A rationally designed universal catalyst for Suzuki-Miyaura coupling processes

Angewandte Chemie - International Edition

Volumn 43, Issue 14, 2004, Pages 1871-1876

  Walker, Shawn D ^a   Barder, Timothy E ^a   Martinelli, Joseph R ^a   Buchwald, Stephen L ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Aryl chlorides; Boronic acids; Cross coupling; Palladium; Phosphane ligands

Indexed keywords

CATALYSTS; CHLORIDE MINERALS; SYNTHESIS (CHEMICAL); TEMPERATURE CONTROL;

ALKYL BORON; ARYL CHLORIDES; MILD COUPLING;

BORON;

BORON DERIVATIVE; CHLORINE DERIVATIVE;

ARTICLE; CATALYST; CHEMICAL STRUCTURE; SUZUKI REACTION; SYNTHESIS;

BIPHENYL COMPOUNDS; BORONIC ACIDS; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PALLADIUM; XYLENES;

EID: 3042654141     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353615     Document Type: Article

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39. II palladate species.[14a] While we cannot unequivocally rule this out, the fact that higher levels of catalytic activity for analogous C-N couplings have been observed for catalysts derived from 2-dicyclohexylphosphanyl-2′,4′,6′- triisopropylbiphenyl than for 1 (E. R. Stricter, S. L. Buchwald, unpublished results) cast doubt on this explanation of the high level of catalytic activity manifested with 1.