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Volumn 128, Issue 12, 2006, Pages 3980-3989

Use of weakly coordinating anions to develop an integrated approach to the tuning of ΔE1/2 values by medium effects

Author keywords

[No Author keywords available]

Indexed keywords

BISMUTH; CHLORINE; ELECTROLYTES; HALIDE MINERALS; NEGATIVE IONS; SODIUM; SOLVENTS; TUNING;

EID: 33645469936     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja058171x     Document Type: Article
Times cited : (477)

References (99)
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    • The literature on this topic is extensive, being represented by: (a) Creutz, C. In Progress in Inorganic Chemistry; Lippard, S. J., Ed.; Wiley and Sons: New York, 1983; Vol. 30, p 1.
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    • note
    • 1/2 values in this paper, whether the redox processes involve oxidations to cations or reductions to anions. The oxidation process is treated as proceeding from the neutral compound A to the +1 and +2-charged species B and C, respectively. When reductions are introduced later in the text, they are also treated as originating from neutral compounds, but leading in that case to anionic products.
  • 30
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    • Swarc, M., Ed.; Wiley-Interscience: New York
    • (a) Swarc, M., Ed. Ions and Ion Pain in Organic Reactions; Wiley-Interscience: New York, 1972; Vols. 1 and 2.
    • (1972) Ions and Ion Pain in Organic Reactions , vol.1-2
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    • and references therein
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    • (2000) Chem. Rev. , vol.100 , pp. 1391
    • Chen, E.Y.-X.1    Marks, T.J.2
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    • (b) A reviewer has pointed out that Drago's S′ solvent values may be used optimally to describe the nonspecific solvation effects assumed in the present work. Relevant references may be found in Mu, L.; Drago, R. S.; Richardson, D. E. J. Chem. Soc., Perkin Trans. 2 1998, 159.
    • (1998) J. Chem. Soc., Perkin Trans. 2 , pp. 159
    • Mu, L.1    Drago, R.S.2    Richardson, D.E.3
  • 63
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    • Refs 16b, p 160 ff. Nonspecific solvation is assumed for the models in the present study. A simple Born model has been shown to provide an adequate description of solvation effects in metallocene redox reactions. See: Ryan, M. F.; Richardson, D. E.; Lichtenberger, D. L.; Gruhn, N. E. Organometallics 1994, 13, 1190.
    • (1994) Organometallics , vol.13 , pp. 1190
    • Ryan, M.F.1    Richardson, D.E.2    Lichtenberger, D.L.3    Gruhn, N.E.4
  • 66
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    • see data entry in Table 1 of this paper
    • (c) Smart, J. C.; Pinsky, B. L. J. Am. Chem. Soc. 1980, 102, 1009 (see data entry in Table 1 of this paper).
    • (1980) J. Am. Chem. Soc. , vol.102 , pp. 1009
    • Smart, J.C.1    Pinsky, B.L.2
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    • See ref 21
    • See ref 21.
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    • note
    • Leading references may be found in ref 2.
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    • Karlin, K. D., Stiefel, E. I., Eds.; John Wiley and Sons; New York
    • (b) Wang, K. In Progress in Inorganic Chemistry, Karlin, K. D., Stiefel, E. I., Eds.; John Wiley and Sons; New York, 2003; Vol. 52, pp 267-314.
    • (2003) Progress in Inorganic Chemistry , vol.52 , pp. 267-314
    • Wang, K.1
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    • Pombeiro, A. J. L., Amatore, C., Eds.; Marcel Dekker: New York
    • (c) Zanello, P.; Grigiotti, E. In Trends in Molecular Electrochemistry; Pombeiro, A. J. L., Amatore, C., Eds.; Marcel Dekker: New York, 2004; pp 3-70.
    • (2004) Trends in Molecular Electrochemistry , pp. 3-70
    • Zanello, P.1    Grigiotti, E.2
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    • note
    • That is, the solvent acts as a continuum and does not form coordinate bonds with the analyte.
  • 85
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    • Wiley: New York
    • p < 60 mV (CV), and widths at half-height less than 90 mV (differential pulse voltammetry and square wave voltammetry. See: Bard, A. J.; Faulkner, L. R. Electrochemical Methods, 2nd ed.; Wiley: New York, 2001.
    • (2001) Electrochemical Methods, 2nd Ed.
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    • note
    • 2 containing the large tetraheptylammonium cation and the small bromide anion.
  • 96
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    • For early references to the search for noncoordinating anions, see ref 13a as well as: (a) Bochmann, M. Angew. Chem., Int. Ed. Engl. 1992, 31, 1181.
    • (1992) Angew. Chem., Int. Ed. Engl. , vol.31 , pp. 1181
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    • note
    • For traditional models addressing the relationship between solvation energies and delocalization of charges in cations, see ref 16b, pp 319 ff.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.