Kinetic isotope effect evidence for the concerted transfer of hydride and proton from hydroxycyclopentadienyl ruthenium hydride in solvents of different polarities and hydrogen bonding ability

Canadian Journal of Chemistry

Volumn 83, Issue 9, 2005, Pages 1339-1346

  Casey, Charles P ^a   Johnson, Jeffrey B ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

Hydrogenation mechanism; Kinetic isotope effects; Ligand metal bifunctional catalysis; Ruthenium hydrogenation catalysis

Indexed keywords

CATALYSIS; HYDRIDES; HYDROGEN BONDS; HYDROGENATION; ISOTOPES; REACTION KINETICS; SOLVENTS;

HYDROGENATION MECHANISM; KINETIC ISOTOPE EFFECTS; LIGAND-METAL BIFUNCTIONAL CATALYSIS; RUTHENIUM HYDROGENATION CATALYSIS;

RUTHENIUM COMPOUNDS;

ACETOPHENONE; ALCOHOL; BENZALDEHYDE; CYCLOPENTADIENE DERIVATIVE; DICHLOROMETHANE; HYDROGEN; HYDROXYCYCLOPENTADIENYLRUTHENIUM HYDRIDE; ISOTOPE; PROTON; RUTHENIUM DERIVATIVE; SOLVENT; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; ENERGY; HYDROGEN BOND; HYDROGENATION; KINETICS; LIGAND BINDING; MOLECULAR STABILITY; PROTON TRANSPORT; REACTION ANALYSIS; REDUCTION;

EID: 33644585505     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v05-140     Document Type: Article

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