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4244001171
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4] converts to -2.86 V vs ferrocene, (b) The electrochemical reduction of cymantrene has also been reported in acetonitrile (-2.90V vs FcH), and the origin of the chemical irreversibility was examined by spectroscopy:
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4] converts to -2.86 V vs ferrocene, (b) The electrochemical reduction of cymantrene has also been reported in acetonitrile (-2.90V vs FcH), and the origin of the chemical irreversibility was examined by spectroscopy:
-
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35
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0001607369
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(e) Barnum, B. A.; Carroll, P. J.; Sneddon, L. G. Inorg. Chem. 1997, 36, 1327.
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44
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0034801571
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(a) Wasczcak, M. D.; Wang, Y.; Garg, A.; Geiger, W. E.; Kang, S. O.; Carroll, P. J.; Sneddon, L. G. J. Am. Chem. Soc. 2001, 123, 2783.
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0037999888
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(b) Ramachandran, B. M.; Trupia, S. M.; Geiger, W. E.; Carroll, P. J.; Sneddon, L. G. Organometallics 2002, 21, 5078.
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46
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34548586342
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5. Based on the measurements of Hawthorne et al., a value of -0.29 V has been reported
-
5. Based on the measurements of Hawthorne et al., a value of -0.29 V has been reported
-
-
-
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47
-
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34548597637
-
-
2-.
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2-.
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-
-
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48
-
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0039721999
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6 see: Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S., Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
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49
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34548584472
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The potential separation of two unresolved but closely spaced oneelectron waves may be obtained by analysis of the ΔEP separation in cyclic voltammetry or the width at half-height, W1/2, in differential pulse voltammograms. Account must be taken of ohmic effects, which in the present case were subtracted by making measurements of a ferrocene standard displaying the same currents as the analyte. The resistance-corrected W 1/2 value for 1 was 89 mV in CH2Cl2/0.1 M [NEt4][B(C6H3(CF3)2) 4, allowing the assignment of E1/2(1, E1/2(2) as 35 mV based on the tabular data in ref 48
-
1/2(2) as 35 mV based on the tabular data in ref 48.
-
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90
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34548560996
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1/2 in V).
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1/2 in V).
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97
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0005946002
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98
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34548592610
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4 ligand in ref 41.
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4 ligand in ref 41.
-
-
-
-
99
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-
34548589662
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-
Additionally, two other smaller hfs also predicted for other nonequivalent borons
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Additionally, two other smaller hfs also predicted for other nonequivalent borons.
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100
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33748621232
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Braga, D.; Benedi, O.; Maini, L.; Grepioni, F. J. Chem. Soc., Dalton Trans. 1999, 2611
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(a) Stoll, M. E.; Belanzoni, P.; Calhorda, M. J.; Drew, M. G. B.; Félix, V.; Geiger, W. E.; Gamelas, C. A.; Gonçalves, I. S.; Romão, C. C.; Veiros, L. F. J. Am. Chem. Soc. 2001, 123, 10595.
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0037083917
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0001483559
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The necessary analytical data are found in: Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20, 1278.
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The necessary analytical data are found in: Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20, 1278.
-
-
-
-
110
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-
34548565110
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-
0/-. Although this difference is not likely to be large, we note that the potential shift that we calculate for replacement of Cp by tricarbadecaboranyl is, in fact, a lower limit.
-
0/-. Although this difference is not likely to be large, we note that the potential shift that we calculate for replacement of Cp by tricarbadecaboranyl is, in fact, a lower limit.
-
-
-
-
111
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-
0001026795
-
-
Separations of 500 mV or more are commonly observed for successive one-electron reductions of metal complexes. See, for example: (a) metal dithiolenes: ref 14a. (b) Metal carboranes: Callahan, K. P.; Hawthorne, M. F. Adv. Organometal. Chem. 1976, 14, 145.
-
Separations of 500 mV or more are commonly observed for successive one-electron reductions of metal complexes. See, for example: (a) metal dithiolenes: ref 14a. (b) Metal carboranes: Callahan, K. P.; Hawthorne, M. F. Adv. Organometal. Chem. 1976, 14, 145.
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112
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3543076252
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Taylor, N.J.4
Marder, T.B.5
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