Models of high-valent intermediates of non-heme diiron alkane monooxygenases: Electronic structure of a bis(μ-oxo)diron(IV) complex with locally low-spin metal centers

Angewandte Chemie - International Edition

Volumn 43, Issue 7, 2004, Pages 834-838

  Ghosh, Abhik ^a   Tangen, Espen ^a   Gonzalez, Emmanuel ^a   Que Jr , Lawrence ^b  

^a UNIVERSITY OF TROMSØ   (Norway)

^b University of Minnesota   (United States)

Author keywords

Density functional calculations; Iron; O ligands; Porphyrinoids

Indexed keywords

DIMERS; MATHEMATICAL MODELS; OXIDATION; PROBABILITY DENSITY FUNCTION; STEREOCHEMISTRY;

DENSITY THEORY CALCULATIONS; HEME DIMERS; OXIDATION STATE;

ELECTRONIC STRUCTURE;

ALKANE DERIVATIVE; DIAMOND; DIMER; HEME; IRON DERIVATIVE; UNSPECIFIC MONOOXYGENASE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; OXIDATION;

ALKANES; CHEMISTRY, PHYSICAL; DIMERIZATION; ELECTRONS; HEMEPROTEINS; IRON COMPOUNDS; LIGANDS; METALS; MIXED FUNCTION OXYGENASES; MODELS, MOLECULAR; NONHEME IRON PROTEINS; PORPHYRINS;

EID: 4544344171     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351768     Document Type: Article

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