메뉴 건너뛰기




Volumn 120, Issue 10, 1998, Pages 2308-2321

Highly regiospecific zirconocene catalysts for the isospecific polymerization of propene

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; METHYLALUMOXANE; PROPYLENE; UNCLASSIFIED DRUG; ZIRCONIUM; ZIRCONIUM DERIVATIVE;

EID: 0032542758     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973160s     Document Type: Article
Times cited : (187)

References (87)
  • 10
    • 0025306664 scopus 로고
    • Mise, T.; Miya, S.; Yamazaki, H. Chem. Lett. 1989, 1853. Roll, W.; Brintzinger, H. H.; Rieger, B.; Zolk, R. Angew. Chem., Int. Ed. Engl. 1990, 29, 279.
    • (1989) Chem. Lett. , pp. 1853
    • Mise, T.1    Miya, S.2    Yamazaki, H.3
  • 18
    • 0011395781 scopus 로고
    • Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin
    • Ewen, J. A.; Elder, M. J. In Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin, 1995; p 99.
    • (1995) Ziegler Catalysts , pp. 99
    • Ewen, J.A.1    Elder, M.J.2
  • 21
    • 2642599490 scopus 로고    scopus 로고
    • Eur. Pat. Appl. 722 949 (to Montell)
    • Nifanf'ev, I. E.; Ivchenko, P. V. Eur. Pat. Appl. 722 949 (to Montell). Nifant'ev, I. E.; Ivchenko, P. V.; Kuz'mina, L. G.; Luzikov, Yu., N.; Sitnikov, A. A.; Sizan, O. E. Synthesis 1997, 469.
    • Nifanf'ev, I.E.1    Ivchenko, P.V.2
  • 23
    • 0343716804 scopus 로고    scopus 로고
    • Eur. Pat. Appl. 722,-950 (to Montell)
    • Nifant'ev, I. E.; Ivchenko, P. V.; Resconi, L. Eur. Pat. Appl. 722,-950 (to Montell); Chem. Abstr. 1996, 125, 196000. Nifant'ev, I. E.; Ivchenko, P. V. Organometallics 1997, 16, 713.
    • (1996) Chem. Abstr. , vol.125 , pp. 196000
    • Nifant'ev, I.E.1    Ivchenko, P.V.2    Resconi, L.3
  • 24
    • 0001694853 scopus 로고    scopus 로고
    • Nifant'ev, I. E.; Ivchenko, P. V.; Resconi, L. Eur. Pat. Appl. 722,-950 (to Montell); Chem. Abstr. 1996, 125, 196000. Nifant'ev, I. E.; Ivchenko, P. V. Organometallics 1997, 16, 713.
    • (1997) Organometallics , vol.16 , pp. 713
    • Nifant'ev, I.E.1    Ivchenko, P.V.2
  • 49
    • 0025512113 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1990) J. Mol. Catal. , vol.62 , pp. 277
    • Eshuis, J.1    Tan, Y.2    Teuben, J.H.3    Renkema, J.4
  • 50
    • 0000473541 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1992) Organometallics , vol.11 , pp. 362
    • Eshuis, J.1    Tan, Y.2    Meetsma, A.3    Teuben, J.H.4
  • 51
    • 0001286729 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 1025
    • Resconi, L.1    Piemontesi, F.2    Franciscono, G.3    Abis, L.4    Fiorani, T.5
  • 52
    • 33748238797 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1992) Angew. Chem., Int. Ed. Engl. , vol.31 , pp. 1375
    • Yang, X.1    Stern, C.L.2    Marks, T.J.3
  • 53
    • 0003013142 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1991) Chem. Lett. , pp. 1525
    • Mise, T.1    Kageyama, A.2    Miya, S.3    Yamazaki, H.4
  • 54
    • 10644225884 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 3565
    • Kesti, M.1    Waymouth, R.2
  • 55
    • 0001362368 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1994) Organometallics , vol.13 , pp. 1424
    • Guo, Z.1    Swenson, D.2    Jordan, R.3
  • 56
    • 0028422034 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1994) Organometallics , vol.13 , pp. 1147
    • Hajela, S.1    Bercaw, J.E.2
  • 57
    • 0028761731 scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 10015
    • Yang, X.1    Stern, C.L.2    Marks, T.J.3
  • 58
    • 0000608703 scopus 로고    scopus 로고
    • A now large number of highly substituted ligands have been found to trigger β-Me transfer. (a) Eshuis, J.; Tan, Y.; Teuben, J. H.; Renkema, J. J. Mol. Catal. 1990, 62, 277. (b) Eshuis, J.; Tan, Y.; Meetsma, A.; Teuben, J. H. Organometallics 1992, 11, 362. (c) Resconi, L.; Piemontesi, F.; Franciscono, G.; Abis, L.; Fiorani, T. J. Am. Chem. Soc. 1992, 114, 1025. (d) Yang, X.; Stern, C. L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375. (e) Mise, T.; Kageyama, A.; Miya, S.; Yamazaki, H. Chem. Lett. 1991, 1525. (f) Kesti, M.; Waymouth, R. J. Am. Chem. Soc. 1992, 114, 3565. (g) Guo, Z.; Swenson, D.; Jordan, R. Organometallics 1994, 13, 1424. (h) Hajela, S.; Bercaw, J. E. Organometallics 1994, 13, 1147. (i) Yang, X.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10015. (j) Resconi, L.; Jones, Rheingold, A.; Yap, G. P. A. Organometallics 1996, 15, 998.
    • (1996) Organometallics , vol.15 , pp. 998
    • Resconi, L.1    Jones Rheingold, A.2    Yap, G.P.A.3
  • 59
    • 2642594539 scopus 로고    scopus 로고
    • note
    • Zr h)) to iPP with both low molecular weight (see Table 3) and low isotacticity.
  • 60
    • 2642625114 scopus 로고    scopus 로고
    • note
    • 3)=CHP group. Other experiments are underway to confirm this assignment.
  • 64
    • 2642657798 scopus 로고    scopus 로고
    • note
    • 27c (Matrix Presented) Alternatively, the internal vinylidene could arise from reinsertion of an allyl-terminated iPP chain, followed by β-H transfer. We are currently testing these two hypotheses.
  • 65
    • 33750267418 scopus 로고
    • and references therein
    • The mechanism and scope of σ-bond metathesis at permethylscandocene derivatives has been described by Bercaw and extended to methyl zirconocene cations by Jordan: Thompson, M.; Baxter, S.; Bulls, A.; Burger, B.; Nolan, M.; Santarsiero, B.; Schaefer, W.; Bercaw, J. J. Am. Chem. Soc. 1987, 109, 203 and references therein. Jordan, R.; Taylor, D.; Baenziger, N. Organometallics 1990, 9, 1546.
    • (1987) J. Am. Chem. Soc. , vol.109 , pp. 203
    • Thompson, M.1    Baxter, S.2    Bulls, A.3    Burger, B.4    Nolan, M.5    Santarsiero, B.6    Schaefer, W.7    Bercaw, J.8
  • 66
    • 0000575557 scopus 로고
    • The mechanism and scope of σ-bond metathesis at permethylscandocene derivatives has been described by Bercaw and extended to methyl zirconocene cations by Jordan: Thompson, M.; Baxter, S.; Bulls, A.; Burger, B.; Nolan, M.; Santarsiero, B.; Schaefer, W.; Bercaw, J. J. Am. Chem. Soc. 1987, 109, 203 and references therein. Jordan, R.; Taylor, D.; Baenziger, N. Organometallics 1990, 9, 1546.
    • (1990) Organometallics , vol.9 , pp. 1546
    • Jordan, R.1    Taylor, D.2    Baenziger, N.3
  • 67
    • 19944399016 scopus 로고
    • and references therein
    • 4, via σ-bond metathesis. (Matrix Presented) See also: Rothwell, I. P. Acc. Chem. Res 1988, 21, 153 and Ryabov, A. D. Chem. Rev. 1990, 90, 403 and references therein.
    • (1985) Acc. Chem. Res , vol.18 , pp. 51
    • Watson, P.1    Parshall, G.2
  • 68
    • 0028761731 scopus 로고
    • 4, via σ-bond metathesis. (Matrix Presented) See also: Rothwell, I. P. Acc. Chem. Res 1988, 21, 153 and Ryabov, A. D. Chem. Rev. 1990, 90, 403 and references therein.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 10015
    • Yang, X.1    Stern, C.2    Marks, T.3
  • 69
    • 33845278992 scopus 로고
    • 4, via σ-bond metathesis. (Matrix Presented) See also: Rothwell, I. P. Acc. Chem. Res 1988, 21, 153 and Ryabov, A. D. Chem. Rev. 1990, 90, 403 and references therein.
    • (1988) Acc. Chem. Res , vol.21 , pp. 153
    • Rothwell, I.P.1
  • 70
    • 0042728760 scopus 로고
    • and references therein
    • 4, via σ-bond metathesis. (Matrix Presented) See also: Rothwell, I. P. Acc. Chem. Res 1988, 21, 153 and Ryabov, A. D. Chem. Rev. 1990, 90, 403 and references therein.
    • (1990) Chem. Rev. , vol.90 , pp. 403
    • Ryabov, A.D.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.