, R. Tacke, Chem. Eur. J. 2005, 11, 7379-7386.
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34848844640
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Crystal structure analyses of 1 and 2: Suitable single crystals were mounted in inert oil (perfluoroalkyl ether, ABCR) on a glass fiber and then transferred to the cold nitrogen gas stream of the diffractometer (Stoe IPDS; graphite-monochromated MoKα radiation, λ, 0.71073 Å, The structures were solved by direct methods (SHELXS-97) and refined by full-matrix least-squares methods on F2 for all unique reflections (SHELXL-97, For the CH hydrogen atoms, a riding model was employed. The positions of the NH hydrogen atoms were localized in difference Fourier syntheses and refined freely. CCDC-647513 (1) and CCDC-647514 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via 1: single crystal of dimensions 0.5 x 0.5 x 0.2 mm obtained by crystallizati
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-3.
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20
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34848880464
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The degree of distortion was calculated by using the dihedral-angle method described in references [5a] and [5b, All nine dihedral angles and the values for the reference geometry of the ideal square pyramid given in reference [5a] were considered for this calculation
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c) The degree of distortion was calculated by using the dihedral-angle method described in references [5a] and [5b]. All nine dihedral angles and the values for the reference geometry of the ideal square pyramid given in reference [5a] were considered for this calculation.
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7744223931
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a) R. Tacke, R. Bertermann, C. Burschka, S. Dragota, M. Penka, I. Richter, J. Am. Chem. Soc. 2004, 126, 14 493-14 505;
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34848916058
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The hydrogen-bonding systems were analyzed by using the program system PLATON: A. L. Spek, PLATON, University of Utrecht, Utrecht, The Netherlands, 1998.
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The hydrogen-bonding systems were analyzed by using the program system PLATON: A. L. Spek, PLATON, University of Utrecht, Utrecht, The Netherlands, 1998.
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24
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34848882784
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Solid-state 13C, 15N, and 29Si VACP/Magic-Angle-Spinning (MAS) NMR studies on 1 and 2: The NMR spectra were recorded at 22°C on a Bruker DSX-400 NMR spectrometer with bottom layer rotors of ZrO2 (diameter, 7 mm) containing ca. 100 mg of sample (13C, 100.6 MHz; 15N, 40.6 MHz; 29Si, 79.5 MHz, external standard TMS (13C, 29Si; δ, 0 ppm) or glycine (15N, δ, 342.0 ppm, spinning rate 5.5-7 kHz; contact time 1 ms (13C, 3 ms 15N, or 5 ms, 29Si, 90° 1H transmitter pulse length, 3.6 μs; repetition time, 4 s
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1H transmitter pulse length, 3.6 μs; repetition time, 4 s.
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