Zirconocene-catalysed propene polymerisation: Kinetics, mechanism, and the role of the anion

Macromolecular Symposia

Volumn 213, Issue , 2004, Pages 173-186

  Song, Fuquan ^a   Hannant, Mark D ^a   Cannon, Roderick D ^a   Bochmann, Manfred ^a  

^a UNIVERSITY OF EAST ANGLIA   (United Kingdom)

Author keywords

Anion effects; Kinetics; Mechanism of polymerisation; Metallocenes; Propene polymerisation

Indexed keywords

ACTIVATION ANALYSIS; ALUMINUM COMPOUNDS; CATALYSIS; CATALYSTS; COMPLEXATION; METHANE; MONOMERS; POLYMERIZATION; QUENCHING; REACTION KINETICS; ZIRCONIUM COMPOUNDS;

ACTIVATOR SYSTEMS; METALLOCENES; QUENCHED-FLOW; ZIRCONOCENE;

PROPYLENE;

ALKENE; ALUMINUM DERIVATIVE; ANION; BORON; METAL DERIVATIVE; METALLOCENE; METHYLALUMINOXANE; PROPYLENE; TRIISOBUTYLALUMINUM; UNCLASSIFIED DRUG; ZIRCONIUM DERIVATIVE; ZIRCONOCENE;

CALCULATION; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CONCENTRATION RESPONSE; CONFERENCE PAPER; ENERGY; KINETICS; MASS; MATHEMATICAL ANALYSIS; MODEL; POLYMERIZATION; REACTION ANALYSIS; REACTION TIME; STRUCTURE ANALYSIS;

EID: 4644354479     PISSN: 10221360     EISSN: None     Source Type: Journal    
DOI: 10.1002/masy.200450917     Document Type: Conference Paper

References (61)

1. Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. Angew. Chem. Int. Ed. Engl. 1995, 34, 1143.
2. Resconi, L.; Cavallo, L.; Fait, A.; Piemontesi, F. Chem. Rev. 2000, 100, 1253.
3. Coates, G. W. Chem. Rev. 2000, 100, 1253.
4. Busico, V.; Cipullo, R. Progr. Polym. Sci. 2001, 26, 443.
5. Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255.
6. Chen, E. Y. X.; Marks, T. J. Chem. Rev. 2000, 100, 1391.
7. Bochmann, M.; Lancaster, S. J. Organometallics 1993, 12, 633.
8. Bochmann, M.; Wilson, L. M. J. Chem. Soc., Chem. Commun. 1986, 1610.
9. (b) Bochmann, M. Angew. Chem. Int. Ed. Engl. 1992, 31, 1181.
10. (c) Bochmann, M.; Lancaster, S. J. J. Organomet. Chem. 1992, 434, C1.
11. (a) Jordan, R. F. Adv. Organomet. Chem. 1991, 32, 325.
12. (b) Yang, X.; Stern, C. L.; Marks, T. J. Organometallics 1991, 10, 840.
13. (c) Metz, M. V.; Schwartz, D. J.; Stern, C. L.; Nickias, P. N.; Marks, T. J. Angew. Chem. Int. Ed. 2000, 39, 1312.
14. (d) Metz, M. V.; Sun, Y.; Stern, C. L.; Marks, T. J. Organometallics 2002, 21, 3691.
15. (e) Chen, M. C.; Marks, T. J. J. Am. Chem. Soc. 2001, 123, 11803.
16. (f) Abramo, G. P.; Li, L.; Marks, T. J. J. Am. Chem. Soc. 2002, 124, 13966.
17. (a) Strauss, S. H. Chem. Rev. 1993, 93, 927.
18. (b) Lupinetti, A. J.; Strauss, S. H. Chemtracts - Inorg. Chem. 1998, 11, 565.
19. (c) Ivanov, S. V.; Miller, S. M.; Anderson, O. P.; Solntsev, K. A.; Strauss, S. H. J. Am. Chem. Soc. 2003, 125, 4694.
20. (d) King, B. T.; Michl, J. J. Am. Chem. Soc. 2000, 122, 10255.
21. (e) Tsang, C. W.; Yang, Q.; Sze, E. T.; Mak, T. C. W.; Chan, D. T.; Xie, Z. Inorg. Chem. 2000, 39, 5851.
22. Reed, C. A. Acc. Chem. Res. 1998, 31, 133.
23. (b) Stasko, D.; Reed, C. A. J. Am. Chem. Soc. 2002, 124, 1148.
24. Rodriguez, G.; Brant, P. Organometallics 2001, 20, 2417.
25. Kaul, F. A. R.; Puchta, G. T.; Schneider, H.; Grosche, M.; Mihalios, D.; Herrmann, W. A. J. Organomet. Chem. 2001, 621, 177.
26. (b) Kaul, F. A. R.; Puchta, G. T.; Schneider, H.; Grosche, M.; Mihalios, D.; Herrmann, W. A. J. Organomet. Chem. 2001, 621, 184.
27. (a) Williams, V. C.; Piers, W. E.; Clegg, W.; Elsegood, M. R. J.; Collins, S.; Marder, T. B. J. Am. Chem. Soc. 1999, 121, 3244.
28. (b) Williams, V. C.; Irvine, G. J.; Piers, W. E.; Li, Z.; Collins, S.; Clegg, W.; Elsegood, M. R. J.; Marder, T. B. Organometallics 2000, 19, 1619.
29. (c) Chase, P. A.; Piers, W. E.; Patrick, B. O. J. Am. Chem. Soc. 2000, 122, 12911.
30. (d) Henderson, L. D.; Piers, W. E.; Irvine, G. J.; McDonald, R. Organometallics 2002, 21, 340.
31. (e) Roesler, R.; Has, B. J. N.; Piers, W. E. Organometallics 2002, 21, 4300.
32. (a) LaPointe, R. E. WO 99/42467, 1999.
33. (b) LaPointe, R. E.; Roof, G. R.; Abboud, K. A.; Klosin, J. J. Am. Chem. Soc. 2000, 122, 9560.
34. Lancaster, S. J.; Walker, D. A.; Thornton-Pett, M.; Bochmann, M. Chem. Commun. 1999, 1533.
35. Lancaster, S. J.; Rodriguez, A.; Lara-Sanchez, A.; Hannant, M. D.; Walker, D. A.; Hughes, D. L.; Bochmann, M. Organometallics 2002, 21, 451.
36. Zhou, J.; Lancaster, S. J.; Walker, D. A.; Beck, S.; Thornton-Pett, M.; Bochmann, M. J. Am. Chem. Soc. 2001, 123, 223.
37. Hannant, M.; Bochmann, M., results to be published.
38. See for example: (a) Busico, V.; Cipullo, R.; Esposito, V. Macromol. Rapid Commun. 1999, 20, 116.
39. (b) Mori, H.; Tashimo, K.; Terano, M. Macromol. Rapid Commun. 1995, 16, 651.
40. (c) Mori, H.; Tashino, K.; Terano, M. Macromol. Chem. Phys. 1996, 197, 895.
41. (d) Mori, H.; Iguchi, H.; Hasebe, K.; Terano, M. Macromol. Chem. Phys. 1997, 198, 1249.
42. Song, F.; Cannon, R. D.; Bochmann, M. J. Am. Chem. Soc. 2003, 125, 7641.
43. (a) Schnell, D.; Fink, G. Angew. Makromol. Chem. 1974, 39, 131.
44. (b) Fink, G.; Zoller, W. Makromol. Chem. 1981, 182, 3265.
45. (c) Fink, G.; Schnell, D. Angew. Makromol. Chem. 1982, 105, 31.
46. (d) Mynott, R.; Fink, G.; Fenzl, W. Angew. Makromol. Chem. 1987, 154, 1.
47. (e) Fink, G.; Fenzl, W.; Mynott, R. Z. Naturforsch. Teil B, 1985, 40b, 158.
48. (a) Liu, Z.; Somsook, E.; Landis, C. R. J. Am. Chem. Soc. 2001, 123, 2915.
49. (b) Liu, Z.; Somsook, E.; White, C. B.; Rosaaen, K. A.; Landis, C. R. J. Am. Chem. Soc. 2001, 123, 11193.
50. Natta, G.; Pasquon, I. Adv. Catal. 1959, 11, 1.
51. Yoder, J. C.; Bercaw, J. E. J. Am. Chem. Soc. 2002, 124, 2548.
52. (a) Lanza, G.; Fragalà, I. L. Topics Catal. 1999, 7, 45.
53. (b) Chan, M. S. W.; Vanka, K.; Pye, C. C.; Ziegler, T. Organometallics 1999, 18, 4624.
54. (c) Vanka, V.; Chan, M. S. W.; Pye, C. C.; Ziegler, T. Organometallics 2000, 19, 1841.
55. (a) Beck, S.; Geyer, A.; Brintzinger, H. H. Chem. Commun. 1999, 2477.
56. (b) Beck, S.; Lieber, S.; Schaper, F.; Geyer, A.; Brintzinger, H. H. J. Am. Chem. Soc. 2001, 123, 1483.
57. (a) Bochmann, M.; Robinson, O. B.; Lancaster, S. J.; Hursthouse, M. B.; Coles, S. J. Organometallics, 1995, 14, 2456.
58. (b) Gillis, D. J.; Quyoum, R.; Tudoret, M. J.; Wang, Q. Y.; Jeremic, D.; Roszak, A. W.; Baird, M. C. Organometallics, 1996, 15, 3600.
59. (c) Gillis, D. J.; Tudoret, M. J.; Baird, M. C. J. Am. Chem. Soc. 1993, 115, 2543.
60. (a) Resconi, R.; Piemontesi, F.; Camurati, I.; Sudmeijer, O.; Nifant'ev, I. E.; Ivchenko, P. V. and Kuz'mina, L. G. J. Am. Chem. Soc. 1998, 120, 2308.
61. (b) Moscardi, G.; Resconi, L.; Cavallo, L. Organometallics 2001, 20, 1918.