메뉴 건너뛰기




Volumn 26, Issue 18, 2007, Pages 4471-4482

Hyperelectronic metal-carborane analogues of cymantrene (MnCp(CO) 3) anions: Electronic and structural noninnocence of the tricarbadecaboranyl ligand

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; CYCLIC VOLTAMMETRY; DENSITY FUNCTIONAL THEORY; ELECTROCHEMISTRY; ELECTRONS; LIGANDS; X RAY CRYSTALLOGRAPHY;

EID: 34548572083     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700496v     Document Type: Article
Times cited : (25)

References (113)
  • 1
    • 0002955304 scopus 로고
    • For examples see: a
    • For examples see: (a) Geiger, W. E. Ace Chem. Res. 1995, 28, 351.
    • (1995) Ace Chem. Res , vol.28 , pp. 351
    • Geiger, W.E.1
  • 3
    • 19944419804 scopus 로고    scopus 로고
    • 2) Appel, A.M.; Newell, R.; Dubois, D. L.; Rakowski DuBois, M. Inorg. Chem. 2005, 44, 3046.
    • 2) Appel, A.M.; Newell, R.; Dubois, D. L.; Rakowski DuBois, M. Inorg. Chem. 2005, 44, 3046.
  • 4
    • 30944442835 scopus 로고    scopus 로고
    • 2) Schrock, R. R. Acc Chem. Res. 2005, 38, 955.
    • 2) Schrock, R. R. Acc Chem. Res. 2005, 38, 955.
  • 5
    • 11244271592 scopus 로고    scopus 로고
    • 2 evolution) Borg, S. J.; Behrsing, T.; Besp, S. P.; Razavet, M.; Liu, X.; Pickett, C. J. J. Am. Chem. Soc 2004, 126, 16988.
    • 2 evolution) Borg, S. J.; Behrsing, T.; Besp, S. P.; Razavet, M.; Liu, X.; Pickett, C. J. J. Am. Chem. Soc 2004, 126, 16988.
  • 6
    • 33751297588 scopus 로고    scopus 로고
    • Also: Felton, G. A. N.; Glass, R. S.; Lichtenberger, D. L.; Evans, D. H. Inorg. Chem. 2006, 45, 9181.
    • Also: Felton, G. A. N.; Glass, R. S.; Lichtenberger, D. L.; Evans, D. H. Inorg. Chem. 2006, 45, 9181.
  • 8
    • 30344481662 scopus 로고    scopus 로고
    • (Olefin polymerization) Scott, J.; Gambarotta, S.: Korobkov, I. Budzelaar, P. H. M. Organometallics 2005, 24, 6298.
    • (d) (Olefin polymerization) Scott, J.; Gambarotta, S.: Korobkov, I. Budzelaar, P. H. M. Organometallics 2005, 24, 6298.
  • 30
    • 0001499304 scopus 로고    scopus 로고
    • Veiros, L. F. J. Organomet. Chem. 1999, 587, 221. There is, of course, a close conceptual parallel between addition of either two electrons or a two-electron donor to a molecule. For leading references to haptotropic shifts involving the latter see:
    • (b) Veiros, L. F. J. Organomet. Chem. 1999, 587, 221. There is, of course, a close conceptual parallel between addition of either two electrons or a two-electron donor to a molecule. For leading references to haptotropic shifts involving the latter see:
  • 34
    • 4244001171 scopus 로고    scopus 로고
    • 4] converts to -2.86 V vs ferrocene, (b) The electrochemical reduction of cymantrene has also been reported in acetonitrile (-2.90V vs FcH), and the origin of the chemical irreversibility was examined by spectroscopy:
    • 4] converts to -2.86 V vs ferrocene, (b) The electrochemical reduction of cymantrene has also been reported in acetonitrile (-2.90V vs FcH), and the origin of the chemical irreversibility was examined by spectroscopy:
  • 46
    • 34548586342 scopus 로고    scopus 로고
    • 5. Based on the measurements of Hawthorne et al., a value of -0.29 V has been reported
    • 5. Based on the measurements of Hawthorne et al., a value of -0.29 V has been reported
  • 47
    • 34548597637 scopus 로고    scopus 로고
    • 2-.
    • 2-.
  • 48
    • 0039721999 scopus 로고    scopus 로고
    • 6 see: Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S., Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
    • 6 see: Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S., Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
  • 49
    • 0001523421 scopus 로고
    • On metalloporphyrin systems see
    • On metalloporphyrin systems see: Guilard, R.: Kadish, K. M. Chem. Rev. 1988, 88, 1121.
    • (1988) Chem. Rev , vol.88 , pp. 1121
    • Guilard, R.1    Kadish, K.M.2
  • 51
    • 0001394394 scopus 로고
    • Leading references to the haptotropic reanangement of the Cp ligand: (a) Basolo, F
    • Leading references to the haptotropic reanangement of the Cp ligand: (a) Basolo, F. Polyhedron 1990, 9, 1503.
    • (1990) Polyhedron , vol.9 , pp. 1503
  • 55
    • 0034683325 scopus 로고    scopus 로고
    • For a systematic set of calculations see the series by, i
    • (b) For a systematic set of calculations see the series by Braden, D. A.; Tyler, D. R. in: (i) Organometallics 2000, 19, 3762;
    • (2000) Organometallics , vol.19 , pp. 3762
    • Braden, D.A.1    Tyler, D.R.2
  • 56
    • 0000467239 scopus 로고    scopus 로고
    • (ii) Organometallics 2000, 19, 1175;
    • (2000) Organometallics , vol.19 , pp. 1175
  • 57
    • 0000362208 scopus 로고    scopus 로고
    • and
    • (iii) Organometallics 1998, 17, 4060; and
    • (1998) Organometallics , vol.17 , pp. 4060
  • 58
    • 0032507017 scopus 로고    scopus 로고
    • J. Am. Chem. Soc 1998, 120, 942.
    • (iv) J. Am. Chem. Soc 1998, 120, 942.
  • 59
    • 0002543261 scopus 로고
    • Cotton, F. A, Ed, John Wiley and Sons, New York
    • (a) McCleverty, J. A. In Progress in Inorganic Chemistry; Cotton, F. A., Ed.; John Wiley and Sons, New York, 1968; Vol. 10, pp 49-219.
    • (1968) Progress in Inorganic Chemistry , vol.10 , pp. 49-219
    • McCleverty, J.A.1
  • 60
    • 34548562928 scopus 로고    scopus 로고
    • Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard. R. D.. McCleverty, J., Eds.; Pergamon Press: Oxford, 1987, 2. pp 595-631.
    • (b) Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard. R. D.. McCleverty, J., Eds.; Pergamon Press: Oxford, 1987, Vol. 2. pp 595-631.
  • 73
  • 76
    • 34548592609 scopus 로고    scopus 로고
    • Crystal Structure Analysis Package; Rigaku Corp
    • CrystalStructure, Crystal Structure Analysis Package; Rigaku Corp.: Rigaku/MSC, 2002.
    • (2002) Rigaku/MSC
    • CrystalStructure1
  • 77
    • 0242560405 scopus 로고    scopus 로고
    • SIR97: Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G. L.; Giovanni, M.; Giacovazzo, C.; Guagliardi, A.; Moliterni, A.; Polidori, G. J.; Spagna, R. J. Appl. Crystallogr. 1999, 32, 115.
    • SIR97: Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G. L.; Giovanni, M.; Giacovazzo, C.; Guagliardi, A.; Moliterni, A.; Polidori, G. J.; Spagna, R. J. Appl. Crystallogr. 1999, 32, 115.
  • 78
    • 0004150157 scopus 로고    scopus 로고
    • Program for the Refinement of Crystal Structures; University of Göttingen: Germany
    • Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures; University of Göttingen: Germany, 1997.
    • (1997) SHELXL-97
    • Sheldrick, G.M.1
  • 82
    • 33845883717 scopus 로고    scopus 로고
    • Vrije Universiteit: Amsterdam, The Netherlands
    • (c) ADF2005.01, SCM, Theoretical Chemistry, Vrije Universiteit: Amsterdam, The Netherlands, http://www.scm.com.
    • (2005) 01, SCM, Theoretical Chemistry
    • ADF1
  • 89
    • 34548584472 scopus 로고    scopus 로고
    • The potential separation of two unresolved but closely spaced oneelectron waves may be obtained by analysis of the ΔEP separation in cyclic voltammetry or the width at half-height, W1/2, in differential pulse voltammograms. Account must be taken of ohmic effects, which in the present case were subtracted by making measurements of a ferrocene standard displaying the same currents as the analyte. The resistance-corrected W 1/2 value for 1 was 89 mV in CH2Cl2/0.1 M [NEt4][B(C6H3(CF3)2) 4, allowing the assignment of E1/2(1, E1/2(2) as 35 mV based on the tabular data in ref 48
    • 1/2(2) as 35 mV based on the tabular data in ref 48.
  • 90
    • 34548560996 scopus 로고    scopus 로고
    • 1/2 in V).
    • 1/2 in V).
  • 98
    • 34548592610 scopus 로고    scopus 로고
    • 4 ligand in ref 41.
    • 4 ligand in ref 41.
  • 99
    • 34548589662 scopus 로고    scopus 로고
    • Additionally, two other smaller hfs also predicted for other nonequivalent borons
    • Additionally, two other smaller hfs also predicted for other nonequivalent borons.
  • 107
    • 0001483559 scopus 로고    scopus 로고
    • The necessary analytical data are found in: Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20, 1278.
    • The necessary analytical data are found in: Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20, 1278.
  • 110
    • 34548565110 scopus 로고    scopus 로고
    • 0/-. Although this difference is not likely to be large, we note that the potential shift that we calculate for replacement of Cp by tricarbadecaboranyl is, in fact, a lower limit.
    • 0/-. Although this difference is not likely to be large, we note that the potential shift that we calculate for replacement of Cp by tricarbadecaboranyl is, in fact, a lower limit.
  • 111
    • 0001026795 scopus 로고    scopus 로고
    • Separations of 500 mV or more are commonly observed for successive one-electron reductions of metal complexes. See, for example: (a) metal dithiolenes: ref 14a. (b) Metal carboranes: Callahan, K. P.; Hawthorne, M. F. Adv. Organometal. Chem. 1976, 14, 145.
    • Separations of 500 mV or more are commonly observed for successive one-electron reductions of metal complexes. See, for example: (a) metal dithiolenes: ref 14a. (b) Metal carboranes: Callahan, K. P.; Hawthorne, M. F. Adv. Organometal. Chem. 1976, 14, 145.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.