Thermal and transition-metal-catalyzed ring-opening polymerization (ROP) of [1]silaferrocenophanes with chlorine substituents at silicon: A route to tunable poly(ferrocenylsilanes)

Organometallics

Volumn 15, Issue 8, 1996, Pages 1972-1978

  Zechel, David L ^a   Hultzsch, Kai C ^a   Rulkens, Ron ^a   Balaishis, David ^a   Ni, Yizeng ^a   Pudelski, John K ^a   Lough, Alan J ^a   Manners, Ian ^a   Foucher, Daniel A ^b  

^a UNIVERSITY OF TORONTO   (Canada)

^b XEROX RESEARCH CENTRE OF CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001616625     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950911v     Document Type: Article

References (58)

1. For example, see: (a) Pittman, C. U., Jr.; Carraher, C. E., Jr.; Reynolds, J. R. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; Vol. 10, p 541. (b) Sheats, J. E.; Carraher, C. E., Jr.; Pittman, C. U. Metal-Containing Polymer Systems; Plenum: New York, 1985. (c) Chisholm, M. H. Angew. Chem., Int. Ed. Engl. 1991, 30, 673. (d) Manners, I. Chem. Br. 1996, 32, 46.
2. For example, see: (a) Pittman, C. U., Jr.; Carraher, C. E., Jr.; Reynolds, J. R. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; Vol. 10, p 541. (b) Sheats, J. E.; Carraher, C. E., Jr.; Pittman, C. U. Metal-Containing Polymer Systems; Plenum: New York, 1985. (c) Chisholm, M. H. Angew. Chem., Int. Ed. Engl. 1991, 30, 673. (d) Manners, I. Chem. Br. 1996, 32, 46.
3. For example, see: (a) Pittman, C. U., Jr.; Carraher, C. E., Jr.; Reynolds, J. R. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; Vol. 10, p 541. (b) Sheats, J. E.; Carraher, C. E., Jr.; Pittman, C. U. Metal-Containing Polymer Systems; Plenum: New York, 1985. (c) Chisholm, M. H. Angew. Chem., Int. Ed. Engl. 1991, 30, 673. (d) Manners, I. Chem. Br. 1996, 32, 46.
4. For example, see: (a) Pittman, C. U., Jr.; Carraher, C. E., Jr.; Reynolds, J. R. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; Vol. 10, p 541. (b) Sheats, J. E.; Carraher, C. E., Jr.; Pittman, C. U. Metal-Containing Polymer Systems; Plenum: New York, 1985. (c) Chisholm, M. H. Angew. Chem., Int. Ed. Engl. 1991, 30, 673. (d) Manners, I. Chem. Br. 1996, 32, 46.
5. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
6. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
7. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
8. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
9. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
10. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
11. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
12. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
13. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
14. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
15. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
16. For example, see: (a) Compton, D. L.; Rauchfuss, T. B. Organometallics 1994, 13, 4367. (b) Brandt, P. F.; Rauchfuss, T. B. J. Am. Chem. Soc. 1992, 114, 1926. (c) Nugent, H. M.; Rosenblum, M.; Klemarczyk, P. J. Am. Chem. Soc. 1993, 115, 3848. (d) Bayer, R.; Pöhlmann, T.; Nuyken, O. Makromol. Chem. Rapid. Commun. 1993, 14, 359. (e) Manners, I. Adv. Mater. 1994, 6, 68. (f) Gonsalves, K.; Zhanru, L.; Rausch, M. D. J. Am. Chem. Soc. 1984, 106, 3862. (g) Neuse, E. W.; Bednarik, L. Macromolecules 1979, 12, 187. (h) Patterson, W. J.; McManus, S.; Pittman, C. U. J. Polym. Sci. A. 1974, 12, 837. (i) Altmann, M.; Bunz, U. H. F. Angew. Chem., Int. Ed. Engl. 1995, 34, 569. (j) Fyfe, H. B.; Mlekuz, M.; Zargarian, D.; Taylor, N. J.; Marder, T. B. J. Chem. Soc., Chem. Commun. 1991, 188. (k) Khan, M. S.; Kakkar, A. K.; Ingham, S. L.; Raithby, P. R.; Lewis, J.; Spencer, B.; Wittmann, F.; Friend, R. H. J. Organomet. Chem. 1994, 472, 247. (1) Hagihara, N.; Sonogashira, K.; Takahashi, S. Adv. Polym. Sci. 1981, 41, 149.
17. Rosenberg, H. U.S. Patent 3,426,053, 1969.
18. Foucher, D. A.; Tang, B.-Z.; Manners, I. J. Am. Chem. Soc. 1992, 114, 6246.
19. Foucher, D. A.; Ziembinski, R.; Tang, B.-Z.; Macdonald, P. M.; Massey, J.; Jaeger, C. R.; Vancso, G. J.; Manners, I. Macromolecules 1993, 26, 2878.
20. Foucher, D. A.; Honeyman, C. H.; Nelson, J. M.; Tang, B.-Z.; Manners, I. Angew. Chem., Int. Ed. Engl. 1993, 32, 1709.
21. Foucher, D.; Ziembinski, R.; Petersen, R.; Pudelski, J.; Edwards, M.; Ni, Y.; Massey, J.; Jaeger, C. R.; Vancso, G. J.; Manners, I. Macromolecules 1994, 27, 3992.
22. Rulkens, R.; Lough, A. J.; Manners, I. J. Am. Chem. Soc. 1994, 116, 797.
23. Tang, B.-Z.; Petersen, R.; Foucher, D. A.; Lough, A. J.; Coombs, N.; Sodhi, R.; Manners, I. J. Chem. Soc., Chem. Commun. 1993, 523.
24. Manners, I. Adv. Organomet. Chem. 1995, 37, 131.
25. For the work of other groups on poly(ferrocenylsilanes) and related materials, see: (a) Tanaka, M.; Hayashi, T. Bull. Chem. Soc. Jpn. 1993, 66, 334. (b) Nguyen, M. T.; Diaz, A. F.; Dement'ev, V. V.; Pannell, K. H. Chem. Mater. 1993, 5, 1389. (c) Hmyene, M.; Yassar, A.; Escorne, M.; Percheron-Guegan, A.; Garnier, F. Adv. Mater. 1994, 5, 564.
26. For the work of other groups on poly(ferrocenylsilanes) and related materials, see: (a) Tanaka, M.; Hayashi, T. Bull. Chem. Soc. Jpn. 1993, 66, 334. (b) Nguyen, M. T.; Diaz, A. F.; Dement'ev, V. V.; Pannell, K. H. Chem. Mater. 1993, 5, 1389. (c) Hmyene, M.; Yassar, A.; Escorne, M.; Percheron-Guegan, A.; Garnier, F. Adv. Mater. 1994, 5, 564.
27. For the work of other groups on poly(ferrocenylsilanes) and related materials, see: (a) Tanaka, M.; Hayashi, T. Bull. Chem. Soc. Jpn. 1993, 66, 334. (b) Nguyen, M. T.; Diaz, A. F.; Dement'ev, V. V.; Pannell, K. H. Chem. Mater. 1993, 5, 1389. (c) Hmyene, M.; Yassar, A.; Escorne, M.; Percheron-Guegan, A.; Garnier, F. Adv. Mater. 1994, 5, 564.
28. Pudelski, J. K.; Manners, I. J. Am. Chem. Soc. 1995, 117, 7265.
29. We have also reported the ROP of other [1]- and [2]metallocenophanes. See for example: (a) Reference 10.
30. (b) Pudelski, J. K.; Gates, D. P.; Rulkens, R.; Lough, A.; Manners, I. Angew. Chem., Int. Ed. Engl. 1995, 34, 1506 and references cited therein.
31. (a) Rulkens, R.; Ni, Y.; Manners, I. J. Am. Chem. Soc. 1994, 116, 12121.
32. (b) Ni, Y.; Rulkens, R.; Manners, I. J. Am. Chem. Soc. 1996, 118, in press.
33. Ni, Y.; Rulkens, R.; Pudelski, J. K.; Manners, I. Macromol. Rapid Commun. 1995, 16, 637.
34. Tanaka, M.; Reddy, N. P.; Yamashita, H. J. Chem. Soc., Chem. Commun. 1995, 2263.
35. Macromolecular substitutions have been used extensively to control the properties of polyphosphazenes. See: (a) Allcock, H. R. Chem. Eng. News 1985, 63 (11), 22. (b) Allcock, H. R. J. Inorg. Organomet. Polym. 1992, 2, 197.
36. Macromolecular substitutions have been used extensively to control the properties of polyphosphazenes. See: (a) Allcock, H. R. Chem. Eng. News 1985, 63 (11), 22. (b) Allcock, H. R. J. Inorg. Organomet. Polym. 1992, 2, 197.
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