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For the full standing-up phase or complete-looping phase the layers on top of Au can be regarded as ordered homogeneous monolayers, and hence the model calculation adequately describes the quantification of the monolayer. However, minor problems with respect to exact quantification are expected for less homogeneous systems, which are possibly responsible for SAMs having both looped and standing-up phases. Therefore, a realistic estimation of the percentage of looped molecules In the monolayer formed is not trivial from XPS results
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For the full standing-up phase or complete-looping phase the layers on top of Au can be regarded as ordered homogeneous monolayers, and hence the model calculation adequately describes the quantification of the monolayer. However, minor problems with respect to exact quantification are expected for less homogeneous systems, which are possibly responsible for SAMs having both looped and standing-up phases. Therefore, a realistic estimation of the percentage of looped molecules In the monolayer formed is not trivial from XPS results.
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Calculation of the molecule length was done with ACD/Labs 8.00 software.
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Calculation of the molecule length was done with ACD/Labs 8.00 software.
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