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Volumn 39, Issue 15, 2000, Pages 3125-3139

Mechanistic studies of (porphinato)iron-catalyzed isobutane oxidation. Comparative studies of three classes of electron-deficient porphyrin catalysts

Author keywords

[No Author keywords available]

Indexed keywords

BROMINE DERIVATIVE; BUTANE; HYDROCARBON; IRON; MACROCYCLIC COMPOUND; OXYGEN; PEROXIDE; PORPHYRIN DERIVATIVE;

EID: 0343278988     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic000284o     Document Type: Article
Times cited : (53)

References (97)
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    • Dawson, J. H. Science 1988, 240, 433-439.
    • (1988) Science , vol.240 , pp. 433-439
    • Dawson, J.H.1
  • 70
    • 0343799536 scopus 로고    scopus 로고
    • note
    • Interestingly, no isobutanol was produced in this reaction, implying that isobutane or tert-butyl hydroperoxide must be present to generate this species, since the acetone generated in this experiment assuredly derives from tert-butoxy radical.
  • 76
    • 0343363648 scopus 로고    scopus 로고
    • note
    • BDE = 93 kcal/mol).
  • 79
    • 0343799535 scopus 로고    scopus 로고
    • note
    • BDE = 111 kcal/mol).
  • 80
    • 0003998388 scopus 로고
    • CRC Press: Boca Raton, FL
    • -1 at 80 °C. Provided that ΔS° for this reaction does not deviate appreciably from 23 eu, a standard value for bond homolysis reactions (see for example: (a) Handbook of Chemistry and Physics, 71st ed.; CRC Press: Boca Raton, FL, 1990; pp D51-D95.
    • (1990) Handbook of Chemistry and Physics, 71st Ed.
  • 82
    • 0000088382 scopus 로고
    • BDE values for PFe-OH complexes that have been measured to date (see: Richert, S. A.; Tsang, P. K. S.; Sawyer, D. T. Inorg. Chem. 1989, 28, 2471-2475. Tung, H. C.; Chooto, P.; Sawyer, D. T. Langmuir 1991, 7, 1635-1641).
    • (1989) Inorg. Chem. , vol.28 , pp. 2471-2475
    • Richert, S.A.1    Tsang, P.K.S.2    Sawyer, D.T.3
  • 83
    • 0026205357 scopus 로고
    • BDE values for PFe-OH complexes that have been measured to date (see: Richert, S. A.; Tsang, P. K. S.; Sawyer, D. T. Inorg. Chem. 1989, 28, 2471-2475. Tung, H. C.; Chooto, P.; Sawyer, D. T. Langmuir 1991, 7, 1635-1641).
    • (1991) Langmuir , vol.7 , pp. 1635-1641
    • Tung, H.C.1    Chooto, P.2    Sawyer, D.T.3
  • 97
    • 3042907629 scopus 로고
    • 4, for reoxidation of PFe(II) by tert-butyl hydroperoxide to compete with the dioxygen-mediated reaction, the bimolecular rate constant for this process would have to exceed that for a diffusion-controlled process by (at least) a factor of 1000
    • 4, for reoxidation of PFe(II) by tert-butyl hydroperoxide to compete with the dioxygen-mediated reaction, the bimolecular rate constant for this process would have to exceed that for a diffusion-controlled process by (at least) a factor of 1000.
    • (1994) Chem. Rev. , vol.94 , pp. 659-698
    • Momenteau, M.1    Reed, C.A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.