A dicoordinate palladium(0) complex with an unusual intramolecular η1-arene coordination

Journal of the American Chemical Society

Volumn 125, Issue 26, 2003, Pages 7816-7817

  Reid, Steven M ^a   Boyle, Robert C ^a   Mague, Joel T ^a   Fink, Mark J ^a  

^a Tulane University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PALLADIUM COMPLEX; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL MODIFICATION; COMPLEX FORMATION; MOLECULAR INTERACTION; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0038788901     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0361493     Document Type: Article

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42. 8 are virtually identical.
43. Full line shape analysis was performed with the gNMR 4.1 software package (Budzelaar, P. H. M. Cherwell Scientific Limited, 1999). Erying plots of the rate constants afforded the activation parameters. A van't Hoff plot of the equilibrium constants afforded the thermodynamic parameters.
44. X-ray crystal structures of 2b, 3, 4b, and 4c have been obtained. Details will be presented in a full paper.