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0344343620
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note
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4, and concentrated in vacuo to afford a colorless oil. The residue was chromatographed on silica gel (eluent hexane/ethyl acetate) and/or crystallized (ethyl acetate/hexane) to afford the products 3 or 4.
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14
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0033591162
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This concept was previously used by us to assign the configuration of a C-glycosylalanine: Lieberknecht, A.; Griesser, H.; Krämer, B.; Bravo, R. D.; Colinas, P. A.; Grigera, R. J. Tetrahedron 1999, 55, 6475.
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Colinas, P.A.5
Grigera, R.J.6
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15
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0345206125
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note
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Also the presence of NOE effect between the H-1 and H-5 in compounds 3a and 4a confirms the configuration of the anomeric center.
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17
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0035936677
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18
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0344343621
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INIBIOLP (UNLP-CONICET), Fac. Cs. Médicas (personal communication)
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Bravo, M. G. de. INIBIOLP (UNLP-CONICET), Fac. Cs. Médicas (personal communication).
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De Bravo, M.G.1
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