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For a two-step synthesis of P,O-type ligands from 2-bromo-acetophenone, see: (a) X. Bei, H. W. Turner, W. H. Weinberg, A. S. Guram and J. L. Petersen, J. Org. Chem., 1999, 64, 6797;
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33
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5044232157
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note
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31P NMR showed that there is no detectable phosphine oxide signal after one month storage under air.
-
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35
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0242600609
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(b) J. F. Jensen, I. Søtofte, H. O. Sørensen and M. Johannsen, J. Org. Chem., 2003, 68, 1258;
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38
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5044230237
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note
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Suzuki-Miyaura coupling of alkylboronic acid with ArCl has seldom been reported, see ref. 4a and most recently ref. 8d.
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