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Trans stereochemistry of the cyclohexene derivative 6 was confirmed by comparison of its spectral data as well as its M.P.
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Trans stereochemistry of the cyclohexene derivative 6 was confirmed by comparison of its spectral data as well as its M.P.
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CCDC 651000 (9), 651048 (10), 651049 (15), 651050 (21), 651051 (22), 651052 (25) contains the supplementary crystallographic data available free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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CCDC 651000 (9), 651048 (10), 651049 (15), 651050 (21), 651051 (22), 651052 (25) contains the supplementary crystallographic data available free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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Stereochemistry was confirmed by comparing the J values of related structures from the following references. (We are thankful to one of the referees for suggesting to establish the stereochemistry of furano sugar derivatives by this comparison.) (a) Liautard, V.; Desvergnes, V.; Martin, O. R. Org. Lett. 2006, 8, 1299.
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The N-glycosyl amides are chemically very stable. We here report for the first time that 1-N acetyl sugar derivatives can be successfully deprotected to free amines.
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The N-glycosyl amides are chemically very stable. We here report for the first time that 1-N acetyl sugar derivatives can be successfully deprotected to free amines.
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