Synthesis and application of arylmonophosphinoferrocene ligands: Ultrafast asymmetric hydrosilylation of styrene

Journal of Organic Chemistry

Volumn 67, Issue 23, 2002, Pages 7982-7994

  Pedersen, Henriette Lodberg ^a   Johannsen, Mogens ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

HYDRSILYLATIONS;

CONFORMATIONS; ELECTRONIC PROPERTIES; ISOMERS; NUCLEAR MAGNETIC RESONANCE; OPTIMIZATION; STEREOCHEMISTRY; STYRENE; X RAY ANALYSIS;

SYNTHESIS (CHEMICAL);

FERROCENE DERIVATIVE; STYRENE; FERROCENE; FERROUS ION; LIGAND; PHOSPHINE DERIVATIVE; SILICON DERIVATIVE;

ARTICLE; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; SILYLATION; SYNTHESIS; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM;

CATALYSIS; FERROUS COMPOUNDS; LIGANDS; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; PHOSPHINES; SILICON COMPOUNDS; STEREOISOMERISM; STYRENE;

EID: 0037111604     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0257804     Document Type: Article

References (120)

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8. For important contributionss to this area see: (a) Marquarding, D.; Klusacek, H.; Gokel, G.; Hoffmann, P.; Ugi, I. J. Am. Chem. Soc. 1970, 92, 5389. (b) Hayashi, T.; Yamamoto, K.; Kumada, M. Tetrahedron Lett. 1974, 15, 4405. (c) Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, M.; Hamada, Y.; Matsumoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M. Bull. Chem. Soc. Jpn. 1980, 53, 1138. (d) Togni, A.; Breutel, C.; Schnyder, A.; Spindler, F.; Landert, H.; Tijani, A. J. Am. Chem. Soc. 1994, 116, 4062. For reviews and accounts, see e.g.: (e) Hayashi, T.; Kumada, M. Acc. Chem. Res. 1982, 15, 395. (f) Hayashi, T. Pure Appl. Chem. 1988, 60, 7. (g) Ferrocenes. Homogeneous Catalysis, Organic Synthesis, Materials Science; Togni, A., Hayashi, T., Eds.; VCH: Weinheim, Germany, 1995. (i) Sawamura, M.; Ito, Y. Chem. Rev. 1992, 92, 857.
9. For important contributionss to this area see: (a) Marquarding, D.; Klusacek, H.; Gokel, G.; Hoffmann, P.; Ugi, I. J. Am. Chem. Soc. 1970, 92, 5389. (b) Hayashi, T.; Yamamoto, K.; Kumada, M. Tetrahedron Lett. 1974, 15, 4405. (c) Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, M.; Hamada, Y.; Matsumoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M. Bull. Chem. Soc. Jpn. 1980, 53, 1138. (d) Togni, A.; Breutel, C.; Schnyder, A.; Spindler, F.; Landert, H.; Tijani, A. J. Am. Chem. Soc. 1994, 116, 4062. For reviews and accounts, see e.g.: (e) Hayashi, T.; Kumada, M. Acc. Chem. Res. 1982, 15, 395. (f) Hayashi, T. Pure Appl. Chem. 1988, 60, 7. (g) Ferrocenes. Homogeneous Catalysis, Organic Synthesis, Materials Science; Togni, A., Hayashi, T., Eds.; VCH: Weinheim, Germany, 1995. (i) Sawamura, M.; Ito, Y. Chem. Rev. 1992, 92, 857.
10. For important contributionss to this area see: (a) Marquarding, D.; Klusacek, H.; Gokel, G.; Hoffmann, P.; Ugi, I. J. Am. Chem. Soc. 1970, 92, 5389. (b) Hayashi, T.; Yamamoto, K.; Kumada, M. Tetrahedron Lett. 1974, 15, 4405. (c) Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, M.; Hamada, Y.; Matsumoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M. Bull. Chem. Soc. Jpn. 1980, 53, 1138. (d) Togni, A.; Breutel, C.; Schnyder, A.; Spindler, F.; Landert, H.; Tijani, A. J. Am. Chem. Soc. 1994, 116, 4062. For reviews and accounts, see e.g.: (e) Hayashi, T.; Kumada, M. Acc. Chem. Res. 1982, 15, 395. (f) Hayashi, T. Pure Appl. Chem. 1988, 60, 7. (g) Ferrocenes. Homogeneous Catalysis, Organic Synthesis, Materials Science; Togni, A., Hayashi, T., Eds.; VCH: Weinheim, Germany, 1995. (i) Sawamura, M.; Ito, Y. Chem. Rev. 1992, 92, 857.
11. For important contributionss to this area see: (a) Marquarding, D.; Klusacek, H.; Gokel, G.; Hoffmann, P.; Ugi, I. J. Am. Chem. Soc. 1970, 92, 5389. (b) Hayashi, T.; Yamamoto, K.; Kumada, M. Tetrahedron Lett. 1974, 15, 4405. (c) Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, M.; Hamada, Y.; Matsumoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M. Bull. Chem. Soc. Jpn. 1980, 53, 1138. (d) Togni, A.; Breutel, C.; Schnyder, A.; Spindler, F.; Landert, H.; Tijani, A. J. Am. Chem. Soc. 1994, 116, 4062. For reviews and accounts, see e.g.: (e) Hayashi, T.; Kumada, M. Acc. Chem. Res. 1982, 15, 395. (f) Hayashi, T. Pure Appl. Chem. 1988, 60, 7. (g) Ferrocenes. Homogeneous Catalysis, Organic Synthesis, Materials Science; Togni, A., Hayashi, T., Eds.; VCH: Weinheim, Germany, 1995. (i) Sawamura, M.; Ito, Y. Chem. Rev. 1992, 92, 857.
12. For important contributionss to this area see: (a) Marquarding, D.; Klusacek, H.; Gokel, G.; Hoffmann, P.; Ugi, I. J. Am. Chem. Soc. 1970, 92, 5389. (b) Hayashi, T.; Yamamoto, K.; Kumada, M. Tetrahedron Lett. 1974, 15, 4405. (c) Hayashi, T.; Mise, T.; Fukushima, M.; Kagotani, M.; Nagashima, M.; Hamada, Y.; Matsumoto, A.; Kawakami, S.; Konishi, M.; Yamamoto, K.; Kumada, M. Bull. Chem. Soc. Jpn. 1980, 53, 1138. (d) Togni, A.; Breutel, C.; Schnyder, A.; Spindler, F.; Landert, H.; Tijani, A. J. Am. Chem. Soc. 1994, 116, 4062. For reviews and accounts, see e.g.: (e) Hayashi, T.; Kumada, M. Acc. Chem. Res. 1982, 15, 395. (f) Hayashi, T. Pure Appl. Chem. 1988, 60, 7. (g) Ferrocenes. Homogeneous Catalysis, Organic Synthesis, Materials Science; Togni, A., Hayashi, T., Eds.; VCH: Weinheim, Germany, 1995. (i) Sawamura, M.; Ito, Y. Chem. Rev. 1992, 92, 857.
13. For early contributions, see: (a) Trost, B. M.; Van Vranken, D. L. Angew. Chem., Int. Ed. Engl. 1992, 31, 228. (b) Trost, B. M.; Van Vranken, D. L.; Bingel, C. J. Am. Chem. Soc. 1992, 114, 9327. For overviews, see: (c) Trost, B. M. Acc. Chem. Res. 1996, 29, 355. (d) Trost, B. M.; Van Vranken, D. L. Chem. Rev. 1996, 96, 395.
14. For early contributions, see: (a) Trost, B. M.; Van Vranken, D. L. Angew. Chem., Int. Ed. Engl. 1992, 31, 228. (b) Trost, B. M.; Van Vranken, D. L.; Bingel, C. J. Am. Chem. Soc. 1992, 114, 9327. For overviews, see: (c) Trost, B. M. Acc. Chem. Res. 1996, 29, 355. (d) Trost, B. M.; Van Vranken, D. L. Chem. Rev. 1996, 96, 395.
15. For early contributions, see: (a) Trost, B. M.; Van Vranken, D. L. Angew. Chem., Int. Ed. Engl. 1992, 31, 228. (b) Trost, B. M.; Van Vranken, D. L.; Bingel, C. J. Am. Chem. Soc. 1992, 114, 9327. For overviews, see: (c) Trost, B. M. Acc. Chem. Res. 1996, 29, 355. (d) Trost, B. M.; Van Vranken, D. L. Chem. Rev. 1996, 96, 395.
16. For early contributions, see: (a) Trost, B. M.; Van Vranken, D. L. Angew. Chem., Int. Ed. Engl. 1992, 31, 228. (b) Trost, B. M.; Van Vranken, D. L.; Bingel, C. J. Am. Chem. Soc. 1992, 114, 9327. For overviews, see: (c) Trost, B. M. Acc. Chem. Res. 1996, 29, 355. (d) Trost, B. M.; Van Vranken, D. L. Chem. Rev. 1996, 96, 395.
17. For early contributions, see: (a) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Organometallics 1990, 9, 2653. (b) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Tetrahedron: Asymmetry 1991, 2, 569. (c) Burk, M. J.; Harlow, R. L. Angew. Chem., Int. Ed. Engl. 1990, 29, 1462. (d) Burk, M. J. J. Am. Chem. Soc. 1991, 113, 8518. For a historical review and an account, see: (e) Burk, M. J. ChemTracts: Org. Chem. 1998, 11, 787. (f) Burk, M. J. Acc. Chem. Res. 2000, 33, 363.
18. For early contributions, see: (a) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Organometallics 1990, 9, 2653. (b) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Tetrahedron: Asymmetry 1991, 2, 569. (c) Burk, M. J.; Harlow, R. L. Angew. Chem., Int. Ed. Engl. 1990, 29, 1462. (d) Burk, M. J. J. Am. Chem. Soc. 1991, 113, 8518. For a historical review and an account, see: (e) Burk, M. J. ChemTracts: Org. Chem. 1998, 11, 787. (f) Burk, M. J. Acc. Chem. Res. 2000, 33, 363.
19. For early contributions, see: (a) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Organometallics 1990, 9, 2653. (b) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Tetrahedron: Asymmetry 1991, 2, 569. (c) Burk, M. J.; Harlow, R. L. Angew. Chem., Int. Ed. Engl. 1990, 29, 1462. (d) Burk, M. J. J. Am. Chem. Soc. 1991, 113, 8518. For a historical review and an account, see: (e) Burk, M. J. ChemTracts: Org. Chem. 1998, 11, 787. (f) Burk, M. J. Acc. Chem. Res. 2000, 33, 363.
20. For early contributions, see: (a) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Organometallics 1990, 9, 2653. (b) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Tetrahedron: Asymmetry 1991, 2, 569. (c) Burk, M. J.; Harlow, R. L. Angew. Chem., Int. Ed. Engl. 1990, 29, 1462. (d) Burk, M. J. J. Am. Chem. Soc. 1991, 113, 8518. For a historical review and an account, see: (e) Burk, M. J. ChemTracts: Org. Chem. 1998, 11, 787. (f) Burk, M. J. Acc. Chem. Res. 2000, 33, 363.
21. For early contributions, see: (a) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Organometallics 1990, 9, 2653. (b) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Tetrahedron: Asymmetry 1991, 2, 569. (c) Burk, M. J.; Harlow, R. L. Angew. Chem., Int. Ed. Engl. 1990, 29, 1462. (d) Burk, M. J. J. Am. Chem. Soc. 1991, 113, 8518. For a historical review and an account, see: (e) Burk, M. J. ChemTracts: Org. Chem. 1998, 11, 787. (f) Burk, M. J. Acc. Chem. Res. 2000, 33, 363.
22. For early contributions, see: (a) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Organometallics 1990, 9, 2653. (b) Burk, M. J.; Feaster, J. E.; Harlow, R. L. Tetrahedron: Asymmetry 1991, 2, 569. (c) Burk, M. J.; Harlow, R. L. Angew. Chem., Int. Ed. Engl. 1990, 29, 1462. (d) Burk, M. J. J. Am. Chem. Soc. 1991, 113, 8518. For a historical review and an account, see: (e) Burk, M. J. ChemTracts: Org. Chem. 1998, 11, 787. (f) Burk, M. J. Acc. Chem. Res. 2000, 33, 363.
23. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
24. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
25. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
26. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
27. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
28. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
29. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
30. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
31. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
32. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
33. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
34. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
35. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
36. Some of the most prominent examples of this are as follows: (a) The asymmetric hydrosilylation: Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. (b) The asymmetric hydrovinylation: RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (c) The asymmetric arylation of imines: Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (d) The asymmetric Grignard cross-coupling: Hayashi, T.; Hayashizaki, K., Kiyoi, T.; Ito, J. J. Am. Chem. Soc. 1988, 110, 8153. (e) See also: Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1993, 1468. (f) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (g) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (h) Stará, I. G.; Stary, I.; Kollárovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (i) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (j) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Léger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (k) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. Engl. 1999, 38, 2395. (l) Hayashi, T. J. Organomet. Chem. 2002, 653 (1-2), 41. (m) Han, J. W.; Tokunaga, N.; Hayashi, T. Synlett 2002, 871. (n) For the asymmetric arylation of aldehydes, see: Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279.
37. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
38. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
39. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
40. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
41. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
42. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
43. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
44. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
45. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
46. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
47. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
48. For examples where monophosphines give higher selectivity than the usual bisphosphines, see e.g.: (a) Feringa, B. L.; Pineschi, M.; Arnold, L. A.; Imbos, R.; de Vries, A. H. M. Angew. Chem., Int. Ed. Engl. 1997, 3G, 2620. For examples where monophosphines give similar selectivities as bisphosphines, see e.g.: (b) Reetz, M. T.; Mehler, G. Angew. Chem., Int. Ed. 2000, 39, 3889 (c) Kitayama, K.; Uozumi, Y.; Hayashi, T. Chem. Commun. 1995, 1533. (d) Tye, H.; Smyth, D.; Eldred, C.; Wills, M. Chem. Commun. 1997, 1053. (e) Graf, C. D.; Malan, C.; Harms, K.; Knochel, P. J. Org. Chem. 1999, 64, 5581. (f) Zhu, G.; Chen, Z.; Jiang, Q.; Xiao, D.; Cao P.; Zhang, X. J. Am. Chem. Soc. 1997, 119, 3836. (g) Bartels, B.; Helmchen, G. Chem. Commun. 1999, 741. For examples where monophosphines display superior reactivity, see e.g.: (h) Old, D. V.; Wolfe, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1998, 120, 9722. (i) Wolfe, J. P.; Buchwald, S. L. Angew. Chem., Int. Ed. Engl. 1999, 38, 2413. (j) Aranyos, A.; Old, D. W.; Kiyomori, A.; Wolfe, J. P.; Sadighi, J. P.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 4369. (k) Wolfe, J. P.; Singer, R. A.; Yang, B. H.; Buchwald, S. L. J. Am. Chem. Soc. 1999, 121, 9550. (l) Fox, J. M. Huang, X.; Chieffi, A.; Buchwald, S. L. J. Am. Chem. Soc. 2000, 122, 1360.
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61. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
62. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
63. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
64. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.;
65. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
66. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
67. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
68. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
69. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
70. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
71. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
72. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
73. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
74. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
75. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
76. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
77. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
78. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
79. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
80. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
81. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
82. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
83. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji,
84. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
85. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
86. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
87. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
88. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
89. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
90. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
91. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
92. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
93. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
94. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
95. For the first contribution, see: (a) Uozumi, Y.; Hayashi, T. J. Am. Chem. Soc. 1991, 113, 9887. For later papers on the use of MOP-ligands, see e.g.: (b) Uozumi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945. (c) Uozumi, Y.; Suzuki, N.; Ogiwara, A.; Hayashi, T. Tetrahedron 1994, 50, 4293. (d) Hayashi, T.; Niizuma, S.; Kamikawa, T.; Suzuki, N.; Uozumi, Y. J. Am. Chem. Soc. 1995, 117, 9101. (e) Uozumi, Y.; Kitayama, K.; Hayashi, T.; Yanagi, K.; Fukuyo, E. Bull. Chem. Soc. Jpn. 1995, 68, 713. (f) Hayashi, T.; Iwamura, H.; Naito, M.; Matsumoto, Y.; Uozumi, Y.; Miki, M.; Yanagi, K. J. Am. Chem. Soc. 1994, 116, 775. (g) Uozumi, Y.; Lee, S.-Y.; Hayashi, T. Tetrahedron Lett. 1992, 33, 7185. (h) Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1993, 34, 2335. (i) Kitayama, K.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1995, 1533. (j) Kitayama, K.; Tsuji, H.; Uozumi, Y.; Hayashi, T. Tetrahedron Lett. 1996, 37, 4169. (k) Hayashi, T.; Iwamura, H.; Uozumi, Y. Tetrahedron Lett. 1994, 35, 4813. (l) Hayashi, T.; Kawatsura, M.; Iwamura, H.; Yamaura, Y.; Uozumi, Y. J. Chem. Soc., Chem. Commun. 1996, 1767. (m) Kawatsura, M.; Uozumi, Y.; Ogasawara, M.; Hayashi, T. Tetrahedron 2000, 56, 2247. (n) Hayashi, T.; Kawatsura, M.; Uozumi, Y. Chem. Commun. 1997, 561. (o) Hayashi, T.; Kawatsura, M.; Uozumi, Y. J. Am. Chem. Soc. 1998, 120, 1681. (p) Matsumoto, Y.; Naito, M.; Hayashi, T. Organometallics 1992, 11, 2732. (q) Matsumoto, Y.; Naito, M.; Uozumi, Y.; Hayashi, T. J. Chem. Soc., Chem. Commun. 1993, 1468. (r) Tsuji, Y.; Kusui, T.; Kojima, T.; Sugiura, Y.; Yamada, N.; Tanaka, S.; Ebihara, M.; Kawamura, T. Organometallics 1998, 17, 4835. (s) Imada, Y.; Fujii, M.; Kubota, Y.; Murahashi, S.-I. Tetrahedron Lett. 1997, 38, 8227. (t) Oppolzer, W.; Kuo, D. L.; Hutzinger, M. W.; Le'ger, R.; Durand, J.-O.; Leslie, C. Tetrahedron Lett. 1997, 38, 6213. (u) Hanzawa, Y.; Tabuchi, N.; Saito, K.; Noguchi, S.; Taguchi, T. Angew. Chem., Int. Ed. 1999, 38, 2395. (v) RajanBabu, T. V.; Nomura, N.; Jin, J.; Radetich, B.; Park, H.; Nandi, M. Chem. Eur. J. 1999, 5, 1963. (w) Sato, Y.; Nishiyama, T.; Mori, M. J. Org. Chem. 1994, 59, 6133. (x) Stara', I. G.; Stary, I.; Kolla'rovic, A.; Teply, F.; Vyskocil, S.; Saman, D. Tetrahedron Lett. 1999, 40, 1993. (y) Sakai, M.; Ueda, M.; Miyaura, N. Angew. Chem., Int. Ed. 1998, 37, 3279. (z) Hayashi, T.; Ishigedani, M. J. Am. Chem. Soc. 2000, 122, 976. (a′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. Chem. Lett. 2000, 1272. (b′) Hayashi, T. Catal. Today 2000, 62, 3. (c′) Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441. (d′) Hayashi, T.; Han, J. W.; Takeda, A.; Tang, J.; Nohmi, K.; Mukaide, K.; Tsuji, H.; Uozumi, Y. Adv. Synth. Catal. 2001, 343 (3), 279. (e′) Han, J. W.; Hayashi, T. Chem. Lett. 2001, 976. (g′) Shimada, T.; Mukaise, K.; Shinohara, A.; Han, J. W.; Hayashi, T. J. Am. Chem. Soc. 2002, 124, 1584. (h′) Han, J. W.; Hayashi, T. Tetrahedron: Asymmetry 2002, 13, 325. For review and accounts on the use of MOP ligands, see: (a) Hayashi, T. Acta Chem. Scand. 1996, 50, 259. (b) Hayashi, T. Acc. Chem. Res. 2000, 33, 354.
96. For early contributions, see: (a) Kyba, E. B.; Koga, K.; Sousa, L. R.; Siegel, M. G.; Cram, D. J. J. Am. Chem. Soc. 1973, 95, 2692. (b) Norori, R.; Tomino, I.; Tanimoto, Y. J. Am. Chem. Soc. 1979, 101, 3129. For overviews, see e.g. (c) Pu, L. Chem. Rev. 1998, 98, 2405. (d) Rosini, C.; Franzini, L.; Raffaelli, A.; Salvadori, P. Synthesis 1992, 503.
97. For early contributions, see: (a) Kyba, E. B.; Koga, K.; Sousa, L. R.; Siegel, M. G.; Cram, D. J. J. Am. Chem. Soc. 1973, 95, 2692. (b) Norori, R.; Tomino, I.; Tanimoto, Y. J. Am. Chem. Soc. 1979, 101, 3129. For overviews, see e.g. (c) Pu, L. Chem. Rev. 1998, 98, 2405. (d) Rosini, C.; Franzini, L.; Raffaelli, A.; Salvadori, P. Synthesis 1992, 503.
98. For early contributions, see: (a) Kyba, E. B.; Koga, K.; Sousa, L. R.; Siegel, M. G.; Cram, D. J. J. Am. Chem. Soc. 1973, 95, 2692. (b) Norori, R.; Tomino, I.; Tanimoto, Y. J. Am. Chem. Soc. 1979, 101, 3129. For overviews, see e.g. (c) Pu, L. Chem. Rev. 1998, 98, 2405. (d) Rosini, C.; Franzini, L.; Raffaelli, A.; Salvadori, P. Synthesis 1992, 503.
99. For early contributions, see: (a) Kyba, E. B.; Koga, K.; Sousa, L. R.; Siegel, M. G.; Cram, D. J. J. Am. Chem. Soc. 1973, 95, 2692. (b) Norori, R.; Tomino, I.; Tanimoto, Y. J. Am. Chem. Soc. 1979, 101, 3129. For overviews, see e.g. (c) Pu, L. Chem. Rev. 1998, 98, 2405. (d) Rosini, C.; Franzini, L.; Raffaelli, A.; Salvadori, P. Synthesis 1992, 503.
100. Asymmetric Synthesis; Hayashi, T., Tomioka, K., Yonemitsu, O., Eds.; Gordon and Breach Science Publishers: Tokyo, 1998. See also refs 2, 9, and 10.
101. The term axial chiral should preferably be avoided in this context since these compounds are not axial chiral but rather rotational diastereomers. Note that the two conformers of the fragment containing the naphthyl and ferrocene molecule with, e.g., the naphthyl group in an exo and endo position are not enantiomorphic, e.g., super imposable mirror images of each other.
102. Part of this work has been communicated: (a) Pedersen, H. L.; Johannsen, M. Chem. Commun. 1999, 2517. For the synthesis of another chiral arylferrocenyl derivative, see: (b) Bringmann, G.; Hinrichs, J.; Peters, K.; Peters, E.-V. J. Org. Chem. 2001, 66, 629.
103. Part of this work has been communicated: (a) Pedersen, H. L.; Johannsen, M. Chem. Commun. 1999, 2517. For the synthesis of another chiral arylferrocenyl derivative, see: (b) Bringmann, G.; Hinrichs, J.; Peters, K.; Peters, E.-V. J. Org. Chem. 2001, 66, 629.
104. This ortho-lithiation chemistry was originally developed by Kagan et al.: Riant, O.; Argourch, G.; Guillaneux, D.; Samuel, O.; Kagan, H. B. J. Org. Chem. 1998, 63, 3511. See also: (b) Hua, D. H.; Lagneau, N. M.; Chen, Y.; Robben, P. M.; Clapham, G.; Robinson, P. D. J. Org. Chem. 1996, 61, 4508.
105. This ortho-lithiation chemistry was originally developed by Kagan et al.: Riant, O.; Argourch, G.; Guillaneux, D.; Samuel, O.; Kagan, H. B. J. Org. Chem. 1998, 63, 3511. See also: (b) Hua, D. H.; Lagneau, N. M.; Chen, Y.; Robben, P. M.; Clapham, G.; Robinson, P. D. J. Org. Chem. 1996, 61, 4508.
106. (a) Henson, P. D.; Naumann, K.; Mislow, K. J. Am. Chem. Soc. 1969, 91, 5645.
107. (b) Imamoto, T.; Kikuchi, S.; Miura, T.; Wada, Y. Org. Lett. 2001, 3, 87.
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111. (f) Imamoto, T.; Hikosaka, T. J. Org. Chem. 1994, 59, 6753.
112. 2) was 0.1138 (all data).
113. For a related observation, see: Uemura, M. J. Org. Chem. 1996, 61, 1375.
114. Tamao, K. Oxidative cleavage of the silicon-carbon bond: Development, mechanism, scope and limitations. In Advances in Silicon Chemistry; Larson, G. L., Ed.; JAI Press: Greenwich, CT, 1996; Vol. 3, pp 1-62.
115. Jensen, J. F.; Svendsen, B. Y.; la Cour, T. V.; Pedersen, H. L.; Johannsen, M. J. Am. Chem. Soc. 2002, 124, 4558.
116. Chalk, A. J.; Harrod, J. F. J. Am. Chem. Soc. 1965, 87, 16.
117. At present, we can only give an underestimate of the actual turnover frequency based on the complete reaction time, i.e., 20 s for each catalytically active species to turn over 1000 molecules (0.1 mol % catalyst) (i.e., 180 000 turnovers per hour). The closest match we have found is in a recently published paper by Hayashi et al. By modifying the standard MOP ligand to a fluoro derivative they increased the TOF from 83 at 0 °C to around 1000 at -24 °C. See: Hayashi, T.; Hirate, S.; Kitayama, K.; Tsuji, H.; Torii, A.; Uozumi, Y. J. Org. Chem. 2001, 66, 1441.
118. For other data supporting the importance of monophosphine complexes in hydrosilylations, see: Marinetti, A. Tetrahedron Lett. 1994, 35, 5861.
119. Gillie, A.; Stille, J. K. J. Am. Chem. Soc. 1980, 102, 4937.
120. To make a reaction industrially relevant, TOF of at least 10 000 is required: Blaser, H.-U.; Spindler, F. In Comprehensive Asymmetric Catalysis; Jacobsen, N. J., Pfaltz, A., Yamamoto, H., Eds.; Springer: Heidelberg, 1999; Chapter 41.1