Reexamination of 1,4-hydride exchange within the η5-naphthalenyl complex [Mn(η5-C10H9)(CO)3] establishes an exchange rate intermediate between those in the cyclohexadienyl and anthracenyl analogues

Organometallics

Volumn 19, Issue 19, 2000, Pages 3942-3947

  Veauthier, Jacqueline M ^a   Chow, Albert ^b   Fraenkel, Gideon ^b   Geib, Steven J ^a   Cooper, N John ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

^b OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; COMPLEXATION; ENTROPY; MAGNETIZATION; MANGANESE COMPOUNDS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTONS;

ANTHRACENE;

ORGANOMETALLICS;

EID: 0034683271     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000102y     Document Type: Article

References (30)

1. Veauthier, J. M.; Chow, A.; Fraenkel, G.; Geib, S. J.; Cooper, N. J. Organometallics 2000, 19, 661.
2. Lamanna, W.; Brookhart, M. J. Am. Chem. Soc. 1980, 102, 3490.
3. Georg, A.; Kreiter, C. G. Eur J. Inorg. Chem. 1999, 651.
4. Thompson, R. L.; Lee, S.; Rheingold, A. L.; Cooper, N. J. Organometallics 1991, 10, 1657.
5. Karplus, M. J. Chem. Phys. 1959, 30, 11.
6. Sun, S. H.; Dullaghan, C. A.; Carpenter, G. B.; Sweigart, D. A.; Lee, S. S.; Chung, Y. K. Inorg. Chim. Acta 1997, 262, 213.
7. Churchill, M. R.; Scholer, F. R. Inorg. Chem. 1969, 8, 1950.
8. (a) Ittel, S. D.; Whitney, J. F.; Chung, Y. K.; Williard, P. G.; Sweigart, D. A. Organometallics 1988, 7, 1323.
9. (b) Ryan, W. J.; Peterson, P. E.; Cao, Y.; Williard, P. G.; Sweigart, D. A.; Baer, C. D.; Thompson, C. F.; Chung, Y. K.; Chung, T.-M. Inorg. Chim. Acta 1993, 211, 1.
10. (c) Reau, R.; Reed, R. W.; Dahan, F.; Bertrand, G. Organometallics 1993, 12, 1501.
11. (d) Lee, T.; Yu, H. B.; Chung, Y. K.; Hallows, W. A.; Sweigart, D. A. Inorg. Chim. Acta 1994, 224, 147.
12. (e) Rose-Munch, F.; Le Corre-Susanne, C.; Baissa, F.; Rose, E.; Vaisserman, J.; Licandro, E.; Papagni, A.; Maiorana, S.; Meng, W.; Stephenson, G. R. J. Organomet. Chem. 1997, 545-546, 9.
13. (f) Baissa, F.; Gagliardini, V.; Le Corre-Susanne, C.; Rose-Munch, F.; Rose, E.; Vaisserman, J. Bull. Soc. Chim. Fr. 1997, 134, 537.
14. (g) Rose-Munch, F.; Gagliardini, V.; Renard, C.; Rose, E. Coord. Chem. Rev. 1998, 178-180, 249.
15. (h) Rose, E.; Le Corre-Susanne, C.; Rose-Munch, F.; Renard, C.; Gagliardini, V.; Teldji, F.; Vaissermann, J. Eur. J. Inorg. Chem. 1999, 3, 421.
16. (a) Sanders, J. K.; Hunter, B. K. In Modern NMR Spectroscopy: A Guide for Chemists; Oxford University Press: New York, 1990; Chapters 1-3, 6, and 17.
17. (b) Noggle, J. H.; Schirmer, R. E. In The Nuclear Overhauser Effect; Academic Press: New York, 1971; Chapters 1 and 7.
18. (c) Forsen, S.; Hoffman, R. A. J. Chem. Phys. 1963, 39, 2892.
19. 1H NMR spectra: (a) Kleier, D. A.; Binsch, G. QCPE 1970, 11, 165. (b) Binsch, G.; Kessler, H. Angew. Chem., Int. Ed. Engl. 1980, 19, 411.
20. 1H NMR spectra: (a) Kleier, D. A.; Binsch, G. QCPE 1970, 11, 165. (b) Binsch, G.; Kessler, H. Angew. Chem., Int. Ed. Engl. 1980, 19, 411.
21. (a) Sandstrom, J. In Dynamic NMR Spectroscopy; Academic Press: London, 1982; Chapter 7.
22. (b) Glasstone, S.; Laidler, K.; Eyring, H. In The Theory of Rate Processes; McGraw-Hill: New York, 1941; p 195.
23. (c) Eyring, H. Chem. Rev. 1935, 17, 65.
24. (a) Rerek, M. E.; Ji, L.-N.; Basolo, F. J. Chem. Soc., Chem. Commun. 1983, 1208.
25. (b) Ji, L.-N.; Rerek, M. E.; Basolo, F. Organometallics 1984, 3, 740.
26. (c) O'Connor, J. M.; Casey, C. P. Chem. Rev. 1987, 87, 307.
27. (d) Merola, J. S.; Kacmarcik, R. T.; Van Engen, D. J. Am. Chem. Soc. 1986, 108, 329, and references therein.
28. (e) Crabtree, R. H. In The Organometallic Chemistry of the Transition Metals, 2nd ed.; John Wiley & Sons: New York, 1994; Chapters 4 and 5.
29. Son, S. U.; Paik, S.-J.; Lee, I. S.; Lee, Y.-A.; Chung, Y. K. Organometallics 1999, 18, 4114.
30. endo is 3.23 (1) Å in 1 and 3.13 (1) Å in 5.