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Although it is unclear as to what might have caused such deviation, it is suspected that the dimethylamino groups in newly formed polymers may interact with the metallomonomer in the polymerization mixture, potentially leading to other reaction pathways.
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It is at the ortho position on the phenyl moiety in 17 and para position in 22
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The structures of 17 and 22 differ only in the position of the ammonium methyl group on the side chain. It is at the ortho position on the phenyl moiety in 17 and para position in 22. This subtle difference is not anticipated to give rise to the significant difference observed in the two groups of LbL films.
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Massey, J.A.1
Kulbaba, K.2
Winnik, M.A.3
Manners, I.4
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