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Volumn 129, Issue 46, 2007, Pages 14303-14310

Homogeneous catalytic reduction of dioxygen using transfer hydrogenation catalysts

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CATALYSIS; CATALYSTS; DERIVATIVES; HYDROGENATION; KINETICS; REDUCTION;

EID: 36448950558     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja073774p     Document Type: Article
Times cited : (108)

References (110)
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    • Many attempts at isolation of metal amine alkoxides have been unsuccessful: Koike, T.; Ikariya, T. Organometallics 2005, 24, 724-730.
  • 39
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    • Although the dehydrogenation of 1H(H) by O2 in benzene-d6 was rapid, catalytic hydrogenation was problematic because [1H]BArF4 is insoluble in benzene-d6, slowing the hydrogenation of 1 to 40% conversion over 30 vs 16 h, for complete conversion in CD2Cl 2
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  • 65
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    • The reduction of turnover number for a greater catalyst-to-substrate ratio is indicative of a catalyst deactivation mechanism different than that observed for the dehydrogenation of ammonia-boranes and 1HH
    • The reduction of turnover number for a greater catalyst-to-substrate ratio is indicative of a catalyst deactivation mechanism different than that observed for the dehydrogenation of ammonia-boranes and 1H(H).
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    • 2, in a methylene chloride solution, 5 equiv of BQ was converted to HQ over the course of 12 h.
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    • 2NCHPhCHPhNTs), 4.5 (br d, 1H, HHNCHPhCHPhNTs), 4.80 (d, 1H, J = 11.1 Hz, HHNCHPhCHPhNTs), 4.91 (br t, 1H, HHNCHPhCHPhNTs), 5.41 (s, 1H), 5.54 (s, 1H), 6.83-7.38 (m, 14H).
    • 2NCHPhCHPhNTs), 4.5 (br d, 1H, HHNCHPhCHPhNTs), 4.80 (d, 1H, J = 11.1 Hz, HHNCHPhCHPhNTs), 4.91 (br t, 1H, HHNCHPhCHPhNTs), 5.41 (s, 1H), 5.54 (s, 1H), 6.83-7.38 (m, 14H).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.