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Volumn 125, Issue 25, 2003, Pages 7641-7653

Zirconocene-catalyzed propene polymerization: A quenched-flow kinetic study

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST INITIATION;

EID: 0038546712     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029150v     Document Type: Article
Times cited : (134)

References (108)
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    • Eur. Patent Appl. 0277 004, 1988
    • (d) Turner, H. W. Eur. Patent Appl. 0277 004, 1988.
    • Turner, H.W.1
  • 57
    • 0002746518 scopus 로고
    • Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer: Berlin
    • - complexes, see: Haselwander, T.; Beck, S.; Brintzinger, H. H. In Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer: Berlin, 1995; p 181. Beck, S.; Prosenc, M. H.; Brintzinger, H. H. J. Mol. Catal. A: Chem. 1998, 128, 41.
    • (1995) Ziegler Catalysts , pp. 181
    • Haselwander, T.1    Beck, S.2    Brintzinger, H.H.3
  • 58
    • 0032570895 scopus 로고    scopus 로고
    • - complexes, see: Haselwander, T.; Beck, S.; Brintzinger, H. H. In Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer: Berlin, 1995; p 181. Beck, S.; Prosenc, M. H.; Brintzinger, H. H. J. Mol. Catal. A: Chem. 1998, 128, 41.
    • (1998) J. Mol. Catal. A: Chem. , vol.128 , pp. 41
    • Beck, S.1    Prosenc, M.H.2    Brintzinger, H.H.3
  • 87
    • 0037883877 scopus 로고    scopus 로고
    • note
    • -1.
  • 88
    • 0037883876 scopus 로고    scopus 로고
    • note
    • p to be determined by this method.
  • 89
    • 0037546105 scopus 로고    scopus 로고
    • note
    • p of only about ≤10%.
  • 91
    • 0038221518 scopus 로고    scopus 로고
    • note
    • t is, however, quite well defined.
  • 94
    • 0038560160 scopus 로고    scopus 로고
    • note
    • 5.
  • 96
    • 0038560161 scopus 로고    scopus 로고
    • note
    • A reviewer suggested inefficient catalyst activation as a likely cause. However, the same effect was found in batch reactions with our catalyst system at longer reaction times (5 min, 20 °C), that is, under conditions where any time delay due to catalyst initiation is negligible as compared to the polymerization time.
  • 101
    • 0037546107 scopus 로고    scopus 로고
    • note
    • n determined by GPC has shown that, for t ≤ 5 s, about 90% of the quenched polymer is saturated.
  • 102
    • 0037546108 scopus 로고    scopus 로고
    • note
    • p′ ∼ 12 would need to be revised upward.
  • 104
    • 0038560168 scopus 로고    scopus 로고
    • note
    • p ratio from 0.08 to 0.09.
  • 107
    • 0037183633 scopus 로고    scopus 로고
    • 2 system: (a) Wilmes, G. M.; Polse, J. L.; Waymouth, R. M. Macromolecules 2002, 35, 6766. (b) Busico, V.; Cipullo, R.; Kretschmer, W. P.; Talarico, G.; Vacatello, M.; van Axel Castelli, V. Angew. Chem., Int. Ed. 2002, 41, 505.
    • (2002) Macromolecules , vol.35 , pp. 6766
    • Wilmes, G.M.1    Polse, J.L.2    Waymouth, R.M.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.