메뉴 건너뛰기




Volumn 26, Issue 18, 2007, Pages 4575-4584

Pyrrolide-supported lanthanide alkyl complexes. influence of ligands on molecular structure and catalytic activity toward isoprene polymerization

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; LIGANDS; MICROSTRUCTURE; MOLECULAR STRUCTURE; PARAFFINS; POLYMERIZATION;

EID: 34548548549     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7003095     Document Type: Article
Times cited : (103)

References (104)
  • 14
    • 33745178786 scopus 로고    scopus 로고
    • Selected reviews: Hou, Z.; Luo, Y.; Li, X. J. Organomet. Chem. 2006, 691, 3114.
    • (g) Selected reviews: Hou, Z.; Luo, Y.; Li, X. J. Organomet. Chem. 2006, 691, 3114.
  • 95
    • 34548553929 scopus 로고    scopus 로고
    • 1H NMR monitoring of the reaction of complex la with 1 equiv of [Ph3C, B(C6F5)4] in C 6D6 at 25 °C showed almost quantitative formation of Ph3CCH2SiMe3 (δ5 7.42-7.43 (m, 6H, o-Ph, 7.19-7.21 (m, 9H, m.pPh, 2.17 (s, 2H, CH2, 0.10 (s, 9H, SiMe3, Additional signals were observed at δ6.95-7.03 (m, 3H, m,p-C6H3, 6.44, 6.80, 6.82 (s, 3H, pyr, 3.26 (s, 8H, THF, 1.68 (s, 6H, C6H3Me2, 1.25 (s, 8H, THF, 0.11 (s, 9H, Lu-CH2SiMe2, 0.01, 0.03 (s, 2H, Lu-CH2SiMe3, which may be assigned to [L 1Lu(CH2SiMe3)(THF)2][B(C6Fs)4, although the proton in the ligand CH=N could not be unequivocally assigned due to possible overlap with the other signals o-Ph
    • 2][B(C6Fs)4], although the proton in the ligand CH=N could not be unequivocally assigned due to possible overlap with the other signals (o-Ph).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.