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The C-C and C-S bond angles are 112°. The C-C bond length is 1.541 Å, and the C-S bond length is 1.81 Å. Without both of the S-bonded H atoms, the dithiol fragment is estimated to be 9.4 Å.
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41
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25544479093
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Theoretical studies suggest that sulfur atoms should be imaged as a protrusion on metal surfaces [Lang, N. D. Phys. Rev. Lett. 1986, 56, 1164]. Also, both experimental and theoretical investigations have shown that sulfur atoms are imaged as bright features on Ni(100) surfaces [Partridge, A.; Tatlock, G. J.; Leibsle, F. M.; Flipse, C. F. J.; Hörmandinger, G.; Pendry, J. B. Phys. Rev. B 1993, 48, 8267].
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The boiling point of 1,6-hexanedithiol is 391 K/15 mm from the Aldrich Chemical Co. Catalog. The boiling point of n-decanethiol is 399 K/19 mm from the CRC Handbook of Physics and Chemistry; Lide, D. R. Ed.; CRC Press: Boca Raton, FL, 1992.
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The boiling point of 1,6-hexanedithiol is 391 K/15 mm from the Aldrich Chemical Co. Catalog. The boiling point of n-decanethiol is 399 K/19 mm from the CRC Handbook of Physics and Chemistry; Lide, D. R. Ed.; CRC Press: Boca Raton, FL, 1992.
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